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Rare Metals

Erschienen in:

20.12.2023 | Mini Review

Structure engineering of cathode host materials for Li–S batteries

verfasst von: Jia-Jun Long, Hua Yu, Wen-Bo Liu

Erschienen in: Rare Metals | Ausgabe 4/2024

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Abstract

Although lithium–sulfur batteries are one of the favorable candidates for next-generation energy storage devices, a few key challenges that have not been addressed have limited its commercialization. These challenges include lithium dendrite growth in the anode side, volume change of the active material, poor electrical conductivity, dissolution and migration of polysulfides, and slow rate of solid-state reactions in the cathode side. Since the electrochemical performance of lithium–sulfur batteries is greatly affected by the design of the cathode host material, it has also been widely discussed in addressing the above-mentioned issues. In this paper, three design ideas of cathode host materials in terms of microstructure, crystal structure and electronic structure are introduced and summarized. Crucially, the current progress of these three structural design strategies and their effects on the electrochemical performance of lithium–sulfur batteries are discussed in detail. Finally, future directions in the structural design of cathode materials for lithium–sulfur batteries are discussed and further perspectives are provided.

Vorheriger Artikel Advance in reversible Zn anodes promoted by 2D materials

Nächster Artikel Rare earth element-modified MOF materials: synthesis and photocatalytic applications in environmental remediation

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[1]

Goodenough JB, Kim Y. Challenges for rechargeable Li batteries. Chem Mater. 2010;22(3):587. https://doi.org/10.1021/cm901452z.CrossRef

[2]

Guo YM, Zhang LJ. Research progress in synthesis and electrochemical performance of cobalt sulfide as anode material for secondary batteries. Chin J Rare Met. 2022,46(2):227. https://doi.org/10.13373/j.cnki.cjrm.XY20050006.

[3]

Kang X, Fu G, Wang X, Shao L, Li W, Tsang CW, Lu XY, Fu XZ, Luo JL. Copper-cobalt-nickel oxide nanowire arrays on copper foams as self-standing anode materials for lithium ion batteries. Chin Chem Lett. 2021;32(2):938. https://doi.org/10.1016/j.cclet.2020.06.013.CrossRef

[4]

Wu Y, Ouyang T, Xiong T, Jiang Z, Hu Y, Deng J, Wang Z, Huang Y, Balogun MS. Boosted storage kinetics in thick hierarchical micro–nano carbon architectures for high areal capacity Li-ion batteries. Energy Environ Mater. 2021;5(4):12241. https://doi.org/10.1002/eem2.12241.CrossRef

[5]

Dong X, Liu W, Chen X, Yan J, Li N, Shi S, Zhang S, Yang X. Novel three dimensional hierarchical porous Sn–Ni alloys as anode for lithium ion batteries with long cycle life by pulse electrodeposition. Chem Eng J. 2018;350:791. https://doi.org/10.1016/j.cej.2018.06.031.CrossRef

[6]

Liu W, Cheng P, Zhang S, Shi S. Facile in-situ synthesis of freestanding 3D nanoporous Cu@Cu₂O hierarchical nanoplate arrays as binder-free integrated anodes for high-capacity, long-life Li-ion batteries. Metall Mater Trans A. 2020;51(5):2536. https://doi.org/10.1007/s11661-020-05655-x.CrossRef

[7]

Liu WB, Chen X, Zhang JZ, Zhang SC, Shi SQ. In-situ synthesis of freestanding porous SnO_x-decorated Ni₃Sn₂ composites with enhanced Li storage properties. Chem Eng J. 2021;412:9. https://doi.org/10.1016/j.cej.2021.128591.CrossRef

[8]

Liu W, Chen L, Cui L, Yan J, Zhang S, Shi S. Freestanding 3D nanoporous Cu@1D Cu₂O nanowire heterostructures: from a facile one-step protocol to robust application in Li storage. J Mater Chem A. 2019;7(25):15089. https://doi.org/10.1039/c9ta02565k.CrossRef

[9]

Liu WB, Zhang SC, Li N, Zheng JW, Xing YL. A facile one-pot route to fabricate nanoporous copper with controlled hierarchical pore size distributions through chemical dealloying of Al–Cu alloy in an alkaline solution. Microporous Mesoporous Mater. 2011;138(1–3):1. https://doi.org/10.1016/j.micromeso.2010.10.003.CrossRef

[10]

Li F, Wang L, Qu G, Hou P, Kong L, Huang J, Xu X. An integrated approach to configure rGO/VS₄/S composites with improved catalysis of polysulfides for advanced lithium–sulfur batteries. Chin Chem Lett. 2022;33(8):3909. https://doi.org/10.1016/j.cclet.2021.11.046.CrossRef

[11]

Ji X, Nazar LF. Advances in Li–S batteries. J Mater Chem. 2010;20(44):9821. https://doi.org/10.1039/b925751a.CrossRef

[12]

Peng H-J, Huang J-Q, Cheng X-B, Zhang Q. Review on high-loading and high-energy lithium–sulfur batteries. Adv Energy Mater. 2017;7(24):1700260. https://doi.org/10.1002/aenm.201700260.CrossRef

[13]

Tang TY, Zhang LG, Guo ZF, Gu XX. Development of cathode and anode materials in lithium sulfur batteries. Chin J Rare Met. 2022,46(7):954. https://doi.org/10.13373/j.cnki.cjrm.XY21070001.

[14]

Zhou L, Danilov DL, Eichel RA, Notten PHL. Host materials anchoring polysulfides in Li–S batteries reviewed. Adv Energy Mater. 2021;11(15):2001304. https://doi.org/10.1002/aenm.202001304.CrossRef

[15]

Wang Y, Huang X, Zhang S, Hou Y. Sulfur hosts against the shuttle effect. Small Methods. 2018;2(6):1700345. https://doi.org/10.1002/smtd.201700345.CrossRef

[16]

Feng S, Singh RK, Fu Y, Li Z, Wang Y, Bao J, Xu Z, Li G, Anderson C, Shi L, Lin Y, Khalifah PG, Wang W, Liu J, Xiao J, Lu D. Low-tortuous and dense single-particle-layer electrode for high-energy lithium–sulfur batteries. Energy Environ Sci. 2022;15(9):3842. https://doi.org/10.1039/d2ee01442d.CrossRef

[17]

Wang Q, Zhao H, Li B, Yang C, Li M, Li Y, Han P, Wu M, Li T, Liu R. MOF-derived Co₉S₈ nano-flower cluster array modified separator towards superior lithium sulfur battery. Chin Chem Lett. 2021;32(3):1157. https://doi.org/10.1016/j.cclet.2020.09.022.CrossRef

[18]

Cuisinier M, Cabelguen PE, Evers S, He G, Kolbeck M, Garsuch A, Bolin T, Balasubramanian M, Nazar LF. Sulfur speciation in Li–S batteries determined by operando X-ray absorption spectroscopy. J Phys Chem Lett. 2013;4(19):3227. https://doi.org/10.1021/jz401763d.CrossRef

[19]

Wild M, O’Neill L, Zhang T, Purkayastha R, Minton G, Marinescu M, Offer GJ. Lithium sulfur batteries, a mechanistic review. Energy Environ Sci. 2015;8(12):3477. https://doi.org/10.1039/c5ee01388g.CrossRef

[20]

Chen X, Peng HJ, Zhang R, Hou TZ, Huang JQ, Li B, Zhang Q. An analogous periodic law for strong anchoring of polysulfides on polar hosts in lithium sulfur batteries: S- or Li-binding on first-row transition-metal sulfides? ACS Energy Lett. 2017;2(4):795. https://doi.org/10.1021/acsenergylett.7b00164.CrossRefADS

[21]

Walus S, Offer G, Hunt I, Patel Y, Stockley T, Williams J, Purkayastha R. Volumetric expansion of lithium-sulfur cell during operation fundamental insight into applicable characteristics. Energy Storage Mater. 2018;10:233. https://doi.org/10.1016/j.ensm.2017.05.017.CrossRef

[22]

Yuan N, Deng YR, Wang SH, Gao L, Yang JL, Zou NC, Liu BX, Zhang JQ, Liu RP, Zhang L. Towards superior lithiumsulfur batteries with metalorganic frameworks and their derivatives. Tungsten. 2022;4(4):269. https://doi.org/10.1007/s42864-022-00186-x.

[23]

Lee BJ, Kang TH, Lee HY, Samdani JS, Jung Y, Zhang C, Yu Z, Xu GL, Cheng L, Byun S, Lee YM, Amine K, Yu JS. Revisiting the role of conductivity and polarity of host materials for long-life lithium–sulfur battery. Adv Energy Mater. 2020;10(22):1903934. https://doi.org/10.1002/aenm.201903934.CrossRef

[24]

Jia L, Wang J, Ren S, Ren G, Jin X, Kao L, Feng X, Yang F, Wang Q, Pan L, Li Q, Liu YS, Wu Y, Liu G, Feng J, Fan S, Ye Y, Guo J, Zhang Y. Unraveling shuttle effect and suppression strategy in lithium/sulfur cells by in situ/operando X-ray absorption spectroscopic characterization. Energy Environ Mater. 2021;4(2):222. https://doi.org/10.1002/eem2.12152.CrossRef

[25]

Yeon JS, Ko YH, Park TH, Park H, Kim J, Park HS. Multidimensional hybrid architecture encapsulating cobalt oxide nanoparticles into carbon nanotube branched nitrogen-doped reduced graphene oxide networks for lithium–sulfur batteries. Energy Environ Mater. 2022;5(2):555. https://doi.org/10.1002/eem2.12187.CrossRef

[26]

Chen H, Wu ZZ, Zheng MT, Liu TC, Yan C, Lu J, Zhang SQ. Catalytic materials for lithium–sulfur batteries: mechanisms, design strategies and future perspective. Mater Today. 2022;52:364. https://doi.org/10.1016/j.mattod.2021.10.026.CrossRef

[27]

Ji X, Lee KT, Nazar LF. A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries. Nat Mater. 2009;8(6):500. https://doi.org/10.1038/nmat2460.CrossRefPubMedADS

[28]

Xin S, Yin YX, Wan LJ, Guo YG. Encapsulation of sulfur in a hollow porous carbon substrate for superior Li–S batteries with long lifespan. Part Part Syst Char. 2013;30(4):321. https://doi.org/10.1002/ppsc.201300029.CrossRef

[29]

Hong XJ, Tang XY, Wei Q, Song CL, Wang SY, Dong RF, Cai YP, Si LP. Efficient encapsulation of small S_2–4 molecules in MOF-derived flowerlike nitrogen-doped microporous carbon nanosheets for high-performance Li–S batteries. ACS Appl Mater Interfaces. 2018;10(11):9435. https://doi.org/10.1021/acsami.7b19609.CrossRefPubMed

[30]

Gao F, Qu J, Zhao Z, Qiu J. Efficient synthesis of graphene/sulfur nanocomposites with high sulfur content and their application as cathodes for Li–S batteries. J Mater Chem A. 2016;4(41):16219. https://doi.org/10.1039/c6ta06953c.CrossRef

[31]

Li H, Sun L, Zhao Y, Tan T, Zhang Y. Blackberry-like hollow graphene spheres synthesized by spray drying for high-performance lithium–sulfur batteries. Electrochim Acta. 2019;295:822. https://doi.org/10.1016/j.electacta.2018.11.012.CrossRef

[32]

Benítez A, Caballero A, Morales J, Hassoun J, Rodríguez-Castellón E, Canales-Vázquez J. Physical activation of graphene: an effective, simple and clean procedure for obtaining microporous graphene for high-performance Li/S batteries. Nano Res. 2019;12(4):759. https://doi.org/10.1007/s12274-019-2282-2.CrossRef

[33]

Liu Z, Wang L, Yang W. Hierarchically porous nitrogen-doped carbon foams decorated with zinc nanodots as high-performance sulfur hosts for lithium–sulfur battery. Chin Chem Lett. 2021;32(9):2919. https://doi.org/10.1016/j.cclet.2021.02.0271001-8417.CrossRef

[34]

Li X, Sun Q, Liu J, Xiao B, Li R, Sun X. Tunable porous structure of metal organic framework derived carbon and the application in lithium–sulfur batteries. J Power Sources. 2016;302:174. https://doi.org/10.1016/j.jpowsour.2015.10.049.CrossRef

[35]

Wang D, Zhao ZY, Wang P, Wang SM, Feng M. Synthesis of MOF-derived nitrogen-doped carbon microtubules via template self-consumption. Rare Met. 2022;41(8):2582. https://doi.org/10.1007/s12598-022-01987-2.

[36]

Wang L, Liu S, Hu J, Zhang X, Li X, Zhang G, Li Y, Zheng C, Hong X, Duan H. Tailoring polysulfide trapping and kinetics by engineering hollow carbon bubble nanoreactors for high-energy Li-S pouch cells. Nano Res. 2021;14(5):1355. https://doi.org/10.1007/s12274-020-3181-2.CrossRefADS

[37]

Jia X, Liu B, Liu J, Zhang S, Sun Z, He X, Li H, Wang G, Chang H. Fabrication of NiO–carbon nanotube/sulfur composites for lithium–sulfur battery application. Rsc Adv. 2021;11(18):10753. https://doi.org/10.1039/d1ra00216c.CrossRefPubMedPubMedCentralADS

[38]

Zhang Y, Lin Y, He L, Murugesan V, Pawar G, Sivakumar BM, Ding H, Ding D, Liaw B, Dufek EJ, Li B. Dual functional Ni₃S₂@Ni core–shell nanoparticles decorating nanoporous carbon as cathode scaffolds for lithium–sulfur battery with lean electrolytes. ACS Appl Energy Mater. 2020;3(5):4173. https://doi.org/10.1021/acsaem.0c00568.CrossRef

[39]

Liu R, Liu W, Bu Y, Yang W, Wang C, Priest C, Liu Z, Wang Y, Chen J, Wang Y, Cheng J, Lin X, Feng X, Wu G, Ma Y, Huang W. Conductive porous laminated vanadium nitride as carbon-free hosts for high-loading sulfur cathodes in lithium–sulfur batteries. ACS Nano. 2020;14(12):17308. https://doi.org/10.1021/acsnano.0c07415.CrossRefPubMed

[40]

Yan Y, Li H, Cheng C, Yan T, Gao W, Mao J, Dai K, Zhang L. Boosting polysulfide redox conversion of Li–S batteries by one-step-synthesized Co–Mo bimetallic nitride. J Energy Chem. 2021;61:336. https://doi.org/10.1016/j.jechem.2021.03.041.CrossRef

[41]

Deng S, Shi X, Zhao Y, Wang C, Wu J, Yao X. Catalytic Mo₂C decorated N-doped honeycomb-like carbon network for high stable lithium–sulfur batteries. Chem Eng J. 2022;433:133683. https://doi.org/10.1016/j.cej.2021.133683.CrossRef

[42]

Shen Z, Cao M, Zhang Z, Pu J, Zhong C, Li J, Ma H, Li F, Zhu J, Pan F, Zhang H. Efficient Ni₂Co₄P₃ nanowires catalysts enhance ultrahigh-loading lithium–sulfur conversion in a microreactor-like battery. Adv Funct Mater. 2020;30(3):1906661. https://doi.org/10.1002/adfm.201906661.CrossRef

[43]

Liang X, Kwok CY, Lodi-Marzano F, Pang Q, Cuisinier M, Huang H, Hart CJ, Houtarde D, Kaup K, Sommer H, Brezesinski T, Janek J, Nazar LF. Tuning transition metal oxide-sulfur interactions for long life lithium sulfur batteries: the “goldilocks” principle. Adv Energy Mater. 2016;6(6):1501636. https://doi.org/10.1002/aenm.201501636.CrossRef

[44]

Liu WB, Zhang SC, Li N, Zheng JW, An SS, Li GX. Influence of dealloying solution on the microstructure of monolithic nanoporous copper through chemical dealloying of al 30 at% Cu alloy. Int J Electrochem Sci. 2012;7(9):7993.CrossRef

[45]

Ge X, Li C, Li Z, Yin L. Tannic acid tuned metal-organic framework as a high-efficiency chemical anchor of polysulfide for lithium–sulfur batteries. Electrochim Acta. 2018;281:700. https://doi.org/10.1016/j.electacta.2018.06.010.CrossRef

[46]

Liu J, Zhu M, Shen Z, Han T, Si T, Hu C, Zhang H. A polysulfides-confined all-in-one porous microcapsule lithium–sulfur battery cathode. Small. 2021;17(41):2103051. https://doi.org/10.1002/smll.202103051.CrossRef

[47]

Li R, Bai Z, Hou W, Qiao J, Sun W, Bai Y, Wang Z, Sun K. Spinel-type bimetal sulfides derived from prussian blue analogues as efficient polysulfides mediators for lithium–sulfur batteries. Chin Chem Lett. 2021;32(12):4063. https://doi.org/10.1016/j.cclet.2020.03.048.CrossRef

[48]

Wang M, Yin D, Cao Y, Dong X, Gao G, Hu X, Jin C, Fan L, Yu J, Liu H. Surface modification of hollow capsule by dawson-type polyoxometalate as sulfur hosts for ultralong-life lithium–sulfur batteries. Chin Chem Lett. 2022;33(9):4350. https://doi.org/10.1016/j.cclet.2021.11.043.CrossRef

[49]

Zhou J, Yu X, Fan X, Wang X, Li H, Zhang Y, Li W, Zheng J, Wang B, Li X. The impact of the particle size of a metal–organic framework for sulfur storage in Li–S batteries. J Mater Chem A. 2015;3(16):8272. https://doi.org/10.1039/c5ta00524h.CrossRef

[50]

Liu W, Cheng P, Yan X, Gou H, Zhang S, Shi S. Facile one-step solution-phase route to synthesize hollow nanoporous Cu_xO microcages on 3D copper foam for superior Li storage. ACS Sustain Chen Eng. 2021;9(12):4363. https://doi.org/10.1021/acssuschemeng.0c09203.CrossRef

[51]

Tian L, Zhang Z, Liu S, Li G, Gao X. High-entropy spinel oxide nanofibers as catalytic sulfur hosts promise the high gravimetric and volumetric capacities for lithium–sulfur batteries. Energy Environ Mater. 2022;5(2):645. https://doi.org/10.1002/eem2.12215.CrossRef

[52]

Cu Q, Shang CQ, Zhou GF, Wang X. Freestanding MoSe2 nanoflowers for superior Li/Na storage properties. Tungsten. 2022. https://doi.org/10.1007/s42864-022-00167-0.

[53]

Chen S, Zhang J, Wang Z, Nie L, Hu X, Yu Y, Liu W. Electrocatalytic NiCo₂O₄ nanofiber arrays on carbon cloth for flexible and high-loading lithium–sulfur batteries. Nano Lett. 2021;21(12):5285. https://doi.org/10.1021/acs.nanolett.1c01422.CrossRefPubMedADS

[54]

Wang M, Yang H, Shen K, Xu H, Wang W, Yang Z, Zhang L, Chen J, Huang Y, Chen M, Mitlin D, Li X. Stable lithium sulfur battery based on in situ electrocatalytically formed Li₂S on metallic MoS₂–carbon cloth support. Small Methods. 2020;4(9):2000353. https://doi.org/10.1002/smtd.202000353.CrossRef

[55]

Zhao Q, Zhu Q, Miao J, Zhang P, Xu B. 2D MXene nanosheets enable small-sulfur electrodes to be flexible for lithium–sulfur batteries. Nanoscale. 2019;11(17):8442. https://doi.org/10.1039/c8nr09653h.CrossRefPubMed

[56]

Zhu Q, Xu HF, Shen K, Zhang YZ, Li B, Yang SB. Efficient polysulfides conversion on Mo2CTx MXene for high-performance lithium-sulfur batteries. Rare Metals. 2022;41(1):311. https://doi.org/10.1007/s12598-021-01839-5.

[57]

Sun Z, Zhang J, Yin L, Hu G, Fang R, Cheng H-M, Li F. Conductive porous vanadium nitride/graphene composite as chemical anchor of polysulfides for lithium–sulfur batteries. Nat Commun. 2017;8(1):14627. https://doi.org/10.1038/ncomms14627.CrossRefPubMedPubMedCentralADS

[58]

Xia J, Chen W, Yang Y, Guan X, Yang T, Xiao M, Zhang S, Xing Y, Lu X, Zhou G. In-situ growth of ultrathin sulfur microcrystal on MXene-based 3D matrice for flexible lithium–sulfur batteries. EcoMat. 2022;4(3):12183. https://doi.org/10.1002/eom2.12183.CrossRef

[59]

Liu WB, Zhang SC, Li N, Zheng JW, An SS, Xing YL. Monolithic nanoporous copper ribbons from Mg–Cu alloys with copper contents below 33 at%: Fabrication, structure evolution and coarsening behavior along the thickness direction. Int J Electrochem Sci. 2011;6(11):5445. https://doi.org/10.1016/S1452-3981(23)18419-7.

[60]

Yan X, Kang H, Cheng P, Zhang S, Shi S, Liu W. Monolithic three-dimensional hollow nanoporous Cu_xO encapsulated mesoporous Cu heterostructures with superior Li storage properties. EcoMat. 2022;4(5):e12208. https://doi.org/10.1002/eom2.12208.CrossRef

[61]

Liu W, Chen X, Xiang P, Zhang S, Yan J, Li N, Shi S. Chemically monodisperse tin nanoparticles on monolithic 3D nanoporous copper for lithium ion battery anodes with ultralong cycle life and stable lithium storage properties. Nanoscale. 2019;11(11):4885. https://doi.org/10.1039/c8nr09398a.CrossRefPubMed

[62]

Han Z, Li S, Xiong R, Jiang Z, Sun M, Hu W, Peng L, He R, Zhou H, Yu C, Cheng S, Xie J. Low tortuosity and reinforced concrete type ultra-thick electrode for practical lithium–sulfur batteries. Adv Funct Mater. 2022;32(12):2108669. https://doi.org/10.1002/adfm.202108669.CrossRef

[63]

Lin S, Wang Y, Chen Y, Cai Z, Xiao J, Muhmood T, Hu X. 3D ordered porous nanostructure confers fast charge transfer rate and reduces the electrode polarization in thick electrode. Small. 2021;18(7):2104224. https://doi.org/10.1002/smll.202104224.CrossRef

[64]

Pu Y, Wu W, Liu J, Liu T, Ding F, Zhang J, Tang Z. A defective MOF architecture threaded by interlaced carbon nanotubes for high-cycling lithium–sulfur batteries. Rsc Adv. 2018;8(33):18604. https://doi.org/10.1039/c8ra02254b.CrossRefPubMedPubMedCentralADS

[65]

Abdul Razzaq A, Yuan X, Chen Y, Hu J, Mu Q, Ma Y, Zhao X, Miao L, Ahn JH, Peng Y, Deng Z. Anchoring MOF-derived CoS₂ on sulfurized polyacrylonitrile nanofibers for high areal capacity lithium–sulfur batteries. J Mater Chem A. 2020;8(3):1298. https://doi.org/10.1039/c9ta11390h.CrossRef

[66]

Guan B, Sun X, Zhang Y, Wu X, Qiu Y, Wang M, Fan L, Zhang N. The discovery of interfacial electronic interaction within cobalt boride@MXene for high performance lithium–sulfur batteries. Chin Chem Lett. 2021;32(7):2249. https://doi.org/10.1016/j.cclet.2020.12.051.CrossRef

[67]

Tian D, Song X, Qiu Y, Sun X, Jiang B, Zhao C, Zhang Y, Xu X, Fan L, Zhang N. Heterogeneous mediator enabling three-dimensional growth of lithium sulfide for high-performance lithium–sulfur batteries. Energy Environ Mater. 2021;5(4):12236. https://doi.org/10.1002/eem2.12236.CrossRef

[68]

Lin Y, Ouyang Z, He S, Song X, Luo Y, Zhao J, Xiao Y, Lei S, Yuan C, Cheng B. An individual sandwich hybrid nanostructure of cobalt disulfide in-situ grown on N doped carbon layer wrapped on multi-walled carbon nanotubes for high-efficiency lithium sulfur batteries. J Colloid Interface Sci. 2022;610:560. https://doi.org/10.1016/j.jcis.2021.11.102.CrossRefPubMedADS

[69]

Zhang J, Shi Y, Ding Y, Peng L, Zhang W, Yu G. A conductive molecular framework derived Li₂S/N, P-codoped carbon cathode for advanced lithium–sulfur batteries. Adv Energy Mater. 2017;7(14):1602876. https://doi.org/10.1002/aenm.201602876.CrossRef

[70]

Song Y, Long X, Luo Z, Guo C, Geng CN, Ouyang QS, Han Z, Zhou G, Shao JJ. Solid carbon spheres with interconnected open pore channels enabling high-efficient polysulfide conversion for high-rate lithium–sulfur batteries. ACS Appl Mater Interfaces. 2022;14(28):32183. https://doi.org/10.1021/acsami.2c09331.CrossRefPubMed

[71]

Wu Z, Wang L, Chen S, Zhu X, Deng Q, Wang J, Zeng Z, Deng S. Facile and low-temperature strategy to prepare hollow ZIF-8/CNT polyhedrons as high-performance lithium–sulfur cathodes. Chem Eng J. 2021;404:126579. https://doi.org/10.1016/j.cej.2020.126579.CrossRef

[72]

Qi C, Zu S, Zhu X, Zhang T, Li L, Song L, Jin Y, Zhang M. Bamboo-shaped Co@NCNTs as superior sulfur host for Li–S batteries. Appl Surf Sci. 2022;601:154245. https://doi.org/10.1016/j.apsusc.2022.154245.CrossRef

[73]

Shi G, Shi X, Hou Y, Zhang S, Han Y, Li Q. An ant-nest like hierarchical nanoreactor for highly efficient sulfur species redox reactions. J Alloys Compd. 2022;914:165211. https://doi.org/10.1016/j.jallcom.2022.165211.CrossRef

[74]

Ai G, Dai Y, Mao W, Zhao H, Fu Y, Song X, En Y, Battaglia VS, Srinivasan V, Liu G. Biomimetic ant-nest electrode structures for high sulfur ratio lithium–sulfur batteries. Nano Lett. 2016;16(9):5365. https://doi.org/10.1021/acs.nanolett.6b01434.CrossRefPubMedADS

[75]

Yao Y, Chang C, Sun H, Guo D, Li R, Pu X, Zhai J. Hollow Ni₃Se₄ with high tap density as a carbon-free sulfur immobilizer to realize high volumetric and gravimetric capacity for lithium–sulfur batteries. ACS Appl Mater Interfaces. 2022;14(22):25267. https://doi.org/10.1021/acsami.2c01951.CrossRefPubMed

[76]

Cui J, Liu J, Chen X, Meng J, Wei S, Wu T, Wang Y, Xie Y, Lu C, Zhang X. Ganoderma lucidum-derived erythrocyte-like sustainable materials. Carbon. 2022;196:70. https://doi.org/10.1016/j.carbon.2022.04.034.CrossRef

[77]

Liu W, Lu B, Liu X, Gan Y, Zhang S, Shi S. In situ synthesis of the peapod-like Cu–SnO₂@copper foam as anode with excellent cycle stability and high area specific capacity. Adv Funct Mater. 2021;31(33):2101999. https://doi.org/10.1002/adfm.202101999.CrossRef

[78]

Feng L, Ji Y, Zhu Z, Yu P, Fu X, Yang M, Wang Y, Yang W. Rational design and superfast production of biomimetic, calendering-compatible, catalytic, sulfur-rich secondary particles for advanced lithium–sulfur batteries. Energy Storage Mater. 2021;40:415. https://doi.org/10.1016/j.ensm.2021.05.038.CrossRef

[79]

Luo Y, Wan Y, Huang J, Li B. Nanofiber enhanced graphene-elastomer with unique biomimetic hierarchical structure for energy storage and pressure sensing. Mater Des. 2021;203:109612. https://doi.org/10.1016/j.matdes.2021.109612.CrossRef

[80]

Jiang B, Tian D, Qiu Y, Song X, Zhang Y, Sun X, Huang H, Zhao C, Guo Z, Fan L, Zhang N. High-index faceted nanocrystals as highly efficient bifunctional electrocatalysts for high-performance lithium–sulfur batteries. Nano-Micro Lett. 2022;14(1):40. https://doi.org/10.1007/s40820-021-00769-2.CrossRefADS

[81]

Liu S, Liu X, Chen M, Wang D, Ge X, Zhang W, Wang X, Wang C, Qin T, Qin H, Qiao L, Zhang D, Ou X, Zheng W. High-density/efficient surface active sites on modified separators to boost Li–S batteries via atomic Co³⁺-Se termination. Nano Res. 2022;15(8):7199. https://doi.org/10.1007/s12274-022-4381-8.CrossRefADS

[82]

Geng P, Wang L, Du M, Bai Y, Li W, Liu Y, Chen S, Braunstein P, Xu Q, Pang H. MIL-96-Al for Li–S batteries: Shape or size? Adv Mater. 2022;34(4):2107836. https://doi.org/10.1002/adma.202107836.CrossRef

[83]

Jiang B, Qiu Y, Tian D, Zhang Y, Song X, Zhao C, Wang M, Sun X, Huang H, Zhao C, Zhou H, Chen A, Fan L, Zhang N. Crystal facet engineering induced active tin dioxide nanocatalysts for highly stable lithium–sulfur batteries. Adv Energy Mater. 2021;11(48):2102995. https://doi.org/10.1002/aenm.202102995.CrossRef

[84]

Wang ZY, Zhang B, Liu S, Li GR, Yan T, Gao XP. Nickel–platinum alloy nanocrystallites with high-index facets as highly effective core catalyst for lithium–sulfur batteries. Adv Funct Mater. 2022;32(27):2200893. https://doi.org/10.1002/adfm.202200893.CrossRef

[85]

Zhang Y, Mu Z, Yang C, Xu Z, Zhang S, Zhang X, Li Y, Lai J, Sun Z, Yang Y, Chao Y, Li C, Ge X, Yang W, Guo S. Rational design of mxene/1T-2H MoS₂-C nanohybrids for high-performance lithium-sulfur batteries. Adv Funct Mater. 2018;28(38):1707578. https://doi.org/10.1002/adfm.201707578.CrossRef

[86]

Cao Y, Lin Y, Wu J, Huang X, Pei Z, Zhou J, Wang G. Two-dimensional MoS₂ for Li-S batteries: structural design and electronic modulation. Chemsuschem. 2020;13(6):1392. https://doi.org/10.1002/cssc.201902688.CrossRefPubMed

[87]

Liu W, Luo C, Zhang S, Zhang B, Ma J, Wang X, Liu W, Li Z, Yang QH, Lv W. Cobalt-doping of molybdenum disulfide for enhanced catalytic polysulfide conversion in lithium–sulfur batteries. ACS Nano. 2021;15(4):7491. https://doi.org/10.1021/acsnano.1c00896.CrossRefPubMed

[88]

Yang D, Li M, Zheng X, Han X, Zhang C, Jacas Biendicho J, Llorca J, Wang J, Hao H, Li J, Henkelman G, Arbiol J, Morante JR, Mitlin D, Chou S, Cabot A. Phase engineering of defective copper selenide toward robust lithium–sulfur batteries. ACS Nano. 2022;16(7):11102. https://doi.org/10.1021/acsnano.2c03788.CrossRefPubMed

[89]

Li R, Rao D, Zhou J, Wu G, Wang G, Zhu Z, Han X, Sun R, Li H, Wang C, Yan W, Zheng X, Cui P, Wu Y, Wang G, Hong X. Amorphization-induced surface electronic states modulation of cobaltous oxide nanosheets for lithium-sulfur batteries. Nat Commun. 2021;12(1):3102. https://doi.org/10.1038/s41467-021-23349-9.CrossRefPubMedPubMedCentralADS

[90]

Wang M, Sun Z, Ci H, Shi Z, Shen L, Wei C, Ding Y, Yang X, Sun J. Identifying the evolution of selenium-vacancy-modulated MoSe₂ precatalyst in lithium–sulfur chemistry. Angew Chem Int Ed. 2021;60(46):24558. https://doi.org/10.1002/anie.202109291.CrossRef

[91]

Hou W, Feng P, Guo X, Wang Z, Bai Z, Bai Y, Wang G, Sun K. Catalytic mechanism of oxygen vacancies in perovskite oxides for lithium–sulfur batteries. Adv Mater. 2022;34(26):2202222. https://doi.org/10.1002/adma.202202222.CrossRef

[92]

Ye Z, Jiang Y, Li L, Wu F, Chen R. Synergetic anion vacancies and dense heterointerfaces into bimetal chalcogenide nanosheet arrays for boosting electrocatalysis sulfur conversion. Adv Mater. 2022;34(13):2109552. https://doi.org/10.1002/adma.202109552.CrossRef

[93]

Guo D, Zhang Z, Xi B, Yu Z, Zhou Z, Chen XA. Ni₃S₂ anchored to N/S co-doped reduced graphene oxide with highly pleated structure as a sulfur host for lithium–sulfur batteries. J Mater Chem A. 2020;8(7):3834. https://doi.org/10.1039/c9ta12235d.CrossRef

[94]

Wang R, Yang J, Chen X, Zhao Y, Zhao W, Qian G, Li S, Xiao Y, Chen H, Ye Y, Zhou G, Pan F. Highly dispersed cobalt clusters in nitrogen-doped porous carbon enable multiple effects for high-performance Li–S battery. Adv Energy Mater. 2020;10(9):1903550. https://doi.org/10.1002/aenm.201903550.CrossRef

[95]

Xie Y, Cao J, Wang X, Li W, Deng L, Ma S, Zhang H, Guan C, Huang W. MOF-derived bifunctional Co_0.85Se nanoparticles embedded in N-doped carbon nanosheet arrays as efficient sulfur hosts for lithium–sulfur batteries. Nano Lett. 2021;21(20):8579. https://doi.org/10.1021/acs.nanolett.1c02037.CrossRefPubMedADS

[96]

Liu G, Luo D, Gao R, Hu Y, Yu A, Chen Z. A combined ordered macro-mesoporous architecture design and surface engineering strategy for high-performance sulfur immobilizer in lithium–sulfur batteries. Small. 2020;16(37):2001089. https://doi.org/10.1002/smll.202001089.CrossRef

[97]

Wang J, Li G, Luo D, Zhang Y, Zhao Y, Zhou G, Shui L, Wang X, Chen Z. Engineering the conductive network of metal oxide-based sulfur cathode toward efficient and longevous lithium–sulfur batteries. Adv Energy Mater. 2020;10(41):2002076. https://doi.org/10.1002/aenm.202002076.CrossRef

[98]

Xiao R, Yang S, Yu T, Hu T, Zhang X, Xu R, Wang Y, Guo X, Sun Z, Li F. A janus separator for inhibiting shuttle effect and lithium dendrite in lithium−sulfur batteries. Batter Supercaps. 2022;5(4):e202100389. https://doi.org/10.1002/batt.202100389.CrossRef

[99]

Xu R, Tang H, Zhou Y, Wang F, Wang H, Shao M, Li C, Wei Z. Enhanced catalysis of radical-to-polysulfide interconversion via increased sulfur vacancies in lithium–sulfur batteries. Chem Sci. 2022;13(21):6224. https://doi.org/10.1039/d2sc01353c.CrossRefPubMedPubMedCentral

[100]

Li Y, Wu H, Wu D, Wei H, Guo Y, Chen H, Li Z, Wang L, Xiong C, Meng Q, Liu H, Chan CK. High-density oxygen doping of conductive metal sulfides for better polysulfide trapping and Li₂S-S₈ redox kinetics in high areal capacity lithium–sulfur batteries. Adv Sci. 2022;9(17):2200840. https://doi.org/10.1002/advs.202200840.CrossRef

[101]

Shi Z, Sun Z, Cai J, Yang X, Wei C, Wang M, Ding Y, Sun J. Manipulating electrocatalytic Li₂S redox via selective dual-defect engineering for Li–S batteries. Adv Mater. 2021;33(43):2103050. https://doi.org/10.1002/adma.202103050.CrossRef

[102]

Yang JL, Cai DQ, Lin Q, Wang XY, Fang ZQ, Huang L, Wang ZJ, Hao XG, Zhao SX, Li J, Cao GZ, Lv W. Regulating the Li₂S deposition by grain boundaries in metal nitrides for stable lithium–sulfur batteries. Nano Energy. 2022;91:106669. https://doi.org/10.1016/j.nanoen.2021.106669.CrossRef

[103]

Wang T, Luo D, Zhang Y, Zhang Z, Wang J, Cui G, Wang X, Yu A, Chen Z. Hierarchically porous Ti₃C₂ MXene with tunable active edges and unsaturated coordination bonds for superior lithium–sulfur batteries. ACS Nano. 2021;15(12):19457. https://doi.org/10.1021/acsnano.1c06213.CrossRefPubMed

[104]

Xu HF, Hu RM, Zhang YZ, Yan HB, Zhu Q, Shang JX, Yang SB, Li B. Nano high-entropy alloy with strong affinity driving fast polysulfide conversion towards stable lithium sulfur batteries. Energy Storage Mater. 2021;43:212. https://doi.org/10.1016/j.ensm.2021.09.003.CrossRef

[105]

Shen Z, Zhang Z, Li M, Yuan Y, Zhao Y, Zhang S, Zhong C, Zhu J, Lu J, Zhang H. Rational design of a Ni₃N_0.85 electrocatalyst to accelerate polysulfide conversion in lithium–sulfur batteries. ACS Nano. 2020;14(6):6673. https://doi.org/10.1021/acsnano.9b09371.CrossRefPubMed

[106]

Zuo JH, Zhai PB, He QQ, Wang L, Chen Q, Gu XK, Yang ZL, Gong YJ. In-situ constructed three-dimensional MoS2-MoN heterostructure as the cathode of lithium-sulfur battery. Rare Met. 2022;41(5):1743. https://doi.org/10.1007/s12598-021-01910-1.CrossRef

[107]

Zhang J, Zhang J, Liu K, Yang T, Tian J, Wang C, Chen M, Wang X. Abundant defects-induced interfaces enabling effective anchoring for polysulfides and enhanced kinetics in lean electrolyte lithium–sulfur batteries. ACS Appl Mater Interfaces. 2019;11(50):46767. https://doi.org/10.1021/acsami.9b15638.CrossRefPubMed

[108]

Zhang X, Yu Z, Wang C, Gong Y, Ai B, Zhang L, Wang J. NC@CoP–Co₃O₄ composite as sulfur cathode for high-energy lithium–sulfur batteries. J Mater Sci. 2021;56(16):10030. https://doi.org/10.1007/s10853-021-05931-0.CrossRefADS

[109]

Wei Y, Zhang M, Yuan L, Wang B, Wang H, Wang Q, Zhang Y, Guo J, Wu H. A heterostructure-in-built multichambered host architecture enabled by topochemical self-nitridation for rechargeable lithiated silicon-polysulfide full battery. Adv Funct Mater. 2021;31(41):2103456. https://doi.org/10.1002/adfm.202103456.CrossRef

[110]

Ye Z, Jiang Y, Yang T, Li L, Wu F, Chen R. Engineering catalytic CoSe–ZnSe heterojunctions anchored on graphene aerogels for bidirectional sulfur conversion reactions. Adv Sci. 2021;9(1):2103456. https://doi.org/10.1002/advs.202103456.CrossRef

[111]

Zhang D, Luo Y, Liu J, Dong Y, Xiang C, Zhao C, Shu H, Hou J, Wang X, Chen M. ZnFe₂O₄–Ni₅P₄ mott–schottky heterojunctions to promote kinetics for advanced Li-S batteries. ACS Appl Mater Interfaces. 2022;14(20):23546. https://doi.org/10.1021/acsami.2c04734.CrossRef

[112]

Wang H, Wei Y, Wang G, Pu Y, Yuan L, Liu C, Wang Q, Zhang Y, Wu H. Selective nitridation crafted a high-density, carbon-free heterostructure host with built-in electric field for enhanced energy density Li–S batteries. Adv Sci. 2022;9(23):2201823. https://doi.org/10.1002/advs.202201823.CrossRef

[113]

Fang L, Feng Z, Cheng L, Winans RE, Li T. Design principles of single atoms on carbons for lithium–sulfur batteries. Small Methods. 2020;4(10):2000315. https://doi.org/10.1002/smtd.202000315.CrossRef

[114]

Zhang T, Walsh AG, Yu J, Zhang P. Single-atom alloy catalysts: Structural analysis, electronic properties and catalytic activities. Chem Soc Rev. 2021;50(1):569. https://doi.org/10.1039/d0cs00844c.CrossRefPubMed

[115]

Song Z, Zhang L, Doyle-Davis K, Fu X, Luo JL, Sun X. Recent advances in MOF-derived single atom catalysts for electrochemical applications. Adv Energy Mater. 2020;10(38):2001561. https://doi.org/10.1002/aenm.202001561.CrossRef

[116]

Wang F, Li J, Zhao J, Yang Y, Su C, Zhong YL, Yang QH, Lu J. Single-atom electrocatalysts for lithium sulfur batteries: progress, opportunities, and challenges. ACS Mater Lett. 2020;2(11):1450. https://doi.org/10.1021/acsmaterialslett.0c00396.CrossRef

[117]

Xie S, Chen X, Wang C, Lu YR, Chan TS, Chuang CH, Zhang J, Yan W, Jin S, Jin H, Wu X, Ji H. Role of the metal atom in a carbon-based single-atom electrocatalyst for Li–S redox reactions. Small. 2022;18(18):2200395. https://doi.org/10.1002/smll.202200395.CrossRef

[118]

Xiao R, Chen K, Zhang XY, Yang ZZ, Hu GJ, Sun ZH, Cheng HM, Li F. Single-atom catalysts for metal-sulfur batteries: current progress and future perspectives. J Energy Chem. 2021;54:452. https://doi.org/10.1016/j.jechem.2020.06.018.CrossRef

[119]

Liu G, Wang W, Zeng P, Yuan C, Wang L, Li H, Zhang H, Sun X, Dai K, Mao J, Li X, Zhang L. Strengthened d–p orbital hybridization through asymmetric coordination engineering of single-atom catalysts for durable lithium–sulfur batteries. Nano Lett. 2022;22(15):6366. https://doi.org/10.1021/acs.nanolett.2c02183.CrossRefPubMedADS

[120]

Xiao R, Yu T, Yang S, Chen K, Li Z, Liu Z, Hu T, Hu G, Li J, Cheng HM, Sun Z, Li F. Electronic structure adjustment of lithium sulfide by a single-atom copper catalyst toward high-rate lithium-sulfur batteries. Energy Storage Mater. 2022;51:890. https://doi.org/10.1016/j.ensm.2022.07.024.CrossRef

Titel: Structure engineering of cathode host materials for Li–S batteries
verfasst von: Jia-Jun Long
Hua Yu
Wen-Bo Liu
Publikationsdatum: 20.12.2023
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 4/2024
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-023-02378-x

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