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Biomass Conversion and Biorefinery

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15.01.2022 | Original Article

Fabrication of polyaniline-coated porous and fibrous nanocomposite with granular morphology using tea waste carbon for effective removal of rhodamine B dye from water samples

verfasst von: Parmeshwar Lal Meena, Jitendra Kumar Saini, Ajay Kumar Surela, Krishna Poswal, Lata Kumari Chhachhia

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 2/2024

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Abstract

Porous and fibrous nanocomposite with granular surface morphology was prepared by coating of polyaniline onto carbonized tea waste material employing a low cost and facile method. The as-synthesized nanofiber adsorbent was characterized using FTIR, Ultraviolet-visible, Thermal gravimetric analysis, BET, FESEM, HRTEM, and zeta potential analysis. The adsorption capacity of the fabricated adsorbent was evaluated against the removal of rhodamine B (RhB) dye from aqueous samples, 34.9315 mg/g adsorption capacity, and 95.21% of removal efficiency was observed. The results show that the prepared nanoadsorbent has well-defined porous and fibrous structure with granular morphology, a small average diameter (3–90nm), high specific surface area (50.1296 m² g⁻¹), and pore volume (0.2054 cm³ g⁻¹). The pore size distribution is ranged from 2 to 5nm. The adsorption kinetics is well described by a pseudo-second-order model, and the adsorption process is controlled jointly by the intra-particle diffusion and film diffusion process. The adsorption data were found to be well fitted with the Langmuir isotherm model. The thermodynamic study has revealed that the adsorption process is spontaneous, exothermic, and marked with the enhancement in randomness at the adsorbent–adsorbate interface. The positive value of ΔH° indicates that the physical forces are involved in the adsorption process. The polyaniline-coated tea waste carbon (PCTWC) nanocomposite has shown its high regeneration ability even after five consecutive cycles of adsorption-desorption.

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Titel: Fabrication of polyaniline-coated porous and fibrous nanocomposite with granular morphology using tea waste carbon for effective removal of rhodamine B dye from water samples
verfasst von: Parmeshwar Lal Meena
Jitendra Kumar Saini
Ajay Kumar Surela
Krishna Poswal
Lata Kumari Chhachhia
Publikationsdatum: 15.01.2022
Verlag: Springer Berlin Heidelberg
Erschienen in: Biomass Conversion and Biorefinery / Ausgabe 2/2024
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI: https://doi.org/10.1007/s13399-021-02267-2

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