Abrasive Wear of Compacted Graphite Cast Iron with Added Tin

Compacted graphite iron (CGI), also called vermicular graphite iron, is the most recent member of the cast iron family since the 1940s [1]. The vermicular-shaped (i.e., worm shaped) graphite is usually stubby with blunt edges, giving CGI a good combination of mechanical and physical properties that fall in between gray cast iron and ductile cast iron [2, 3]. CGI offers higher strength and stiffness than gray cast iron and easier casting and higher thermal conductivity than ductile cast iron [4]. Its unique thermal fatigue resistance makes it very suitable for certain applications such as internal combustion engines and brake components [5, 6].

In the modern transportation era of higher speeds and capacities, CGI is increasingly used in both the railway and automobile industries to replace gray cast iron for brake disks [7‐9]. During braking, the high kinetic energy of a vehicle is dissipated by frictional heat between the brake disk and brake pad [10]. Therefore, a brake disk undergoes repeated heating and cooling cycles under working conditions, making thermal fatigue a major concern for this component. Investigations of the thermal shock behavior of cast iron with different graphite shapes have shown that CGI has higher resistance to thermal cracking than both gray cast iron and ductile cast iron [1, 5].

Wear resistance is another important property for brake components, and a number of investigations have demonstrated that CGI also has advantages in wear resistance over gray cast iron [7, 9]. For instance, this property was demonstrated in studies of surface oxidation and subsurface features of CGI subjected to wear [11, 12]. Some efforts were made to enhance the wear resistance of CGI by induction hardening and laser cladding [13‐16]. These methods are rather hard to perform and greatly increased the cost of production. On the other hand, alloying is likely to be an easy way to improve the properties of CGI. Copper, titanium, and tin were found to be effective in increasing the strength of CGI by promoting the formation of pearlite [17‐19], but the influences of these alloys to the wear resistance of CGI is not fully understood.

The aim of this work was to study the effect of tin on the abrasive wear behavior of compacted graphite iron using a pin-on-disk test rig. Microstructure and worn surfaces were measured and analyzed to characterize the likely mechanisms of wear.

In this study, the microstructure and abrasive wear behavior of compacted graphite cast iron (CGI) was strongly influenced by the addition of Sn.

It is suggested by Fig. 1 that Sn decreases the graphite size in cast iron, which agrees with the findings of Shaban et al. [20]. The possible mechanism is likely to be the low melting point of Sn (231.9 °C). As a consequence, during solidification of molten iron, Sn will be one of the last components to solidify and will tend to stay at the front edge of the unsolidified melting, thereby hindering the growth of graphite. Figure 2 shows that the addition of Sn promotes the generation of pearlite in vermicular cast iron. Usually, during eutectic reaction, carbon atoms continuously move from austenite to graphite and leave a C-lack area around graphite, which will finally become ferrite. Lyu et al. [19] demonstrated that Sn tends to exist at the boundary between graphite and austenite during eutectic reaction, obstructing the C transfer. Consequently, the areas close to vermicular graphite contained enough C atoms to form pearlite.

With respect to the abrasive wear test results (Table 2), it appears that the addition of Sn into CGI decreases wear loss, which could result from improvement in the microstructure (a reduction in graphite size and increase in pearlite). It is widely accepted that the properties of cast iron largely depend on the graphite morphology and matrix constitutions [1]. Graphite in cast iron yields a very low strength (~ 20 MPa), much lower than a typical strength value of the matrix. Usually, the graphite is considered to be tiny inclusions in the matrix and a smaller size of graphite tends to improve the properties of cast iron. In the current study, the CGI–Sn specimen had a smaller average size of graphite compared with the CGI specimen, indicating a higher abrasive wear resistance.

In addition to the graphite morphology, matrix constitutions also contribute to the properties of cast iron. For example, the austempering process is widely used to produce bainite, which largely improves the strength and wear resistance of ductile cast iron [21]. The properties of gray cast iron and compacted graphite iron depend more on the graphite than on the matrix, making gray cast iron and compacted graphite iron to be usually used as-cast. Therefore, techniques that can increase the amount of pearlite in the cast iron matrix are of great interest in the foundry industry. Alloying additions are considered to be effective for affecting the matrix structure [6], and copper, molybdenum, and other elements have succeeded in altering the as-cast matrix from ferrite to pearlite [1], improving the mechanical properties and wear resistance. Sn added as the alloying element also promoted the generation of pearlite (Fig. 2), resulting in an increase in wear resistance (Table 2).

From the worn surfaces shown in Fig. 3, one can notice a clue to the improved wear resistance of CGI–Sn. In Fig. 3a, a severe abrasive wear morphology with a large number of plowing and fragmentation features can be seen. In contrast, the worn morphology of the CGI–Sn specimen in Fig. 3c indicates mild abrasive wear with cutting features on smoother surface. A large missing fragment can be seen in Fig. 3b (worn surface of CGI at high magnification). This fragment is likely to be a piece of vermicular graphite coupled with some ferrite around it (compare with the unworn matrix in Fig. 2a). Ferrite is weaker than pearlite, and it can adhere strongly to graphite. Graphite, because it is the weakest part in cast iron, has a high chance of getting sheared off during relative sliding. In the same process, a large amount of ferrite is also peeled from the surface, resulting in a high wear loss of CGI. At the same magnification, similar kinds of fragments were not found in CGI–Sn specimen (Fig. 3d). A small piece of peeling is likely to be seen on the worn surface (Fig. 3d), which looks like a piece of vermicular graphite without matrix structure around it. In Fig. 2b, one can notice that ferrite around vermicular graphite disappeared when Sn was added to CGI. During relative sliding, graphite was preferentially peeled off due to its low strength and weak adhesive force with the matrix structure, while pearlite remains on the surface because of its high shear strength. This appears to be the likely mechanism of the decreased wear loss of CGI–Sn specimen compared with CGI specimen (Table 2).