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Erschienen in: Polymer Bulletin 3/2010

01.02.2010 | Original Paper

SBS nanocomposites as toughening agent for polypropylene

verfasst von: Patrícia A. da Silva, Marly M. Jacobi, Luciane K. Schneider, Ronilson V. Barbosa, Paulo A. Coutinho, Ricardo V. B. Oliveira, Raquel S. Mauler

Erschienen in: Polymer Bulletin | Ausgabe 3/2010

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Abstract

The toughening of polypropylene [PP] with styrene–butadiene–styrene rubber [SBS]/montmorillonite [MMT] nanocomposites was investigated with respect to morphological, thermal, and mechanical properties. The MMT/SBS nanocomposites were prepared in an internal mixer, using an epoxidized SBS [SBSe] to investigate its effect as a compatibilizer. The MMT/SBS nanocomposite was added to PP up to 10 wt%, aiming at material toughening. Transmission electron microscopy (TEM) revealed MMT induced dispersed-phase reductions when compared to typical PP/SBS blends. In addition, changes in the PP crystallization process were observed in the presence of the nanocomposite. Surprisingly, the use of nanofiller, combined with SBSe compatibilizer agent, increased the PP impact strength by about 60%, with no reduction in the tensile module.

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Literatur
1.
Zurück zum Zitat Hong CK, Kim MJ, Oh SH, Lee YS, Nah C (2008) Effects of polypropylene-g-(maleic anhydride/styrene) compatibilizer on mechanical and rheological properties of polypropylene/clay nanocomposites. J Ind Eng Chem 14:236 Hong CK, Kim MJ, Oh SH, Lee YS, Nah C (2008) Effects of polypropylene-g-(maleic anhydride/styrene) compatibilizer on mechanical and rheological properties of polypropylene/clay nanocomposites. J Ind Eng Chem 14:236
2.
Zurück zum Zitat Denac M, Smit I, Musil V (2005) Polypropylene/talc/SEBS (SEBS-g-MA) composites. Struct Compos Part A Appl Sci Manuf Compos: Part A 36:1094–1101CrossRef Denac M, Smit I, Musil V (2005) Polypropylene/talc/SEBS (SEBS-g-MA) composites. Struct Compos Part A Appl Sci Manuf Compos: Part A 36:1094–1101CrossRef
3.
Zurück zum Zitat Farahani RD, Ramazani ASA (2008) Melt preparation and investigation of properties of toughened Polyamide 66 with SEBS-g-MA and their nanocomposites. Mater Des 29:105–111 Farahani RD, Ramazani ASA (2008) Melt preparation and investigation of properties of toughened Polyamide 66 with SEBS-g-MA and their nanocomposites. Mater Des 29:105–111
4.
Zurück zum Zitat Paul DR, Robenson LM (2008) Polymer nanotechnology: nanocomposites. Polymer 49:3187–3204CrossRef Paul DR, Robenson LM (2008) Polymer nanotechnology: nanocomposites. Polymer 49:3187–3204CrossRef
5.
Zurück zum Zitat Calcagno CIW, Mariani CM, Teixeira SR, Mauler RS (2007) The effect of organic modifier of the clay on morphology and crystallization properties of PET nanocomposites. Polymer 48:966–974CrossRef Calcagno CIW, Mariani CM, Teixeira SR, Mauler RS (2007) The effect of organic modifier of the clay on morphology and crystallization properties of PET nanocomposites. Polymer 48:966–974CrossRef
6.
Zurück zum Zitat Santos KS, Liberman SA, Oviedo MAS, Mauler RS (2009) Optimization of the mechanical properties of polypropylene-based nanocomposite via the addition of a combination of organoclays. J Polym Sci: Part B Polym Phys 40:1199–1209 Santos KS, Liberman SA, Oviedo MAS, Mauler RS (2009) Optimization of the mechanical properties of polypropylene-based nanocomposite via the addition of a combination of organoclays. J Polym Sci: Part B Polym Phys 40:1199–1209
7.
Zurück zum Zitat Castel CD, Bianchi O, Oviedo MA, Liberman SA, Mauler RS, Oliveira RVB (2009) The influence of interfacial agents on the morphology and viscoelasticity of PP/MMT nanocomposites. Mater Sci Eng C 29:602–606 Castel CD, Bianchi O, Oviedo MA, Liberman SA, Mauler RS, Oliveira RVB (2009) The influence of interfacial agents on the morphology and viscoelasticity of PP/MMT nanocomposites. Mater Sci Eng C 29:602–606
8.
Zurück zum Zitat Alexandre M, Dubois P (2000) Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Mater Sci Eng R Rep 28:1–63CrossRef Alexandre M, Dubois P (2000) Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Mater Sci Eng R Rep 28:1–63CrossRef
9.
Zurück zum Zitat Arroyo M, López-Manchado MA, Herrero B (2003) Organo-montmorillonite as substitute of carbon black in natural rubber compounds. Polymer 44:2447–2453CrossRef Arroyo M, López-Manchado MA, Herrero B (2003) Organo-montmorillonite as substitute of carbon black in natural rubber compounds. Polymer 44:2447–2453CrossRef
10.
Zurück zum Zitat Dennis HR, Hunter DL, Chang D, Kim S, White JL, Cho JW, Paul DR (2001) Effect of melt processing conditions on the extent of exfoliation in organoclay-based nanocomposites. Polymer 42:9513CrossRef Dennis HR, Hunter DL, Chang D, Kim S, White JL, Cho JW, Paul DR (2001) Effect of melt processing conditions on the extent of exfoliation in organoclay-based nanocomposites. Polymer 42:9513CrossRef
11.
Zurück zum Zitat Zhang Z, Zhang L, Li Y, Xu H (2005) Styrene-butadiene-styrene/montmorillonite nanocomposites synthesized by anionic polymerization. J Appl Polym Sci 99:2273–2278CrossRef Zhang Z, Zhang L, Li Y, Xu H (2005) Styrene-butadiene-styrene/montmorillonite nanocomposites synthesized by anionic polymerization. J Appl Polym Sci 99:2273–2278CrossRef
12.
Zurück zum Zitat Arroyo M, López-Manchado MA, Valentin JL, Carretero J (2007) Morphology/behaviour relationship of nanocomposites based on natural rubber blends. Comp Sci Technol 67:1330CrossRef Arroyo M, López-Manchado MA, Valentin JL, Carretero J (2007) Morphology/behaviour relationship of nanocomposites based on natural rubber blends. Comp Sci Technol 67:1330CrossRef
13.
Zurück zum Zitat Sengupta R, Chakraborty S, Bandyopadhyay S, Dasgupta S, Mukhopadhyay R, Auddy K, Deuri AS (2007) A short review on rubber/clay nanocomposites with emphasis on mechanical properties. Polym Eng Sci 47:1956CrossRef Sengupta R, Chakraborty S, Bandyopadhyay S, Dasgupta S, Mukhopadhyay R, Auddy K, Deuri AS (2007) A short review on rubber/clay nanocomposites with emphasis on mechanical properties. Polym Eng Sci 47:1956CrossRef
14.
Zurück zum Zitat Ray SS, Pouliot S, Bousmina M, Utracki LA (2004) Role of organically modified layered silicate as an active interfacial modifier in immiscible polystyrene/polypropylene blends. Polymer 45:8403–8413CrossRef Ray SS, Pouliot S, Bousmina M, Utracki LA (2004) Role of organically modified layered silicate as an active interfacial modifier in immiscible polystyrene/polypropylene blends. Polymer 45:8403–8413CrossRef
15.
Zurück zum Zitat Hong JS, Namkung H, Ahn KH, Lee SJ, Kim C (2006) The role of organically modified layered silicate in the breakup and coalescence of droplets in PBT/PE blends. Polymer 47:3967–3975CrossRef Hong JS, Namkung H, Ahn KH, Lee SJ, Kim C (2006) The role of organically modified layered silicate in the breakup and coalescence of droplets in PBT/PE blends. Polymer 47:3967–3975CrossRef
16.
Zurück zum Zitat Khatua BB, Lee DJ, Kim HY, Kim JK (2004) Effect of organoclay platelets on morphology of Nylon-6 and Poly(ethylene-ran-propylene) rubber blends. Macromolecules 37:2454–2459CrossRef Khatua BB, Lee DJ, Kim HY, Kim JK (2004) Effect of organoclay platelets on morphology of Nylon-6 and Poly(ethylene-ran-propylene) rubber blends. Macromolecules 37:2454–2459CrossRef
17.
Zurück zum Zitat Si M, Araki T, Ade H, Kilcoyne ALD, Fisher R, Sokolov JC, Rafailovich MH (2006) Compatibilizing bulk polymer blends by using organoclays. Macromolecules 39:4793–4801CrossRef Si M, Araki T, Ade H, Kilcoyne ALD, Fisher R, Sokolov JC, Rafailovich MH (2006) Compatibilizing bulk polymer blends by using organoclays. Macromolecules 39:4793–4801CrossRef
18.
Zurück zum Zitat Halimatudahliana IH, Nasir M (2002) Morphological studies of uncompatibilized and compatibilized polystyrene/polypropylene blend. Polym Test 21:263CrossRef Halimatudahliana IH, Nasir M (2002) Morphological studies of uncompatibilized and compatibilized polystyrene/polypropylene blend. Polym Test 21:263CrossRef
19.
Zurück zum Zitat Halimatudahliana IH, Nasir M (2002) The effect of various compatibilizers on mechanical properties of polystyrene/polypropylene blend. Polym Test 21:163CrossRef Halimatudahliana IH, Nasir M (2002) The effect of various compatibilizers on mechanical properties of polystyrene/polypropylene blend. Polym Test 21:163CrossRef
20.
Zurück zum Zitat Sung YT, Han MS, Hyun JC, Kim WN, Lee HS (2003) Rheological properties and interfacial tension of polypropylene-poly(styrene-co-acrylonitrile) blend containing compatibilizer. Polymer 44:1681–1687CrossRef Sung YT, Han MS, Hyun JC, Kim WN, Lee HS (2003) Rheological properties and interfacial tension of polypropylene-poly(styrene-co-acrylonitrile) blend containing compatibilizer. Polymer 44:1681–1687CrossRef
21.
Zurück zum Zitat Macaúbas PHP, Demarquette NR (2001) Morphologies and interfacial tensions of immiscible polypropylene/polystyrene blends modified with triblock copolymers. Polymer 42:2543–2554CrossRef Macaúbas PHP, Demarquette NR (2001) Morphologies and interfacial tensions of immiscible polypropylene/polystyrene blends modified with triblock copolymers. Polymer 42:2543–2554CrossRef
22.
Zurück zum Zitat Li Y, Hu S, Sheng J (2007) Evolution of phase dimensions and interfacial morphology of polypropylene/polystyrene compatibilized blends during mixing. Eur Polym J 43:561–572CrossRef Li Y, Hu S, Sheng J (2007) Evolution of phase dimensions and interfacial morphology of polypropylene/polystyrene compatibilized blends during mixing. Eur Polym J 43:561–572CrossRef
23.
Zurück zum Zitat Souza AMC, Dermaquette NR (2002) Influence of coalescence and interfacial tension on the morphology of PP/HDPE compatibilized blends. Polymer 43:3959–3967CrossRef Souza AMC, Dermaquette NR (2002) Influence of coalescence and interfacial tension on the morphology of PP/HDPE compatibilized blends. Polymer 43:3959–3967CrossRef
24.
Zurück zum Zitat Jacobi MM, Santin CK, Schuster RHV (2004) Study of the epoxidation of polydienes rubbers II. Influence of microstructure on the epoxidation of BR with performic acid. Kautsch Gummi Kunstst 57:82 Jacobi MM, Santin CK, Schuster RHV (2004) Study of the epoxidation of polydienes rubbers II. Influence of microstructure on the epoxidation of BR with performic acid. Kautsch Gummi Kunstst 57:82
25.
Zurück zum Zitat Coutinho PA, Silva PA, Jacobi MM, Schneider LK, Barbosa RV, Cassinelli JRD, Mauler RS (2005) Processo para obtenção de material compósito em que uma nanocarga é aplicada a um polímero e material compósito resultante. Petroflex Indústria e Comércio S/A. INPI, Brazil, Patent no PI0701345-0 Coutinho PA, Silva PA, Jacobi MM, Schneider LK, Barbosa RV, Cassinelli JRD, Mauler RS (2005) Processo para obtenção de material compósito em que uma nanocarga é aplicada a um polímero e material compósito resultante. Petroflex Indústria e Comércio S/A. INPI, Brazil, Patent no PI0701345-0
26.
Zurück zum Zitat Amash A, Zugenmaier P (2000) Morphology and properties of isotropic and oriented samples of cellulose fibre-polypropylene composites. Polymer 41:1589–1596CrossRef Amash A, Zugenmaier P (2000) Morphology and properties of isotropic and oriented samples of cellulose fibre-polypropylene composites. Polymer 41:1589–1596CrossRef
27.
Zurück zum Zitat Han CD (1981) Multiphase flow in polymer processing. Academic Press, London Han CD (1981) Multiphase flow in polymer processing. Academic Press, London
28.
Zurück zum Zitat Kontopoulou M, Liu Y, Austin JR, Parent JS (2007) The dynamics of montmorillonite clay dispersion and morphology development in immiscible ethylene-propylene rubber/polypropylene blends. Polymer 48:4520–4528CrossRef Kontopoulou M, Liu Y, Austin JR, Parent JS (2007) The dynamics of montmorillonite clay dispersion and morphology development in immiscible ethylene-propylene rubber/polypropylene blends. Polymer 48:4520–4528CrossRef
29.
Zurück zum Zitat Wang K, Wang C, Li J, Su J, Zhang Q, Du R, Fu Q (2007) Effects of clay on phase morphology and mechanical properties in polyamide 6/EPDM-g-MA/organoclay ternary nanocomposites. Polymer 48:2144CrossRef Wang K, Wang C, Li J, Su J, Zhang Q, Du R, Fu Q (2007) Effects of clay on phase morphology and mechanical properties in polyamide 6/EPDM-g-MA/organoclay ternary nanocomposites. Polymer 48:2144CrossRef
30.
Zurück zum Zitat Li Y, Wei G, Sue H (2002) Hybrid self-assembled multilayer film formed by alternating layers of H4SiW12O40 and 1,10—diaminodecane (DAD). J Mater Sci 37:2447–2459CrossRef Li Y, Wei G, Sue H (2002) Hybrid self-assembled multilayer film formed by alternating layers of H4SiW12O40 and 1,10—diaminodecane (DAD). J Mater Sci 37:2447–2459CrossRef
31.
Zurück zum Zitat Balakrishnan S, Start PR, Raghavan D, Hudson SD (2005) The influence of clay and elastomer concentration on the morphology and fracture energy of preformed acrylic rubber dispersed clay filled epoxy nanocomposites. Polymer 46:11255–11262CrossRef Balakrishnan S, Start PR, Raghavan D, Hudson SD (2005) The influence of clay and elastomer concentration on the morphology and fracture energy of preformed acrylic rubber dispersed clay filled epoxy nanocomposites. Polymer 46:11255–11262CrossRef
32.
Zurück zum Zitat Kelnar I, Khunová V, Kotek J, Kaprálková L (2007) Effect of clay treatment on structure and mechanical behaviour of elastomer – containing polyamide 6 nanocomposite. Polymer 48:5332–5339CrossRef Kelnar I, Khunová V, Kotek J, Kaprálková L (2007) Effect of clay treatment on structure and mechanical behaviour of elastomer – containing polyamide 6 nanocomposite. Polymer 48:5332–5339CrossRef
33.
Zurück zum Zitat Contreras V, Cafiero M, Da Silva S, Rosales C, Perera R, Matos M (2006) Characterization and tensile properties of ternary blends with PA-6 nanocomposites. Polym Eng Sci 46:1111–1120CrossRef Contreras V, Cafiero M, Da Silva S, Rosales C, Perera R, Matos M (2006) Characterization and tensile properties of ternary blends with PA-6 nanocomposites. Polym Eng Sci 46:1111–1120CrossRef
34.
Zurück zum Zitat Wang Y, Zhang Q, Fu Q (2003) Compatibilization of immiscible poly(propylene)/polystyrene blends using clay. Macromol Rapid Commun 24:231CrossRef Wang Y, Zhang Q, Fu Q (2003) Compatibilization of immiscible poly(propylene)/polystyrene blends using clay. Macromol Rapid Commun 24:231CrossRef
35.
Zurück zum Zitat Zebarjad SM, Lazzeri A, Bagheri R, Reihani SMS, Frounch M (2003) Fracture mechanism under dynamic loading of elastomer-modified polypropylene. Mater Lett 57:2733–2741CrossRef Zebarjad SM, Lazzeri A, Bagheri R, Reihani SMS, Frounch M (2003) Fracture mechanism under dynamic loading of elastomer-modified polypropylene. Mater Lett 57:2733–2741CrossRef
36.
Zurück zum Zitat Jain S, Goossens H, Duin MV, Lemstra P (2005) Effect of in situ prepared silica nano-particles on non-isothermal crystallization of polypropylene. Polymer 46:8805–8818 Jain S, Goossens H, Duin MV, Lemstra P (2005) Effect of in situ prepared silica nano-particles on non-isothermal crystallization of polypropylene. Polymer 46:8805–8818
Metadaten
Titel
SBS nanocomposites as toughening agent for polypropylene
verfasst von
Patrícia A. da Silva
Marly M. Jacobi
Luciane K. Schneider
Ronilson V. Barbosa
Paulo A. Coutinho
Ricardo V. B. Oliveira
Raquel S. Mauler
Publikationsdatum
01.02.2010
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 3/2010
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-009-0159-3

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