Skip to main content
Erschienen in: Polymer Bulletin 8/2013

01.08.2013 | Original Paper

The synthesis of shape-controlled polypyrrole/graphene and the study of its capacitance properties

verfasst von: Xiaomiao Feng, Zhenzhen Yan, Ruimei Li, Xingfen Liu, Wenhua Hou

Erschienen in: Polymer Bulletin | Ausgabe 8/2013

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Polypyrrole (PPy)/graphene nainocomposite was prepared by methyl orange (MO) reactive template. By changing the amount of MO, the morphology of PPy can be controlled to range from nanoparticle to nanowire. Transmission electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and X-ray diffraction results demonstrated that the composites were successfully synthesized. The different morphologies of PPy/graphene nanocomposites had certain effects on the supercapacitor performance. The experimental results showed that the capacitance of PPy (nanoparticle)/graphene was higher than that of PPy (nanowire)/graphene. As a model, PPy (nanoparticle)/graphene was used to construct a supercapacitor. By changing the amount of pyrrole monomer, the performance of the supercapacitor prepared from different PPy content was studied in detail.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Cui X, Li CM, Zang J, Zhou Q, Gan Y, Bao H, Guo J, Lee VS, Moochhala SM (2007) Biocatalytic Generation of ppy-enzyme-CNT nanocomposite: from network assembly to film growth. J Phys Chem C 111:2025–2031CrossRef Cui X, Li CM, Zang J, Zhou Q, Gan Y, Bao H, Guo J, Lee VS, Moochhala SM (2007) Biocatalytic Generation of ppy-enzyme-CNT nanocomposite: from network assembly to film growth. J Phys Chem C 111:2025–2031CrossRef
2.
Zurück zum Zitat Liew SY, Thielemans W, Walsh DA (2010) Electrochemical capacitance of nanocomposite polypyrrole/cellulose films. J Phys Chem C 114:17926–17933CrossRef Liew SY, Thielemans W, Walsh DA (2010) Electrochemical capacitance of nanocomposite polypyrrole/cellulose films. J Phys Chem C 114:17926–17933CrossRef
3.
Zurück zum Zitat Feng XM, Sun ZZ, Hou WH, Zhu JJ (2007) Synthesis of functional polypyrrole/prussian blue and polypyrrole/Ag composite microtubes by using a reactive template. Nanotechnology 18:195603(1–7) Feng XM, Sun ZZ, Hou WH, Zhu JJ (2007) Synthesis of functional polypyrrole/prussian blue and polypyrrole/Ag composite microtubes by using a reactive template. Nanotechnology 18:195603(1–7)
4.
Zurück zum Zitat Wang J, Dai J, Yarlagadda T (2005) Carbon nanotube—conducting-Polymer composite nanowires. Langmuir 21:9–12CrossRef Wang J, Dai J, Yarlagadda T (2005) Carbon nanotube—conducting-Polymer composite nanowires. Langmuir 21:9–12CrossRef
5.
Zurück zum Zitat Gu Z, Li C, Wang G, Zhuang L, Li X, Wang W, Jin S (2010) Synthesis and characterization of polypyrrole/graphite oxide composite by in situ emulsion polymerization. J Polym Sci Pol Phys 48:1329–1335CrossRef Gu Z, Li C, Wang G, Zhuang L, Li X, Wang W, Jin S (2010) Synthesis and characterization of polypyrrole/graphite oxide composite by in situ emulsion polymerization. J Polym Sci Pol Phys 48:1329–1335CrossRef
6.
Zurück zum Zitat Yang X, Zhu Z, Dai T, Lu Y (2005) Facile fabrication of functional polypyrrole nanotubes via a reactive self-degraded template. Macromol Rapid Com 26:1736–1740CrossRef Yang X, Zhu Z, Dai T, Lu Y (2005) Facile fabrication of functional polypyrrole nanotubes via a reactive self-degraded template. Macromol Rapid Com 26:1736–1740CrossRef
7.
Zurück zum Zitat Bagheri H, Ayazi Z (2011) Polypyrrole nanowires network for convenient and highly efficient microextraction in packed syringe. Anal Methods 3:2630–2636CrossRef Bagheri H, Ayazi Z (2011) Polypyrrole nanowires network for convenient and highly efficient microextraction in packed syringe. Anal Methods 3:2630–2636CrossRef
8.
Zurück zum Zitat Zhang L, Liu P, Ju L, Wang L, Zhao S (2010) Polypyrrole nanocapsules via interfacial polymerization. Macromol Res 18:648–652CrossRef Zhang L, Liu P, Ju L, Wang L, Zhao S (2010) Polypyrrole nanocapsules via interfacial polymerization. Macromol Res 18:648–652CrossRef
9.
Zurück zum Zitat Sahoo NG, Jung YC, So HH, Cho JW (2007) Polypyffole coated carbon nanotubes: synthesis, characterization, and enhanced electrical properties. Synth Met 157:374–379CrossRef Sahoo NG, Jung YC, So HH, Cho JW (2007) Polypyffole coated carbon nanotubes: synthesis, characterization, and enhanced electrical properties. Synth Met 157:374–379CrossRef
10.
Zurück zum Zitat Yang X, Li L (2010) Polypyrrole nanofibers synthesized via reactive template approach and their NH3 gas sensitivity. Synth Met 160:1365–1367CrossRef Yang X, Li L (2010) Polypyrrole nanofibers synthesized via reactive template approach and their NH3 gas sensitivity. Synth Met 160:1365–1367CrossRef
11.
Zurück zum Zitat Zhao Y, Zhan L, Tian J, Nie S, Ning Z (2011) Enhanced electrocatalytic oxidation of methanol on Pd/polypyrrole-graphene in alkaline medium. Electrochim Acta 56:1967–1972CrossRef Zhao Y, Zhan L, Tian J, Nie S, Ning Z (2011) Enhanced electrocatalytic oxidation of methanol on Pd/polypyrrole-graphene in alkaline medium. Electrochim Acta 56:1967–1972CrossRef
12.
Zurück zum Zitat Zhang D, Zhang X, Chen Y, Yu P, Wang C, Ma Y (2011) Enhanced capacitance and rate capability of graphene/polypyrrole composite as electrode material for supercapacitors. J Power Sour 196:5990–5996CrossRef Zhang D, Zhang X, Chen Y, Yu P, Wang C, Ma Y (2011) Enhanced capacitance and rate capability of graphene/polypyrrole composite as electrode material for supercapacitors. J Power Sour 196:5990–5996CrossRef
13.
Zurück zum Zitat Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339CrossRef Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339CrossRef
14.
Zurück zum Zitat Nakada K, Fujita M (1996) Edge state in graphene ribbons: nanometer size effect and edge shape dependence. Phys Rev B 54:17954–17961CrossRef Nakada K, Fujita M (1996) Edge state in graphene ribbons: nanometer size effect and edge shape dependence. Phys Rev B 54:17954–17961CrossRef
15.
Zurück zum Zitat Han YQ, Hao LA, Zhang XG (2010) Preparation and electrochemical performances of graphite oxide/polypyrrole composites. Synth Met 160:2336–2340CrossRef Han YQ, Hao LA, Zhang XG (2010) Preparation and electrochemical performances of graphite oxide/polypyrrole composites. Synth Met 160:2336–2340CrossRef
16.
Zurück zum Zitat Du D, Ye XX, Cai J, Liu JA, Zhang AD (2010) Acetylcholinesterase biosensor design based on carbon nanotube-encapsulated polypyrrole and polyaniline copolymer for amperometric detection of organophosphates. Biosens Bioelectron 25:2503–2508CrossRef Du D, Ye XX, Cai J, Liu JA, Zhang AD (2010) Acetylcholinesterase biosensor design based on carbon nanotube-encapsulated polypyrrole and polyaniline copolymer for amperometric detection of organophosphates. Biosens Bioelectron 25:2503–2508CrossRef
17.
Zurück zum Zitat Whitby RLD, Korobeinyk A, Mikhalovsky SV, Fukuda T, Maekawa T (2011) Morphological effects of single-layer graphene oxide in the formation of covalently bonded polypyrrole composites using intermediate diisocyanate chemistry. J Nanopart Res 13:4829–4837CrossRef Whitby RLD, Korobeinyk A, Mikhalovsky SV, Fukuda T, Maekawa T (2011) Morphological effects of single-layer graphene oxide in the formation of covalently bonded polypyrrole composites using intermediate diisocyanate chemistry. J Nanopart Res 13:4829–4837CrossRef
18.
Zurück zum Zitat Seredych M, Tamashausky T, Bandosz TJ (2010) Graphite oxides obtained from porous graphite: the role of surface chemistry and texture in ammonia retention at ambient conditions. Adv Funct Mater 20:1670–1679CrossRef Seredych M, Tamashausky T, Bandosz TJ (2010) Graphite oxides obtained from porous graphite: the role of surface chemistry and texture in ammonia retention at ambient conditions. Adv Funct Mater 20:1670–1679CrossRef
19.
Zurück zum Zitat Huang Y, Qin Y, Zhou Y, Niu H, Yu ZZ, Dong JY (2010) Polypropylene/graphene oxide nanocomposites prepared by in situ ziegler-natta polymerization. Chem Mater 22:4096–4102CrossRef Huang Y, Qin Y, Zhou Y, Niu H, Yu ZZ, Dong JY (2010) Polypropylene/graphene oxide nanocomposites prepared by in situ ziegler-natta polymerization. Chem Mater 22:4096–4102CrossRef
20.
Zurück zum Zitat Chen S, Zhu J, Wang X (2010) One-Step Synthesis of graphene–cobalt hydroxide nanocomposites and their electrochemical properties. J Phys Chem C 114:11829–11834CrossRef Chen S, Zhu J, Wang X (2010) One-Step Synthesis of graphene–cobalt hydroxide nanocomposites and their electrochemical properties. J Phys Chem C 114:11829–11834CrossRef
21.
Zurück zum Zitat Zhang LL, Zhao S, Tian XN, Zhao XS (2010) Layered graphene oxide nanostructures with sandwiched conducting polymers as supercapacitor electrodes. Langmuir 26:17624–17628CrossRef Zhang LL, Zhao S, Tian XN, Zhao XS (2010) Layered graphene oxide nanostructures with sandwiched conducting polymers as supercapacitor electrodes. Langmuir 26:17624–17628CrossRef
22.
Zurück zum Zitat Wang Y, Shi Z, Huang Y, Ma Y, Wang C, Chen M (2009) Supercapacitor devices based on graphene materials. J Phys Chem C 113:13103–13107CrossRef Wang Y, Shi Z, Huang Y, Ma Y, Wang C, Chen M (2009) Supercapacitor devices based on graphene materials. J Phys Chem C 113:13103–13107CrossRef
23.
Zurück zum Zitat Mi H, Zhang X, Ye X, Yang S (2008) Preparation and enhanced capacitance of core-shell polypyrrole/polyaniline composite electrode for supercapacitors. J Power Sour 176:403–409CrossRef Mi H, Zhang X, Ye X, Yang S (2008) Preparation and enhanced capacitance of core-shell polypyrrole/polyaniline composite electrode for supercapacitors. J Power Sour 176:403–409CrossRef
24.
Zurück zum Zitat Jua YW, Choi GR, Jung HR, Lee W (2008) Electrochemical properties of electrospun PAN/MWCNT carbon nanofibers electrodes coated with polypyrrole. Electrochim Acta 53:5796–5803CrossRef Jua YW, Choi GR, Jung HR, Lee W (2008) Electrochemical properties of electrospun PAN/MWCNT carbon nanofibers electrodes coated with polypyrrole. Electrochim Acta 53:5796–5803CrossRef
25.
Zurück zum Zitat Wang ZP, Yusop Z, Ghosh P, Hayashi Y, Tanemura M (2011) Formation of carbon nanostructures containing single-crystalline cobalt carbides by ion irradiation method. Appl Surf Sci 257:3168–3173CrossRef Wang ZP, Yusop Z, Ghosh P, Hayashi Y, Tanemura M (2011) Formation of carbon nanostructures containing single-crystalline cobalt carbides by ion irradiation method. Appl Surf Sci 257:3168–3173CrossRef
26.
Zurück zum Zitat Zhang K, Zhang LL, Zhao XS, Wu J (2010) Graphene/polyaniline nanofiber composites as supercapacitor electrodes. Chem Mater 22:1392–1401CrossRef Zhang K, Zhang LL, Zhao XS, Wu J (2010) Graphene/polyaniline nanofiber composites as supercapacitor electrodes. Chem Mater 22:1392–1401CrossRef
27.
Zurück zum Zitat Hou H, Ge JJ, Zeng J, Li Q, Reneker DH, Greiner A, Cheng SZD (2005) Electrospun polyacrylonitrile nanofibers containing a high concentration of well-aligned multiwall carbon nanotubes. Chem Mater 17:967–973CrossRef Hou H, Ge JJ, Zeng J, Li Q, Reneker DH, Greiner A, Cheng SZD (2005) Electrospun polyacrylonitrile nanofibers containing a high concentration of well-aligned multiwall carbon nanotubes. Chem Mater 17:967–973CrossRef
Metadaten
Titel
The synthesis of shape-controlled polypyrrole/graphene and the study of its capacitance properties
verfasst von
Xiaomiao Feng
Zhenzhen Yan
Ruimei Li
Xingfen Liu
Wenhua Hou
Publikationsdatum
01.08.2013
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 8/2013
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-013-0952-x

Weitere Artikel der Ausgabe 8/2013

Polymer Bulletin 8/2013 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.