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Erschienen in: Polymer Bulletin 2/2014

01.02.2014 | Original Paper

Preliminary swelling and dye sorption studies of acrylamide/4-styrenesulfonic acid sodium salt copolymers and semi-interpenetrating polymer networks composed of gelatin and/or PEG

verfasst von: Semiha Kundakcı, Erdener Karadağ

Erschienen in: Polymer Bulletin | Ausgabe 2/2014

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Abstract

Semi-IPN hydrogels based gelatin (GEL) and/or poly (ethylene glycol) (PEG) were prepared with acrylamide (AAm) and 4-styrenesulfonic acid sodium salt, (SSS) as a water adsorbent for cationic dye (methyl violet, MV) sorption. For this, chemically crosslinked copolymer of AAm/SSS copolymer with GEL and/or PEG were prepared by polymerization of aqueous solution of AAm and SSS using ammonium persulfate (APS)/N,N,N′,N′-tetramethylethylenediamine (TEMED) as redox initiating pair in presence of poly(ethylene glycol)diacrylate (PEGDA) as crosslinker. FT-IR analysis was used to identify the presence of different repeating units in the semi-IPNs. Surface morphology was characterized by scanning electron microscopy (SEM). Some swelling and diffusion characteristics were calculated for different semi-IPNs and hydrogels prepared under various formulations. Water uptake, and dye sorption properties of the crosslinked polymeric systems such as AAm/SSS, AAm/GEL/SSS, AAm/PEG/SSS and AAm/GEL/PEG/SSS hydrogel systems were investigated as a function of chemical composition of the hydrogels. MV have used in sorption studies.

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Metadaten
Titel
Preliminary swelling and dye sorption studies of acrylamide/4-styrenesulfonic acid sodium salt copolymers and semi-interpenetrating polymer networks composed of gelatin and/or PEG
verfasst von
Semiha Kundakcı
Erdener Karadağ
Publikationsdatum
01.02.2014
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 2/2014
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-013-1065-2

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