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Erschienen in: Polymer Bulletin 6/2018

11.08.2017 | Original Paper

Synthesis, characterization, and Schottky diode applications of low-cost new chitin derivatives

verfasst von: Önder Aksoy, İlhan Uzun, Giray Topal, Yusuf Selim Ocak, Ömer Çelik, Derya Batibay

Erschienen in: Polymer Bulletin | Ausgabe 6/2018

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Abstract

In this study, low-cost two new chitin derivatives were first synthesized. Products formed in the consequence of the reaction of chitin with 4-nitrobenzoyl chloride and 3,5-dinitrobenzoyl chloride were named C4NC and C35DC, respectively. Then, C4NC and C35DC were characterized by FTIR and 13C CP-MAS solid-state NMR spectroscopies and X-ray powder diffraction technique. Surface topography and composition of C4NC and C35DC with a scanning electron microscope were investigated. Mass loss in C4NC and C35DC with thermogravimetric analysis method was determined as a function of increasing temperature. Endothermic and exothermic transitions in C4NC and C35DC were investigated with differential thermal analysis and differential scanning calorimetry techniques. Later on, charge carrier density, hole mobility, and electrical conductivity values of C4NC and C35DC were determined. Besides, Schottky diodes of C4NC and C35DC were constructed, and several parameters related to these diodes were determined. Finally, the sensitivity of these diodes to light was studied.

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Literatur
1.
Zurück zum Zitat Muzzarelli RAA (1977) Chitin. Pergamon Press, Oxford Muzzarelli RAA (1977) Chitin. Pergamon Press, Oxford
2.
Zurück zum Zitat Akkaya G, Uzun İ, Güzel F (2007) Kinetics of the adsorption of reactive dyes by chitin. Dyes Pigments 73:168–177CrossRef Akkaya G, Uzun İ, Güzel F (2007) Kinetics of the adsorption of reactive dyes by chitin. Dyes Pigments 73:168–177CrossRef
3.
Zurück zum Zitat Akkaya G, Uzun İ, Güzel F (2009) Adsorption of some highly toxic dyestuffs from aqueous solution by chitin and its synthesized derivatives. Desalination 249:1115–1123CrossRef Akkaya G, Uzun İ, Güzel F (2009) Adsorption of some highly toxic dyestuffs from aqueous solution by chitin and its synthesized derivatives. Desalination 249:1115–1123CrossRef
4.
Zurück zum Zitat Kim SK (2011) Chitin, chitosan, oligosaccharides and their derivatives: biological activities and applications. CRC Press, Boca Raton Kim SK (2011) Chitin, chitosan, oligosaccharides and their derivatives: biological activities and applications. CRC Press, Boca Raton
5.
Zurück zum Zitat Kim SS, Kim SJ, Moon YD, Lee YM (1994) Thermal characteristics of chitin and hydroxypropyl chitin. Polymer 35:3212–3216CrossRef Kim SS, Kim SJ, Moon YD, Lee YM (1994) Thermal characteristics of chitin and hydroxypropyl chitin. Polymer 35:3212–3216CrossRef
6.
Zurück zum Zitat Park IK, Park YH (2001) Preparation and structural characterization of water-soluble o-hydroxypropyl chitin derivatives. J Appl Polym Sci 80:2624–2632CrossRef Park IK, Park YH (2001) Preparation and structural characterization of water-soluble o-hydroxypropyl chitin derivatives. J Appl Polym Sci 80:2624–2632CrossRef
7.
Zurück zum Zitat Kittur FS, Prashanth KVH, Sankar KU, Tharanathan RN (2002) Characterization of chitin, chitosan and their carboxymethyl derivatives by differential scanning calorimetry. Carbohydr Polym 49:185–193CrossRef Kittur FS, Prashanth KVH, Sankar KU, Tharanathan RN (2002) Characterization of chitin, chitosan and their carboxymethyl derivatives by differential scanning calorimetry. Carbohydr Polym 49:185–193CrossRef
8.
Zurück zum Zitat Vasnev VA, Tarasov AI, Markova GD, Vinogradova SV, Garkusha OG (2006) Synthesis and properties of acylated chitin and chitosan derivatives. Carbohydr Polym 64:184–189CrossRef Vasnev VA, Tarasov AI, Markova GD, Vinogradova SV, Garkusha OG (2006) Synthesis and properties of acylated chitin and chitosan derivatives. Carbohydr Polym 64:184–189CrossRef
9.
Zurück zum Zitat Rao V, Ramaprasad AT (2007) Optical and conductivity studies of pseudo-doped chitin-polyaniline blend. J Appl Polym Sci 106:309–313CrossRef Rao V, Ramaprasad AT (2007) Optical and conductivity studies of pseudo-doped chitin-polyaniline blend. J Appl Polym Sci 106:309–313CrossRef
10.
Zurück zum Zitat Sugimoto M, Kawahara M, Teramoto Y, Nishio Y (2010) Synthesis of acyl chitin derivatives and miscibility characterization of their blends with poly(ε-caprolactone). Carbohydr Polym 79:948–954CrossRef Sugimoto M, Kawahara M, Teramoto Y, Nishio Y (2010) Synthesis of acyl chitin derivatives and miscibility characterization of their blends with poly(ε-caprolactone). Carbohydr Polym 79:948–954CrossRef
11.
Zurück zum Zitat Bhatt LR, Kim BM, Hyun K, Kwak GB, Lee CH, Chai KY (2011) Preparation and characterization of chitin benzoic acid esters. Molecules 16:3029–3036CrossRefPubMed Bhatt LR, Kim BM, Hyun K, Kwak GB, Lee CH, Chai KY (2011) Preparation and characterization of chitin benzoic acid esters. Molecules 16:3029–3036CrossRefPubMed
12.
Zurück zum Zitat Jindal DK, Singh SK, Kumar D (2013) Synthesis and characterization of some chitin co-(acetate/propionate) copolymers. Int J Pharm Biol Sci 3:260–265 Jindal DK, Singh SK, Kumar D (2013) Synthesis and characterization of some chitin co-(acetate/propionate) copolymers. Int J Pharm Biol Sci 3:260–265
13.
Zurück zum Zitat Uzun İ, Topal G (2013) Synthesis and physicochemical characterization of chitin derivatives. J Chem 2013:982638-1–982638-8CrossRef Uzun İ, Topal G (2013) Synthesis and physicochemical characterization of chitin derivatives. J Chem 2013:982638-1–982638-8CrossRef
14.
Zurück zum Zitat Uzun I, Celik O (2015) Physicochemical characterization and the comparison of chitin and chitin modified with maleic anhydride. Orient J Chem 31:619–627CrossRef Uzun I, Celik O (2015) Physicochemical characterization and the comparison of chitin and chitin modified with maleic anhydride. Orient J Chem 31:619–627CrossRef
15.
Zurück zum Zitat Akkılıç K, Aydın ME, Uzun İ, Kılıçoğlu T (2006) The calculation of electronic parameters of an Ag/chitin/n-Si Schottky barrier diode. Synth Met 156:958–962CrossRef Akkılıç K, Aydın ME, Uzun İ, Kılıçoğlu T (2006) The calculation of electronic parameters of an Ag/chitin/n-Si Schottky barrier diode. Synth Met 156:958–962CrossRef
16.
Zurück zum Zitat Akkılıç K, Uzun İ, Kılıçoğlu T (2007) The calculation of electronic properties of an Ag/chitosan/n-Si Schottky barrier diode. Synth Met 157:297–302CrossRef Akkılıç K, Uzun İ, Kılıçoğlu T (2007) The calculation of electronic properties of an Ag/chitosan/n-Si Schottky barrier diode. Synth Met 157:297–302CrossRef
17.
Zurück zum Zitat Ramaprasad AT, Rao V (2008) Electronic conduction mechanism in chitin-polyaniline blend. Synth Met 158:1047–1053CrossRef Ramaprasad AT, Rao V (2008) Electronic conduction mechanism in chitin-polyaniline blend. Synth Met 158:1047–1053CrossRef
18.
Zurück zum Zitat Akkılıç K, Yakuphanoğlu F (2008) Electrical and photovoltaic properties of a n-Si/chitosan/Ag photodiode. Microelectron Eng 85:1826–1830CrossRef Akkılıç K, Yakuphanoğlu F (2008) Electrical and photovoltaic properties of a n-Si/chitosan/Ag photodiode. Microelectron Eng 85:1826–1830CrossRef
19.
Zurück zum Zitat Jin J, Lee D, Im HG, Han YC, Jeong EG, Rolandi M, Choi KC, Bae BS (2016) Chitin nanofiber transparent paper for flexible green electronics. Adv Mater 28:5169–5175CrossRefPubMed Jin J, Lee D, Im HG, Han YC, Jeong EG, Rolandi M, Choi KC, Bae BS (2016) Chitin nanofiber transparent paper for flexible green electronics. Adv Mater 28:5169–5175CrossRefPubMed
20.
Zurück zum Zitat Segal L, Creely JJ, Martin AE Jr, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794CrossRef Segal L, Creely JJ, Martin AE Jr, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794CrossRef
21.
Zurück zum Zitat Jayakumar R, Tamura H (2008) Synthesis, characterization and thermal properties of chitin-g-poly(ε-caprolactone) copolymers by using chitin gel. Int J Biol Macromol 43:32–36CrossRefPubMed Jayakumar R, Tamura H (2008) Synthesis, characterization and thermal properties of chitin-g-poly(ε-caprolactone) copolymers by using chitin gel. Int J Biol Macromol 43:32–36CrossRefPubMed
22.
Zurück zum Zitat Stevens MP (1999) Polymer chemistry. Oxford University Press, New York Stevens MP (1999) Polymer chemistry. Oxford University Press, New York
23.
Zurück zum Zitat Rhoderick EH (1978) Metal-semiconductor contacts. Oxford University Press, New York Rhoderick EH (1978) Metal-semiconductor contacts. Oxford University Press, New York
24.
Zurück zum Zitat Ocak YS, Kulakci M, Kılıçoğlu T, Turan R, Akkılıç K (2009) Current-voltage and capacitance-voltage characteristics of a Sn/methylene blue/p-Si Schottky diode. Synth Met 159:1603–1607CrossRef Ocak YS, Kulakci M, Kılıçoğlu T, Turan R, Akkılıç K (2009) Current-voltage and capacitance-voltage characteristics of a Sn/methylene blue/p-Si Schottky diode. Synth Met 159:1603–1607CrossRef
25.
Zurück zum Zitat Norde H (1979) A modified forward I–V plot for Schottky diodes with high series resistance. J Appl Phys 50:5052–5053CrossRef Norde H (1979) A modified forward IV plot for Schottky diodes with high series resistance. J Appl Phys 50:5052–5053CrossRef
26.
Zurück zum Zitat Cheung SK, Cheung NW (1986) Extraction of Schottky diode parameters from forward current-voltage characteristics. Appl Phys Lett 49:85–87CrossRef Cheung SK, Cheung NW (1986) Extraction of Schottky diode parameters from forward current-voltage characteristics. Appl Phys Lett 49:85–87CrossRef
27.
Zurück zum Zitat Gupta RK, Al-Ghamdi AA, Al-Hartomi O, Hasar H, El-Tantawy F, Yakuphanoglu F (2012) Series resistance controlling photosensor of Ag/DNA/p-Si/Al diode. Synth Met 162:981–987CrossRef Gupta RK, Al-Ghamdi AA, Al-Hartomi O, Hasar H, El-Tantawy F, Yakuphanoglu F (2012) Series resistance controlling photosensor of Ag/DNA/p-Si/Al diode. Synth Met 162:981–987CrossRef
28.
Zurück zum Zitat El-Nahass MM, Abd-El-Rahman KF, Farag AAM, Darwish AAA (2005) Photovoltaic properties of NiPc/p-Si (organic/inorganic) heterojunctions. Org Electron 6:129–136CrossRef El-Nahass MM, Abd-El-Rahman KF, Farag AAM, Darwish AAA (2005) Photovoltaic properties of NiPc/p-Si (organic/inorganic) heterojunctions. Org Electron 6:129–136CrossRef
29.
Zurück zum Zitat Yakuphanoglu F (2007) Electronic and photovoltaic properties of Al/p-Si/copper phthalocyanine photodiode junction barrier. Sol Energy Mater Sol Cells 91:1182–1186CrossRef Yakuphanoglu F (2007) Electronic and photovoltaic properties of Al/p-Si/copper phthalocyanine photodiode junction barrier. Sol Energy Mater Sol Cells 91:1182–1186CrossRef
30.
Zurück zum Zitat Tombak A, Ocak YS, Asubay S, Kılıçoğlu T, Özkahraman F (2014) Fabrication and electrical properties of an organic-inorganic device based on Coumarin 30 dye. Mater Sci Semicond Process 24:187–192CrossRef Tombak A, Ocak YS, Asubay S, Kılıçoğlu T, Özkahraman F (2014) Fabrication and electrical properties of an organic-inorganic device based on Coumarin 30 dye. Mater Sci Semicond Process 24:187–192CrossRef
Metadaten
Titel
Synthesis, characterization, and Schottky diode applications of low-cost new chitin derivatives
verfasst von
Önder Aksoy
İlhan Uzun
Giray Topal
Yusuf Selim Ocak
Ömer Çelik
Derya Batibay
Publikationsdatum
11.08.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 6/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-2151-7

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