nach oben

Polymer Bulletin

Erschienen in:

29.11.2018 | Original Paper

PANINFs synthesized electrochemically as an electrode material for energy storage application

verfasst von: M. R. Waikar, A. A. Shaikh, R. G. Sonkawade

Erschienen in: Polymer Bulletin | Ausgabe 9/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

To obtain the highest performance of supercapacitive properties, it is necessary to discover an appropriate pair of electrode material and electrolyte. Supercapacitors have many applications in the industry over batteries, and our result shows the advantages of low-cost polyaniline (PANI) electrode material in supercapacitors. In the present work, the polyaniline nanofibers (PANINFs) thin films can be directly used as an electrode for supercapacitor. PANINFs electrode showed maximum specific capacitance of 633 F/g which exhibited at 5 mV/s scan rate, the specific energy density of 45.67 Wh/kg, the power density of 500 W/kg and the coulomb efficiency of 85.59% at 0.5 mA/cm² current density with 0.32 Ω equivalent series resistance (ESR) value. The capacitance value is obtained by electrochemical impedance spectroscopy (EIS) of 20.33 mF/cm² with the relaxation time of 0.14 s. Nanofibrous network (50–60 nm diameter) confirmed hydrophilic nature by wettability test. From the supercapacitive performance of PANINFs thin films conclude that they are promising for energy storage application.

Graphical abstract

Vorheriger Artikel Molecular structure of PANI and its homologue PANI–PEO2000 catalyzed by Maghnite-H+ (Algerian MMT): synthesis, characterization and physical and chemical properties

Nächster Artikel Polycarbonate-based thermoplastic polyurethane elastomers modified by DMPA

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Chen Y, Zhang X, Zhang D et al (2011) High performance supercapacitors based on reduced graphene oxide in aqueous and ionic liquid electrolytes. Carbon N Y 49:573–580. https://doi.org/10.1016/j.carbon.2010.09.060 CrossRef

Wang F, Sun S, Xu Y et al (2017) High performance asymmetric supercapacitor based on Cobalt Nickle Iron-layered double hydroxide/carbon nanofibres and activated carbon. Sci Rep 7:1–11. https://doi.org/10.1038/s41598-017-04807-1 CrossRefPubMedPubMedCentral

Anwar AW, Majeed A, Iqbal N et al (2015) Specific capacitance and cyclic stability of graphene based metal/metal oxide nanocomposites: a review. J Mater Sci Technol 31:699–707. https://doi.org/10.1016/j.jmst.2014.12.012 CrossRef

Ghouri ZK, Shaheer Akhtar M, Zahoor A et al (2015) High-efficiency super capacitors based on hetero-structured α-MnO₂ nanorods. J Alloys Compd 642:210–215. https://doi.org/10.1016/j.jallcom.2015.04.082 CrossRef

Wang G, Zhang L, Zhang J (2012) A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev 41:797–828. https://doi.org/10.1039/C1CS15060J CrossRefPubMed

Gupta V, Miura N (2006) Influence of the microstructure on the supercapacitive behavior of polyaniline/single-wall carbon nanotube composites. J Power Sources 157:616–620. https://doi.org/10.1016/j.jpowsour.2005.07.046 CrossRef

Giuliani E, Demetrio RFÆ, Soares AW (2008) Electrical properties of electrodeposited polyaniline nanotubes. J Mater Sci Mater Electron 19:457–462. https://doi.org/10.1007/s10854-007-9362-x CrossRef

Dhawale DS, Dubal DP, Jamadade VS et al (2010) Fuzzy nanofibrous network of polyaniline electrode for supercapacitor application. Synth Met 160:519–522. https://doi.org/10.1016/j.synthmet.2010.01.021 CrossRef

Chao Y, Chen S, Chen H et al (2018) Densely packed porous graphene film for high volumetric performance supercapacitor. Electrochim Acta 276:118–124. https://doi.org/10.1016/j.electacta.2018.04.156 CrossRef

10.

Zhang J, Ji X, Zhou J et al (2018) Pyridinium substituted BODIPY as NIR fluorescent probe for simultaneous sensing of hydrogen sulphide/glutathione and cysteine/homocysteine. Sens Actuators B Chem 257:1076–1082. https://doi.org/10.1016/j.snb.2017.10.133 CrossRef

11.

Ghouri ZK, Barakat NAM, Kim HY (2015) Influence of copper content on the electrocatalytic activity toward methanol oxidation of Co ‡ Cu y alloy nanoparticles-decorated CNFs. Sci Rep 5:1–12. https://doi.org/10.1063/1.109598 CrossRef

12.

Ghouri ZK, Barakat NAM, Park M et al (2015) Synthesis and characterization of Co/SrCO₃ nanorods-decorated carbon nanofibers as novel electrocatalyst for methanol oxidation in alkaline medium. Ceram Int 41:6575–6582. https://doi.org/10.1016/j.ceramint.2015.01.103 CrossRef

13.

Barakat NAM, El-Newehy M, Al-Deyab SS, Kim HY (2014) Cobalt/copper-decorated carbon nanofibers as novel non-precious electrocatalyst for methanol electrooxidation. Nanoscale Res Lett 9:1–10. https://doi.org/10.1186/1556-276X-9-2 CrossRef

14.

Khan Z, Khaled G, Saeed E, Barakat ANAM (2017) Applicable anode based on Co₃O₄–SrCO₃ heterostructure nanorods-incorporated CNFs with low-onset potential for DUFCs. Appl Nanosci 7:625–631. https://doi.org/10.1007/s13204-017-0601-z CrossRef

15.

Al-Meer S, Ghouri ZK, Elsaid K et al (2017) Engineering of magnetically separable ZnFe₂O₄@ TiO₂ nanofibers for dye-sensitized solar cells and removal of pollutant from water. J Alloys Compd 723:477–483. https://doi.org/10.1016/j.jallcom.2017.06.211 CrossRef

16.

Ghouri ZK, Barakat NAM, Kim HY et al (2016) Nano-engineered ZnO/CeO₂dots@CNFs for fuel cell application. Arab J Chem 9:219–228. https://doi.org/10.1016/j.arabjc.2015.05.024 CrossRef

17.

Ali Y, Kumar V, Sonkawade RG et al (2013) Two-step electrochemical synthesis of Au nanoparticles decorated polyaniline nanofiber. Vacuum 93:79–83. https://doi.org/10.1016/j.vacuum.2013.01.007 CrossRef

18.

Zhang H, Wang J, Wang Z et al (2009) Electrodeposition of polyaniline nanostructures: a lamellar structure. Synth Met 159:277–281CrossRef

19.

Prasad KR, Munichandraiah N (2002) Potentiodynamically deposited polyaniline on stainless steel. J Electrochem Soc 149:A1393. https://doi.org/10.1149/1.1509458 CrossRef

20.

Zhou KL, Wang H, Jiu JT et al (2018) Polyaniline films with modified nanostructure for bifunctional flexible multicolor electrochromic and supercapacitor applications. Chem Eng J 345:290–299. https://doi.org/10.1016/j.cej.2018.03.175 CrossRef

21.

Yuan Y, Zhu W, Du G et al (2018) Two-step method for synthesizing polyaniline with bimodal nanostructures for high performance supercapacitors. Electrochim Acta. https://doi.org/10.1016/j.electacta.2018.06.006 CrossRef

22.

Ghouri ZK, Barakat NAM, Saud PS et al (2016) Supercapacitors based on ternary nanocomposite of TiO₂&Pt@graphenes. J Mater Sci Mater Electron 27:3894–3900. https://doi.org/10.1007/s10854-015-4239-x CrossRef

23.

Ghouri ZK, Barakat NAM, Kim HY (2015) Synthesis and electrochemical properties of MnO₂ and co-decorated graphene as novel nanocomposite for electrochemical super capacitors application. Energy Environ Focus 4:34–39. https://doi.org/10.1166/eef.2015.1136 CrossRef

24.

Ghouri ZK, Barakat NAM, Alam AM et al (2015) Synthesis and characterization of Nitrogen-doped & CaCO₃-decorated reduced graphene oxide nanocomposite for electrochemical supercapacitors. Electrochim Acta 184:193–202. https://doi.org/10.1016/j.electacta.2015.10.069 CrossRef

25.

Zhang X, Meng X, Wang Q et al (2018) Preparation and electrochemical investigation of polyaniline nanowires for high performance supercapacitor. Mater Lett 217:312–315. https://doi.org/10.1016/j.matlet.2018.01.112 CrossRef

26.

Deshmukh PR, Shinde NM, Patil SV et al (2013) Supercapacitive behavior of polyaniline thin films deposited on fluorine doped tin oxide (FTO) substrates by microwave-assisted chemical route. Chem Eng J 223:572–577. https://doi.org/10.1016/j.cej.2013.03.056 CrossRef

27.

Ghouri ZK, Barakat NAM, Alam A-M et al (2015) Facile synthesis of Fe/CeO₂-doped CNFs and their capacitance behavior. Int J Electrochem Sci 10:2064–2071

28.

Sumboja A, Wang X, Yan J, Lee PS (2012) Nanoarchitectured current collector for high rate capability of polyaniline based supercapacitor electrode. Electrochim Acta 65:190–195. https://doi.org/10.1016/j.electacta.2012.01.046 CrossRef

29.

Dhawale DS, Salunkhe RR, Jamadade VS et al (2010) Hydrophilic polyaniline nanofibrous architecture using electrosynthesis method for supercapacitor application. Curr Appl Phys 10:904–909. https://doi.org/10.1016/j.cap.2009.10.020 CrossRef

30.

Li N, Xiao Y, Xu C et al (2013) Facile preparation of polyaniline nanoparticles via electrodeposition for supercapacitors. Int J Electrochem Sci 8:1181–1188

31.

Sazou D, Kourouzidou M, Pavlidou E (2007) Potentiodynamic and potentiostatic deposition of polyaniline on stainless steel: electrochemical and structural studies for a potential application to corrosion control. Electrochim Acta 52:4385–4397. https://doi.org/10.1016/j.electacta.2006.12.020 CrossRef

32.

Saini P, Choudhary V, Singh BP et al (2009) Polyaniline—MWCNT nanocomposites for microwave absorption and EMI shielding. Mater Chem Phys 113:919–926. https://doi.org/10.1016/j.matchemphys.2008.08.065 CrossRef

33.

Gupta V, Miura N (2005) Large-area network of polyaniline nanowires prepared by potentiostatic deposition process. Electrochem Commun 7:995–999. https://doi.org/10.1016/j.elecom.2005.07.008 CrossRef

34.

Jamadade VS, Dhawale DS, Lokhande CD (2010) Studies on electrosynthesized leucoemeraldine, emeraldine and pernigraniline forms of polyaniline films and their supercapacitive behavior. Synth Met 160:955–960. https://doi.org/10.1016/j.synthmet.2010.02.007 CrossRef

35.

Sowmya SY, Selvakumar M (2016) Supercapacitor studies of electrochemically synthesized multi-layered polyaniline on stainless steel substrate. Ionics (Kiel) 22:1729–1739. https://doi.org/10.1007/s11581-016-1705-2 CrossRef

36.

Buron CC, Lakard B, Monnin AF et al (2011) Elaboration and characterization of polyaniline films electrodeposited on tin oxides. Synth Met 161:2162–2169. https://doi.org/10.1016/j.synthmet.2011.08.021 CrossRef

37.

Li GR, Feng ZP, Zhong JH et al (2010) Electrochemical synthesis of polyaniline nanobelts with predominant electrochemical performances. Macromolecules 43:2178–2183. https://doi.org/10.1021/ma902317k CrossRef

38.

Shinde PA, Lokhande VC, Chodankar NR et al (2016) Enhanced electrochemical performance of monoclinic WO3 thin film with redox additive aqueous electrolyte. J Colloid Interface Sci 483:261–267. https://doi.org/10.1016/j.jcis.2016.08.011 CrossRefPubMed

39.

Deshmukh PR, Pusawale SN, Jamadade VS et al (2011) Microwave assisted chemical bath deposited polyaniline films for supercapacitor application. J Alloys Compd 509:5064–5069. https://doi.org/10.1016/j.jallcom.2010.12.009 CrossRef

40.

Dhawale DS, Vinu A, Lokhande CD (2011) Stable nanostructured polyaniline electrode for supercapacitor application. Electrochim Acta 56:9482–9487. https://doi.org/10.1016/j.electacta.2011.08.042 CrossRef

41.

Li T, Zhou Y, Liang B et al (2017) One–pot synthesis and electrochemical properties of polyaniline nanofibers through simply tuning acid–base environment of reaction medium. Electrochim Acta 249:33–42. https://doi.org/10.1016/j.electacta.2017.07.177 CrossRef

42.

Dubal DP, Fulari VJ, Lokhande CD (2012) Effect of morphology on supercapacitive properties of chemically grown β-Ni(OH)₂ thin films. Microporous Mesoporous Mater 151:511–516. https://doi.org/10.1016/j.micromeso.2011.08.034 CrossRef

43.

Dubal DP, Gund GS, Holze R et al (2013) Surfactant-assisted morphological tuning of hierarchical CuO thin films for electrochemical supercapacitors. Dalton Trans 42:6459. https://doi.org/10.1039/c3dt50275a CrossRefPubMed

44.

Jagadale AD, Dubal DP, Lokhande CD (2012) Electrochemical behavior of potentiodynamically deposited cobalt oxyhydroxide (CoOOH) thin films for supercapacitor application. Mater Res Bull 47:672–676. https://doi.org/10.1016/j.materresbull.2011.12.029 CrossRef

45.

Mujawar SH, Ambade SB, Battumur T et al (2011) Electropolymerization of polyaniline on titanium oxide nanotubes for supercapacitor application. Electrochim Acta 56:4462–4466. https://doi.org/10.1016/j.electacta.2011.02.043 CrossRef

46.

Chen W, Rakhi RB, Alshareef HN (2013) Facile synthesis of polyaniline nanotubes using reactive oxide templates for high energy density pseudocapacitors. J Mater Chem A 1:3315–3324. https://doi.org/10.1039/c3ta00499f CrossRef

47.

Kuang H, Cao Q, Wang X et al (2013) Influence of the reaction temperature on polyaniline morphology and evaluation of their performance as supercapacitor electrode. J Appl Polym Sci 130:3753–3758. https://doi.org/10.1002/app.39650 CrossRef

48.

Chen YC, Hsu YK, Lin YG et al (2011) Highly flexible supercapacitors with manganese oxide nanosheet/carbon cloth electrode. Electrochim Acta 56:7124–7130. https://doi.org/10.1016/j.electacta.2011.05.090 CrossRef

49.

Shinde PA, Lokhande AC, Chodankar NR et al (2017) Temperature dependent surface morphological modifications of hexagonal WO₃ thin films for high performance supercapacitor application. Electrochim Acta 224:397–404. https://doi.org/10.1016/j.electacta.2016.12.066 CrossRef

50.

Li T, Qin Z, Liang B et al (2015) Morphology-dependent capacitive properties of three nanostructured polyanilines through interfacial polymerization in various acidic media. Electrochim Acta 177:343–351. https://doi.org/10.1016/j.electacta.2015.03.169 CrossRef

Titel: PANINFs synthesized electrochemically as an electrode material for energy storage application
verfasst von: M. R. Waikar
A. A. Shaikh
R. G. Sonkawade
Publikationsdatum: 29.11.2018
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 9/2019
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-018-2634-1

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Graphical abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 9/2019

Ornidazole-loaded polyethylene glycol-based micron-level particles: influence of eutectic liquid on reservoir-type particle formation, drug entrapment efficiency and drug dissolution or release behavior

Molecular structure of PANI and its homologue PANI–PEO2000 catalyzed by Maghnite-H+ (Algerian MMT): synthesis, characterization and physical and chemical properties

Aminophosphonic groups grafted onto the structure of macroporous styrene–divinylbenzene copolymer: preparation and studies on the antimicrobial effect

Preparation and characterization of the acrylic latex-laminating adhesives applied in BOPP/PE composite films

Functionalized polyethersulfone as PES-NH2-metal oxide nanofilers for the detection of Y3+

Synthesis, characterization and rheological properties of epoxy monomers derived from bifunctional aromatic amines

Premium Partner

Marktübersichten