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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 15-16/2011

01.10.2011 | Original Contribution

Enhancement effect of filler network on isotactic polypropylene/carbon black composite melts

verfasst von: Shilin Huang, Zhengying Liu, Chaolu Yin, Yu Wang, Yongjuan Gao, Chen Chen, Mingbo Yang

Erschienen in: Colloid and Polymer Science | Ausgabe 15-16/2011

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Abstract

The linear viscoelastic behavior of the isotactic polypropylene/carbon black composite melt in which the filler particles can aggregate and form a filler network is investigated. With a higher filler loading the enhancement effect of the filler particles on the composite melt becomes more significant, which can be explained by the filler–polymer interaction and the hydrodynamic effect. When the filler network appears in the composite melt, the storage modulus exhibits another increasing mode, revealing that the percolating filler network has an additional enhancement effect on the composite melt. This is explained in a microscopic view of point with the consideration of the polymer shells on the filler particles.
Vorheriger Artikel Morphology and mechanical property of high-density polyethylene parts prepared by gas-assisted injection molding
Nächster Artikel The co-continuous morphology of biocompatible ethylene-vinyl acetate copolymers/poly(ε-caprolactone) blend: effect of viscosity ratio and vinyl acetate content

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Literatur
1.
Jouault N, Vallat P, Dalmas F, Said S, Jestin J, Boue F (2009) Well-dispersed fractal aggregates as filler in polymer–silica nanocomposites: long-range effects in rheology. Macromolecules 42:2031–2040CrossRef
2.
Xu L, Nakajima H, Manias E, Krishnamoorti R (2009) Tailored nanocomposites of polypropylene with layered silicates. Macromolecules 42:3795–3803CrossRef
3.
Anderson BJ, Zukoski CF (2009) Rheology and microstructure of entangled polymer nanocomposite melts. Macromolecules 42:8370–8384CrossRef
4.
Thomin JD, Keblinski P, Kmnar SK (2008) Network effects on the nonlinear rheology of polymer nanocomposites macromolecules 41:5988–5991
5.
Wang XL, Sun PC, Xue G, Winter HH (2010) Late-state ripening dynamics of a polymer/clay nanocomposite. Macromolecules 43:1901–1906CrossRef
6.
Krishnamoorti R, Yurekli K (2001) Rheology of polymer layered silicate nanocomposites. Curr Opin Colloid Interface Sci 6:464–470CrossRef
7.
Sternstein SS, Zhu AJ (2002) Reinforcement mechanism of nanofilled polymer melts as elucidated by nonlinear viscoelastic behavior. Macromolecules 35:7262–7273CrossRef
8.
Zhang Q, Archer LA (2002) Poly(ethylene oxide)/silica nanocomposites: structure and rheology. Langmuir 18:10435–10442CrossRef
9.
Cassagnau P (2008) Melt rheology of organoclay and fumed silica nanocomposites. Polymer 49:2183–2196CrossRef
10.
Payne AR (1962) The dynamic properties of carbon black-loaded natural rubber vulcanizates. Part I. J Appl Polym Sci 6:57–63CrossRef
11.
Krishnamoorti R, Giannelis EP (1997) Rheology of end-tethered polymer layered silicate nanocomposites. Macromolecules 30:4097–4102CrossRef
12.
Galgali G, Ramesh C, Lele A (2001) A rheological study on the kinetics of hybrid formation in polypropylene nanocomposites. Macromolecules 34:852–858CrossRef
13.
Gusev AA (2006) Micromechanical mechanism of reinforcement and losses in filled rubbers. Macromolecules 39:5960–5962CrossRef
14.
Cassagnau P (2003) Payne effect and shear elasticity of silica-filled polymers in concentrated solutions and in molten state. Polymer 44:2455–2462CrossRef
15.
Meier JG, Kluppel M (2008) Carbon black networking in elastomers monitored by dynamic mechanical and dielectric spectroscopy. Macromol Mater Eng 293:12–38CrossRef
16.
Wang K, Liang S, Deng J, Yang H, Zhang Q, Fu Q, Dong X, Wang D, Han CC (2006) The role of clay network on macromolecular chain mobility and relaxation in isotactic polypropylene/organoclay nanocomposites. Polymer 47:7131–7144CrossRef
17.
Pryamitsyn V, Ganesan V (2006) Origins of linear viscoelastic behavior of polymer-nanoparticle composites. Macromolecules 39:844–856CrossRef
18.
Sarvestani AS, Picu CR (2004) Network model for the viscoelastic behavior of polymer nanocomposites. Polymer 45:7779–7790CrossRef
19.
Heinrich G, Kluppel M, Vilgis TA (2002) Reinforcement of elastomers. Curr Opin Colloid Interface Sci 6:195–203
20.
Du F, Scogna RC, Zhou W, Brand S, Fischer JE, Winey KI (2004) Nanotube networks in polymer nanocomposites: rheology and electrical conductivity. Macromolecules 37:9048–9055CrossRef
21.
Potschke P, Abdel-Goad M, Alig I, Dudkin S, Lellinger D (2004) Rheological and dielectrical characterization of melt mixed polycarbonate-multiwalled carbon nanotube composites. Polymer 45:8863–8870CrossRef
22.
Song YH, Zheng Q (2010) Linear viscoelasticity of polymer melts filled with nano-sized fillers. Polymer 51:3262–3268CrossRef
23.
Litvinov VM, Steeman PAM (1999) EPDM–carbon black interactions and the reinforcement mechanisms, as studied by low-resolution 1H NMR. Macromolecules 32:8476–8490CrossRef
24.
Berriot J, Montes H, Lequeux F, Long D, Sotta P (2002) Evidence for the shift of the glass transition near the particles in silica-filled elastomers. Macromolecules 35:9756–9762CrossRef
25.
Frohlich J, Niedermeier W, Luginsland HD (2005) The effect of filler–filler and filler–elastomer interaction on rubber reinforcement. Compos Part A-Appl Sci Manuf 36:449–460CrossRef
26.
Kayatin MJ, Davis VA (2009) Viscoelasticity and shear stability of single-walled carbon nanotube/unsaturated polyester resin dispersions. Macromolecules 42:6624–6632CrossRef
27.
Wu G, Lin J, Zheng Q, Zhang M (2006) Correlation between percolation behavior of electricity and viscoelasticity for graphite filled high density polyethylene. Polymer 47:2442–2447CrossRef
28.
Wu G, Zheng Q (2004) Estimation of the agglomeration structure for conductive particles and fiber-filled high-density polyethylene through dynamic rheological measurements. J Polym Sci Part B-Polym Phys 42:1199–1205CrossRef
29.
Wu GZ, Asai S, Zhang C, Miura T, Sumita M (2000) A delay of percolation time in carbon-black-filled conductive polymer composites. J Appl Phys 88:1480–1487CrossRef
30.
Larson RG (1999) The structure and rheology of complex fluids. New York, Oxford (Chapter 7)
31.
Meakin P (1983) Formation of fractal clusters and networks by irreversible diffusion-limited aggregation. Phys Rev Lett 51:1119–1122CrossRef
32.
Witten TA, Sander LM (1983) Diffusion-limited aggregation. Phys Rev B 27:5686–5697CrossRef
33.
Jullien R, Kolb M, Botet R (1984) Aggregation by kinetic clustering of clusters in dimensions d > 2. J Physique Lett 45:211–216CrossRef
34.
Rwei SP, Ku FH, Cheng KC (2002) Dispersion of carbon black in a continuous phase: electrical, rheological, and morphological studies. Colloid Polym Sci 280:1110–1115CrossRef
35.
Winter HH, Mours M (1997) Rheology of polymers near liquid–solid transitions. Adv Polym Sci 134:165–234CrossRef
36.
Liu ZY, Yu RZ, Yang MB, Feng JM, Yang W, Yin B (2008) A novel approach in preparing polymer/nano-CaCO3 composites. Front Chem Eng China 2:115–122CrossRef
37.
Yin CL, Liu ZY, Yang W, Yang MB, Feng JM (2009) Crystallization and morphology of iPP/MWCNT prepared by compounding iPP melt with MWCNT aqueous suspension. Colloid Polym Sci 287:615–620CrossRef
38.
Rieker TP, Hindermann-Bischoff M, Ehrburger-Dolle F (2000) Small-angle X-ray scattering study of the morphology of carbon black mass fractal aggregates in polymeric composites. Langmuir 16:5588–5592CrossRef
39.
Sumita M, Sakata K, Asai S, Miyasaka K, Nakagawa H (1991) Dispersion of fillers and the electrical conductivity of polymer blends filled with carbon black. Polym bull 25:265–271CrossRef
40.
Zhu ZY, Thompson T, Wang SQ, Meerwall ED, Halasa A (2005) Investigating linear and nonlinear viscoelastic behavior using model silica-particle-filled polybutadiene. Macromolecules 38:8816–8824CrossRef
41.
Sherman RD, Middleman LM, Jacobs SM (1983) Electron transport processes in conductor-filled polymers. Polym Eng Sci 23:36–46CrossRef
42.
Zou JF, Yu ZZ, Pan YX, Fang XP, Ou YC (2002) Conductive mechanism of polymer/graphite conducting composites with low percolation threshold. J Polym Sci Part B-Polym Phys 40:954–963CrossRef
43.
Chambon F, Petrovic ZS, MacKnight WJ, Winter HH (1986) Rheology of model polyurethanes at the gel point. Macromolecules 19:2146–2149CrossRef
44.
Pogodina NV, Winter HH (1998) Polypropylene crystallization as a physical gelation process. Macromolecules 31:8164–8172CrossRef
45.
De Rosa ME, Mours M, Winter HH (1997) The gel point as reference state: a simple kinetic model for crosslinking polybutadiene via hydrosilation. Polym Gels Netw 5:69–94CrossRef
46.
Xu DH, Wang ZG, Douglas JF (2008) Influence of carbon nanotube aspect ratio on normat stress differences in isotactic polypropylene nanocomposite melts. Macromolecules 41:815–825CrossRef
47.
Kota AK, Cipriano BH, Duesterberg MK, Gershon AL, Powell D, Raghavan SR, Bruck HA (2007) Electrical and rheological percolation in polystyrene/MWCNT nanocomposites. Macromolecules 40:7400–7406CrossRef
48.
Huang S, Liu Z, Yin C, Wang Y, Gao Y, Chen C, Yang M (2011) Dynamic electrical and rheological percolation in isotactic poly(propylene)/carbon black composites. Macromol Mater Eng 296: doi:10.​1002/​mame.​201100150
49.
Tadros TF (1996) Correlation of viscoelastic properties of stable and flocculated suspensions with their interparticle interactions. Adv Colloid Interf Sci 68:97–200
Metadaten
Titel
Enhancement effect of filler network on isotactic polypropylene/carbon black composite melts
verfasst von
Shilin Huang
Zhengying Liu
Chaolu Yin
Yu Wang
Yongjuan Gao
Chen Chen
Mingbo Yang
Publikationsdatum
01.10.2011
Verlag
Springer-Verlag
Erschienen in
Colloid and Polymer Science / Ausgabe 15-16/2011
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-011-2489-6

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