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Erschienen in: Colloid and Polymer Science 7/2014

01.07.2014 | Original Contribution

Sodium silicate route to coat polymer particles with silica

verfasst von: Hua Zou, Helmut Schlaad

Erschienen in: Colloid and Polymer Science | Ausgabe 7/2014

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Abstract

This paper presents a low-cost method to coat polymer particles with silica nanoparticles from inexpensive sodium silicate solution, which is a less-common precursor compared with tetraethyl orthosilicate for coating of polymer particles. The method is based on deposition of active silicic acid in the presence of polymer particles, prepared by emulsion polymerization of styrene involving poly(N-vinyl-2-pyrrolidone), under conditions that a dilute silica sol can be formed from this active silicic acid. The whole process was conducted in aqueous media. The effects of different reaction parameters, such as reaction temperature, amount of active silicic acid and solution pH, on the morphology and size of composite particles were investigated.

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Literatur
1.
Zurück zum Zitat Imhof A (2001) Preparation and characterization of titania-coated polystyrene spheres and hollow titania shells. Langmuir 17:3579–3585CrossRef Imhof A (2001) Preparation and characterization of titania-coated polystyrene spheres and hollow titania shells. Langmuir 17:3579–3585CrossRef
2.
Zurück zum Zitat Guerrero-Martínez A, Pérez-Juste J, Liz-Marzán LM (2010) Recent progress on silica coating of nanoparticles and related nanomaterials. Adv Mater 22:1182–1195CrossRef Guerrero-Martínez A, Pérez-Juste J, Liz-Marzán LM (2010) Recent progress on silica coating of nanoparticles and related nanomaterials. Adv Mater 22:1182–1195CrossRef
3.
Zurück zum Zitat Graf C, Vossen DLJ, Imhof A, van Blaaderen A (2003) A general method to coat colloidal particles with silica. Langmuir 19:6693–6700CrossRef Graf C, Vossen DLJ, Imhof A, van Blaaderen A (2003) A general method to coat colloidal particles with silica. Langmuir 19:6693–6700CrossRef
4.
Zurück zum Zitat Tissot I, Novat C, Lefebvre F, Bourgeat-Lami E (2001) Hybrid latex particles coated with silica. Macromolecules 34:5737–5739CrossRef Tissot I, Novat C, Lefebvre F, Bourgeat-Lami E (2001) Hybrid latex particles coated with silica. Macromolecules 34:5737–5739CrossRef
5.
Zurück zum Zitat Tissot I, Reymond JP, Lefebvre F, Bourgeat-Lami E (2002) SiOH-functionalized polystyrene latexes. A step toward the synthesis of hollow silica nanoparticles. Chem Mater 14:1325–1331CrossRef Tissot I, Reymond JP, Lefebvre F, Bourgeat-Lami E (2002) SiOH-functionalized polystyrene latexes. A step toward the synthesis of hollow silica nanoparticles. Chem Mater 14:1325–1331CrossRef
6.
Zurück zum Zitat Lu Y, McLellan J, Xia YN (2004) Synthesis and crystallization of hybrid spherical colloids composed of polystyrene cores and silica shells. Langmuir 20:3464–3470CrossRef Lu Y, McLellan J, Xia YN (2004) Synthesis and crystallization of hybrid spherical colloids composed of polystyrene cores and silica shells. Langmuir 20:3464–3470CrossRef
7.
Zurück zum Zitat Liz-Marzán LM, Giersig M, Mulvaney P (1996) Homogeneous silica coating of vitreo phobic colloids. Chem Commun 731–732 Liz-Marzán LM, Giersig M, Mulvaney P (1996) Homogeneous silica coating of vitreo phobic colloids. Chem Commun 731–732
8.
Zurück zum Zitat Liz-Marzán LM, Giersig M, Mulvaney P (1996) Synthesis of nanosized gold-silica core-shell particles. Langmuir 12:4329–4335CrossRef Liz-Marzán LM, Giersig M, Mulvaney P (1996) Synthesis of nanosized gold-silica core-shell particles. Langmuir 12:4329–4335CrossRef
9.
Zurück zum Zitat Cornelissen JJLM, Connor EF, Kim HC, Lee VY, Magibitang T, Rice PM, Volksen W, Sundberg LK, Miller RD (2003) Versatile synthesis of nanometersized hollow silica spheres. Chem Commun 1010–1011 Cornelissen JJLM, Connor EF, Kim HC, Lee VY, Magibitang T, Rice PM, Volksen W, Sundberg LK, Miller RD (2003) Versatile synthesis of nanometersized hollow silica spheres. Chem Commun 1010–1011
10.
Zurück zum Zitat Caruso F, Caruso RA, Möhwald H (1999) Production of hollow microspheres from nanostructured composite particles. Chem Mater 11:3309–3314CrossRef Caruso F, Caruso RA, Möhwald H (1999) Production of hollow microspheres from nanostructured composite particles. Chem Mater 11:3309–3314CrossRef
11.
Zurück zum Zitat Caruso F (2001) Nanoengineering of particle surfaces. Adv Mater 13:11–22CrossRef Caruso F (2001) Nanoengineering of particle surfaces. Adv Mater 13:11–22CrossRef
12.
Zurück zum Zitat Caruso R, Susha A, Caruso F (2001) Colloidal templates and resulting inorganic hollow spheres. Chem Mater 13:400–409CrossRef Caruso R, Susha A, Caruso F (2001) Colloidal templates and resulting inorganic hollow spheres. Chem Mater 13:400–409CrossRef
13.
Zurück zum Zitat SierraL GJL (1999) Synthesis of mesoporous silica with tunable pore size from sodium silicate solutions and a polyethyleneoxide surfactant. Microporous Mesoporous Mater 28:243–253CrossRef SierraL GJL (1999) Synthesis of mesoporous silica with tunable pore size from sodium silicate solutions and a polyethyleneoxide surfactant. Microporous Mesoporous Mater 28:243–253CrossRef
14.
Zurück zum Zitat Bhatia RB, Brinker CJ, Gupta AK, Singh AK (2000) Aqueous sol-gel process for proteinen capsulation. Chem Mater 12:2434–2441CrossRef Bhatia RB, Brinker CJ, Gupta AK, Singh AK (2000) Aqueous sol-gel process for proteinen capsulation. Chem Mater 12:2434–2441CrossRef
15.
Zurück zum Zitat Boissière C, Larbot A, Prouzet E (2000) Synthesis of mesoporous MSU-X materials using inexpensive silica sources. Chem Mater 12:1937–1940CrossRef Boissière C, Larbot A, Prouzet E (2000) Synthesis of mesoporous MSU-X materials using inexpensive silica sources. Chem Mater 12:1937–1940CrossRef
16.
Zurück zum Zitat Corriu RJP, Mehdi A, Reye C, Thieuleux C (2004) Direct syntheses of functionalized mesostructured silica by using an inexpensive silica source. Chem Commun 12:1440–1441CrossRef Corriu RJP, Mehdi A, Reye C, Thieuleux C (2004) Direct syntheses of functionalized mesostructured silica by using an inexpensive silica source. Chem Commun 12:1440–1441CrossRef
17.
Zurück zum Zitat Kosuge K, Sato T, Kikukawa N, Takemori M (2004) Morphological control of rod- and fiberlike SBA-15 type mesoporous silica using water-soluble sodium silicate. Chem Mater 16:899–905CrossRef Kosuge K, Sato T, Kikukawa N, Takemori M (2004) Morphological control of rod- and fiberlike SBA-15 type mesoporous silica using water-soluble sodium silicate. Chem Mater 16:899–905CrossRef
18.
Zurück zum Zitat Kosuge K, Kikukawa N, Takemori M (2004) One-step preparation of porous silica spheres from sodium silicate using triblock copolymer templating. Chem Mater 16:4181–4186CrossRef Kosuge K, Kikukawa N, Takemori M (2004) One-step preparation of porous silica spheres from sodium silicate using triblock copolymer templating. Chem Mater 16:4181–4186CrossRef
19.
Zurück zum Zitat Kim KD, Choi KY, Yang JW (2005) Formation of spherical hollow silica particles from sodium silicate solution by ultrasonic spray pyrolysis method. Coll Surf A 254:193–198CrossRef Kim KD, Choi KY, Yang JW (2005) Formation of spherical hollow silica particles from sodium silicate solution by ultrasonic spray pyrolysis method. Coll Surf A 254:193–198CrossRef
20.
Zurück zum Zitat Isobe H, Utsumi S, Yamamoto K, Kanoh H, Kaneko K (2005) Micropore to macropore structure-designed silicas with regulated condensation of silicic acid nanoparticles. Langmuir 21:8042–8047CrossRef Isobe H, Utsumi S, Yamamoto K, Kanoh H, Kaneko K (2005) Micropore to macropore structure-designed silicas with regulated condensation of silicic acid nanoparticles. Langmuir 21:8042–8047CrossRef
21.
Zurück zum Zitat Elimelech H, Avnir D (2008) Sodium-silicate route to submicrometer hybrid PEG@silica particles. Chem Mater 20:2224–2227CrossRef Elimelech H, Avnir D (2008) Sodium-silicate route to submicrometer hybrid PEG@silica particles. Chem Mater 20:2224–2227CrossRef
22.
Zurück zum Zitat Jung CY, Kim JS, Chang TS, Kim ST, Lim HJ, Koo SM (2010) One-step synthesis of structurally controlled silicate particles from sodium silicates using a simple precipitation process. Langmuir 26:5456–5461CrossRef Jung CY, Kim JS, Chang TS, Kim ST, Lim HJ, Koo SM (2010) One-step synthesis of structurally controlled silicate particles from sodium silicates using a simple precipitation process. Langmuir 26:5456–5461CrossRef
23.
Zurück zum Zitat Zou H, Wu SS, Shen J (2008) Polymer/silica nanocomposites: preparation, characterization, properties, and applications. Chem Rev 108:3893–3957CrossRef Zou H, Wu SS, Shen J (2008) Polymer/silica nanocomposites: preparation, characterization, properties, and applications. Chem Rev 108:3893–3957CrossRef
24.
Zurück zum Zitat Bird PG (1941) Colloidal solutions of inorganic oxides. U.S. Patent 2244325 Bird PG (1941) Colloidal solutions of inorganic oxides. U.S. Patent 2244325
25.
Zurück zum Zitat Bechtold MF, Pa KS, Snyder OE (1951) Chemical processes and composition. U.S. Patent 2574902 Bechtold MF, Pa KS, Snyder OE (1951) Chemical processes and composition. U.S. Patent 2574902
26.
Zurück zum Zitat Alexander GB (1956) Process for producing sols of 5-8 millimicron silica particles, and product. U.S. Patent 2750345 Alexander GB (1956) Process for producing sols of 5-8 millimicron silica particles, and product. U.S. Patent 2750345
27.
Zurück zum Zitat Tsai MS (2004) The study of formation colloidal silica via sodium silicate. Mater Sci Eng, B 106:52–55CrossRef Tsai MS (2004) The study of formation colloidal silica via sodium silicate. Mater Sci Eng, B 106:52–55CrossRef
28.
Zurück zum Zitat Yoshida A (2006) Silicic acids and colloidal silica. In: Bergna HE, Roberts WO (eds) Colloidal silica: fundamentals and applications; surfactant science series, vol 131. CRC Press Taylor & Francis Group, Boca Raton, pp pp 37–pp 39 Yoshida A (2006) Silicic acids and colloidal silica. In: Bergna HE, Roberts WO (eds) Colloidal silica: fundamentals and applications; surfactant science series, vol 131. CRC Press Taylor & Francis Group, Boca Raton, pp pp 37–pp 39
29.
Zurück zum Zitat Deng ZW, Chen M, Zhou SX, You B, Wu LM (2006) A novel method for the fabrication of monodisperse hollow silica spheres. Langmuir 22:6403–6407CrossRef Deng ZW, Chen M, Zhou SX, You B, Wu LM (2006) A novel method for the fabrication of monodisperse hollow silica spheres. Langmuir 22:6403–6407CrossRef
30.
Zurück zum Zitat Zou H, Wu SS, Ran QP, Shen J (2008) A simple and low-cost method for the preparation of monodisperse hollow silica spheres. J Phys Chem C 112:11623–11629CrossRef Zou H, Wu SS, Ran QP, Shen J (2008) A simple and low-cost method for the preparation of monodisperse hollow silica spheres. J Phys Chem C 112:11623–11629CrossRef
31.
Zurück zum Zitat Smith JN, Meadows J, Williams PA (1996) Adsorption of PVP onto polystyrene latices and the effect on colloid stability. Langmuir 12:3773–3778CrossRef Smith JN, Meadows J, Williams PA (1996) Adsorption of PVP onto polystyrene latices and the effect on colloid stability. Langmuir 12:3773–3778CrossRef
32.
Zurück zum Zitat Molyneux P (1983) Water-soluble synthetic polymers: properties and behavior. CRC Press Inc, Boca Raton, FL Molyneux P (1983) Water-soluble synthetic polymers: properties and behavior. CRC Press Inc, Boca Raton, FL
33.
Zurück zum Zitat Franks F (1982) In: Franks F (ed) Water: a comprehensive treatise, vol 3. Plenum Press, New York and London Franks F (1982) In: Franks F (ed) Water: a comprehensive treatise, vol 3. Plenum Press, New York and London
34.
Zurück zum Zitat Goto K (1956) Effect of pH on polymerization of silicic acid. J Phys Chem 60:1007–1008CrossRef Goto K (1956) Effect of pH on polymerization of silicic acid. J Phys Chem 60:1007–1008CrossRef
35.
Zurück zum Zitat Roberts WO (2006) Manufacturing and applications of water-borne colloidal silica. In: Bergna HE, Roberts WO (eds) Colloidal silica: fundamentals and applications; surfactant science series, vol 131. CRC Press Taylor & Francis Group, Boca Raton, pp pp 131–pp 175 Roberts WO (2006) Manufacturing and applications of water-borne colloidal silica. In: Bergna HE, Roberts WO (eds) Colloidal silica: fundamentals and applications; surfactant science series, vol 131. CRC Press Taylor & Francis Group, Boca Raton, pp pp 131–pp 175
Metadaten
Titel
Sodium silicate route to coat polymer particles with silica
verfasst von
Hua Zou
Helmut Schlaad
Publikationsdatum
01.07.2014
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 7/2014
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-014-3229-5

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