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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 4/2017

16.02.2017 | Original Contribution

A simple algorithm for the calculation of an approximate electrophoretic mobility of a spherical colloidal particle based on the modified Poisson-Boltzmann equation

verfasst von: Hiroyuki Ohshima

Erschienen in: Colloid and Polymer Science | Ausgabe 4/2017

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Abstract

A simple algorithm is presented for the calculation of an approximate electrophoretic mobility of a spherical colloidal particle in an electrolyte solution. The obtained expressions are based on an approximate form of the modified Poisson-Boltzmann equation taking into account the ion size effects through Carnahan-Starling activity coefficients of electrolyte ions (J Chem Phys 51:635,31). Agreement with the exact numerical results by López-García et al. (J Colloid Interface Sci 458:273,27) is good for most practical cases.
Vorheriger Artikel Numerical and experimental investigation of micro-bubble fluid infiltration in porous media
Nächster Artikel Evolution of block copolymer template structure during the synthesis of ordered mesoporous silica

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Metadaten
Titel
A simple algorithm for the calculation of an approximate electrophoretic mobility of a spherical colloidal particle based on the modified Poisson-Boltzmann equation
verfasst von
Hiroyuki Ohshima
Publikationsdatum
16.02.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 4/2017
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-017-4038-4

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