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Colloid and Polymer Science

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08.06.2017 | Invited Article

Stabilization of coated inorganic nanoparticles by amphiphilic copolymers in aqueous media. Dissipative particle dynamics study

verfasst von: Karel Šindelka, Zuzana Limpouchová, Miroslav Štěpánek, Karel Procházka

Erschienen in: Colloid and Polymer Science | Ausgabe 8/2017

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Abstract

Hybrid organic-inorganic nanoparticles find a number of applications in medicine and in various nanotechnologies, and they have been amply studied both by experimentalists and theoreticians. Their safe application assumes the design and development of stable aqueous dispersions. In this paper, we report on computer simulations aimed at the elucidation of our recent experimental results. By dissipative particle dynamics, we emulated aqueous mixtures of two different species: (i) associates of heavy inorganic nanoparticles modified by relatively short hydrophobic chains tethered to their surface and (ii) amphiphilic copolymer chains. The simulations show that coated inorganic nanoparticles can be stabilized by block copolymers and that a relatively modest excess of copolymer chains with respect to the number of nanoparticles is sufficient to stabilize the aqueous dispersions.

Vorheriger Artikel Thermodynamic and kinetic analysis of phase separation of temperature-sensitive poly(vinyl methyl ether) in the presence of hydrophobic tert-butyl alcohol

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Titel: Stabilization of coated inorganic nanoparticles by amphiphilic copolymers in aqueous media. Dissipative particle dynamics study
verfasst von: Karel Šindelka
Zuzana Limpouchová
Miroslav Štěpánek
Karel Procházka
Publikationsdatum: 08.06.2017
Verlag: Springer Berlin Heidelberg
Erschienen in: Colloid and Polymer Science / Ausgabe 8/2017
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-017-4090-0

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