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Clean Technologies and Environmental Policy

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24.03.2016 | Original Paper

Pyrolysis of Sedum plumbizincicola, a zinc and cadmium hyperaccumulator: pyrolysis kinetics, heavy metal behaviour and bio-oil production

verfasst von: Daoxu Zhong, Zhaoping Zhong, Longhua Wu, Kuan Ding, Yongming Luo, Peter Christie

Erschienen in: Clean Technologies and Environmental Policy | Ausgabe 7/2016

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Abstract

Appropriate disposal of hyperaccumulator biomass is a problem inhibiting the widespread use of phytoremediation technology. In the present study, kinetic analysis of the pyrolysis process of Sedum plumbizincicola, the behaviour of heavy metals and bio-oil composition were studied. The kinetic analysis of the pyrolysis process shows that activation energy (E) changed from 150 to 186 kJ mol⁻¹ and the frequency factor (A) changed from 1.34 × 10¹¹ to 8.99 × 10¹⁵ s⁻¹. At temperatures of 450–750 °C more than 66.3 % of zinc (Zn) remained in the char. More than 87.6 % of the cadmium (Cd) was found in the bio-oil. Pyrolysis at 650 °C led to the highest yield of alkanes with low-oxygen compounds found in the bio-oil. Pyrolysis at 650 °C can likely offer a valuable processing method for S. plumbizincicola and recovery of Zn from the char and recovery of Cd from the bio-oil will be attempted in future research.

Vorheriger Artikel Fate of toxic phorbol esters in Jatropha curcas oil by a biodiesel fuel production process

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Titel: Pyrolysis of Sedum plumbizincicola, a zinc and cadmium hyperaccumulator: pyrolysis kinetics, heavy metal behaviour and bio-oil production
verfasst von: Daoxu Zhong
Zhaoping Zhong
Longhua Wu
Kuan Ding
Yongming Luo
Peter Christie
Publikationsdatum: 24.03.2016
Verlag: Springer Berlin Heidelberg
Erschienen in: Clean Technologies and Environmental Policy / Ausgabe 7/2016
Print ISSN: 1618-954X
Elektronische ISSN: 1618-9558
DOI: https://doi.org/10.1007/s10098-016-1150-y

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