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Adsorption
Erschienen in: Adsorption 6-7/2015

01.10.2015

Seeking metal–organic frameworks for methane storage in natural gas vehicles

verfasst von: Jia Fu, Yun Tian, Jianzhong Wu

Erschienen in: Adsorption | Ausgabe 6-7/2015

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Abstract

Promising metal–organic frameworks (MOFs) have been identified from Grand Canonical Monte Carlo simulation to meet the ARPA-E target for methane storage in natural gas vehicles set by the U.S. Department of Energy (DOE). While none of MOF materials known today are able to meet the ARPA-E target for in vehicle natural gas storage, it could be reached by relaxing the operation conditions for gas compression and delivery. When methane is compressed at 298 K and 170 bar and released at 358 K and 5 bar, top ranked MOFs are able to deliver over 90 % of the required gas delivery amount. Besides, a large number of MOF materials could achieve the ARPA-E target 100 % if the compression temperature is set to 233 K. The simulation results provide useful insights into chemical and geometric characteristics of new materials for methane storage. Future materials development should be focused on improving the volumetric delivery amount rather than the total volumetric gas storage capacity that is often quoted in the literature.

Graphical Abstract

Monte Carlo simulation identifies promising MOF materials and operation parameters to meet the ARPA-E target for methane storage.
Vorheriger Artikel Adsorption of atrazine on hemp stem-based activated carbons with different surface chemistry
Nächster Artikel CO2 capture by vacuum swing adsorption: role of multiple pressure equalization steps

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Metadaten
Titel
Seeking metal–organic frameworks for methane storage in natural gas vehicles
verfasst von
Jia Fu
Yun Tian
Jianzhong Wu
Publikationsdatum
01.10.2015
Verlag
Springer US
Erschienen in
Adsorption / Ausgabe 6-7/2015
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI
https://doi.org/10.1007/s10450-015-9688-2

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