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Cellulose

Erschienen in:

01.04.2012

Simple synthesis of mixed cellulose acylate phosphonates applying n-propyl phosphonic acid anhydride

verfasst von: Thomas Heinze, Velina Sarbova, Matilde Calado Vieira Nagel

Erschienen in: Cellulose | Ausgabe 2/2012

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Abstract

Cellulose mixed esters containing alkylphosphonate and carboxylate groups were prepared homogeneously by a new one-pot method using n-propyl phosphonic acid anhydride (T3P^®) in LiCl/N-methyl-2-pyrrolidone (NMP). n-Propyl phosphonic acid anhydride acts as both an activating agent for carboxylic acids and phosphonation reagent. Cellulose mixed esters with DS_acyl ranging from 1.4 to 1.8, and DS_phos up to 0.7 could be prepared. The structure of the cellulose mixed esters was elucidated by FTIR- and NMR spectroscopy, as well as by GPC and solubility tests.

Vorheriger Artikel Salt-induced acceleration of chemical reactions in cellulose nanopores

Nächster Artikel Surface modification of cellulose fibers with layer-by-layer self-assembly of lignosulfonate and polyelectrolyte: effects on fibers wetting properties and paper strength

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Titel: Simple synthesis of mixed cellulose acylate phosphonates applying n-propyl phosphonic acid anhydride
verfasst von: Thomas Heinze
Velina Sarbova
Matilde Calado Vieira Nagel
Publikationsdatum: 01.04.2012
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 2/2012
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-011-9646-4

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