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Cellulose

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01.12.2012 | Original Paper

Properties of plasticized composite films prepared from nanofibrillated cellulose and birch wood xylan

verfasst von: Natanya M. L. Hansen, Thomas O. J. Blomfeldt, Mikael S. Hedenqvist, David V. Plackett

Erschienen in: Cellulose | Ausgabe 6/2012

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Abstract

Xylans, an important sub-class of hemicelluloses, represent a largely untapped resource for new renewable materials derived from biomass. As with other carbohydrates, nanocellulose reinforcement of xylans is interesting as a route to new bio-materials. With this in mind, birch wood xylan was combined with nanofibrillated cellulose (NFC) and films were cast with and without glycerol, sorbitol or methoxypolyethylene glycol (MPEG) as plasticizers. Microscopy revealed some NFC agglomeration in the composite films as well as a layered nanocellulose structure. Equilibrium moisture content in plasticized films increased with glycerol content but was independent of xylan:NFC ratio in unplasticized films. Sorbitol- and MPEG-plasticized films showed equilibrium moisture contents of approximately 10 wt% independent of plasticizer content. Tensile testing revealed increases in tensile strength with increased NFC content in the xylan:NFC composition range from 50:50 to 80:20 and plasticizer addition generally provided less brittle films. The oxygen permeability of unplasticized xylan-NFC films fell into a range which was similar to that for previously measured pure NFC films and was statistically independent of the xylan:NFC ratio. Water vapor permeability values of 1.9–2.8·10⁻¹¹ g Pa⁻¹ m⁻¹ s⁻¹ were found for unplasticized composite films, but these values were significantly reduced in the case of films plasticized with 10–40 wt% sorbitol.

Vorheriger Artikel The relationship between cellulose content and the contents of sugars and minerals during fiber development in colored cotton cultivars

Nächster Artikel Approaching zero cellulose loss in cellulose nanocrystal (CNC) production: recovery and characterization of cellulosic solid residues (CSR) and CNC

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Units recalculated from the original paper—original units: g mm kPa⁻¹ m⁻² day^−1.

Units recalculated from the original paper—original units: mol H₂O m Pa⁻¹ m⁻² s^−1.

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Titel: Properties of plasticized composite films prepared from nanofibrillated cellulose and birch wood xylan
verfasst von: Natanya M. L. Hansen
Thomas O. J. Blomfeldt
Mikael S. Hedenqvist
David V. Plackett
Publikationsdatum: 01.12.2012
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 6/2012
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-012-9764-7

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