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Cellulose
Erschienen in: Cellulose 4/2015

01.08.2015 | Original Paper

Magnetic Cu0.5Co0.5Fe2O4 ferrite nanoparticles immobilized in situ on the surfaces of cellulose nanocrystals

verfasst von: Chen Tian, Shiyu Fu, Lucian A. Lucia

Erschienen in: Cellulose | Ausgabe 4/2015

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Abstract

A novel magnetic cellulose nanocrystal material decorated with Cu–Co ferrite was synthesized in situ by controlled hydrothermal chemistry in the presence of NH3·H2O. The ferrite nanoparticles immobilized on cellulose were found to exist in their oxide forms as identified by FTIR, XPS and Raman spectra. They demonstrate very good dispersibility with smaller crystal size after being formed in situ on the surface of a nanocellulose crystal template by the application of ammonia. The crystalline structure of cellulose can only be maintained at relatively low contents of ferrite surface decoration (11.0 %) versus high contents (e.g., 75.6 %). Moreover, the magnetic properties of the resultant materials could be controlled by changing the ratio of the molecular components in the ferrites. At the low ferrite contents, the composition was Cu0.5Co0.5Fe2O4 at a small crystal size of 13.5 nm that provided a maximum saturation magnetization of 10.95 emu/g. Finally, the thermostability of the nanocomposite was improved after immobilizing the magnetic nanoparticles.
Vorheriger Artikel Biocomposites of polyamide 4.10 and surface modified microfibrillated cellulose (MFC): influence of processing parameters on structure and thermomechanical properties
Nächster Artikel Diethylenetriamine-functionalized chitosan magnetic nano-based particles for the sorption of rare earth metal ions [Nd(III), Dy(III) and Yb(III)]

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Literatur
Altavilla C, Ciliberto E, Aiello A, Sangregorio C, Gatteschi D (2007) A shortcut to organize self-assembled monolayers of cobalt ferrite nanoparticles on silicon. Chem Mater 19:5980–5985CrossRef
Ayyappan S, Mahadevan S, Chandramohan P, Srinivasan MP, Philip J, Raj B (2010) Influence of Co2+ ion concentration on the size, magnetic properties, and purity of CoFe2O4 spinel ferrite nanoparticles. J Phys Chem C 114:6334–6341CrossRef
Baig RBN, Nadagouda MN, Varma RS (2014) Carbon-coated magnetic palladium: applications in partial oxidation of alcohols and coupling reactions. Green Chem 16:4333–4338CrossRef
Bao N, Shen L, Wang Y, Padhan P, Gupta A (2007) A facile thermolysis route to monodisperse ferrite nanocrystals. J Am Chem Soc 129:12374–12375CrossRef
Barreto A, Santiago VR, Mazzetto SE, Denardin JC, Lavín R, Mele G, Ribeiro M, Vieira IG, Gonçalves T, Ricardo N (2011) Magnetic nanoparticles for a new drug delivery system to control quercetin releasing for cancer chemotherapy. J Nanoparticle Res 13:6545–6553CrossRef
Comes Franchini M, Baldi G, Bonacchi D, Gentili D, Giudetti G, Lascialfari A, Corti M, Marmorato P, Ponti J, Micotti E (2010) Bovine serum albumin-based magnetic nanocarrier for MRI diagnosis and hyperthermic therapy: a potential theranostic approach against cancer. Small 6:366–370CrossRef
De Souza LK, Zamian JR, Da Rocha Filho GN, Soledade LE, Dos Santos IM, Souza AG, Scheller T, Angélica RS, Da Costa CE (2009) Blue pigments based on CoxZn1−xAl2O4 spinels synthesized by the polymeric precursor method. Dyes Pigments 81:187–192CrossRef
Elazzouzi-Hafraoui S, Nishiyama Y, Putaux J, Heux L, Dubreuil F, Rochas C (2007) The shape and size distribution of crystalline nanoparticles prepared by acid hydrolysis of native cellulose. Biomacromolecules 9:57–65CrossRef
Eshraghi M, Kameli P (2011) Magnetic properties of CoFe2O4 nanoparticles prepared by thermal treatment of ball-milled precursors. Curr Appl Phys 11:476–481CrossRef
Fu Y, Chen Q, He M, Wan Y, Sun X, Xia H, Wang X (2012) Copper ferrite-graphene hybrid: a multifunctional heteroarchitecture for photocatalysis and energy storage. Ind Eng Chem Res 51:11700–11709CrossRef
Galland S, Andersson RL, Salajková M, Ström V, Olsson RT, Berglund LA (2013) Cellulose nanofibers decorated with magnetic nanoparticles–synthesis, structure and use in magnetized high toughness membranes for a prototype loudspeaker. J Mater Chem C 1:7963–7972CrossRef
Gandhi N, Singh K, Ohlan A, Singh DP, Dhawan SK (2011) Thermal, dielectric and microwave absorption properties of polyaniline—CoFe2O4 nanocomposites. Compos Sci Technol 71:1754–1760CrossRef
Habibi Y, Goffin A, Schiltz N, Duquesne E, Dubois P, Dufresne A (2008) Bionanocomposites based on poly (ε-caprolactone)-grafted cellulose nanocrystals by ring-opening polymerization. J Mater Chem 18:5002–5010CrossRef
Han Q, Liu Xu, Chen Wang, Zhang H (2007) Growth and properties of single-crystalline γ-Fe2O3 nanowires. J Phys Chem C 111:5034–5038CrossRef
Han L, Wei H, Tu B, Zhao D (2011) A facile one-pot synthesis of uniform core–shell silver nanoparticle@ mesoporous silica nanospheres. Chem Commun 47:8536–8538CrossRef
Hao R, Xing R, Xu Z, Hou Y, Gao S, Sun S (2010) Synthesis, functionalization, and biomedical applications of multifunctional magnetic nanoparticles. Adv Mater 22:2729–2742CrossRef
He HY (2012) Comparison study on magnetic property of Co0.5Zn0.5Fe2O4 powders by template-assisted sol–gel and hydrothermal methods. J Mater Sci: Mater Electron 23:995–1000
He J, Kunitake T, Nakao A (2003) Facile in situ synthesis of noble metal nanoparticles in porous cellulose fibers. Chem Mater 15:4401–4406CrossRef
Jovanović S, Spreitzer M, Tramšek M, Trontelj Z, Suvorov D (2014) Effect of oleic acid concentration on the physicochemical properties of cobalt ferrite nanoparticles. J Phys Chem C 118:13844–13856CrossRef
Kaiser M (2009) Effect of nickel substitutions on some properties of Cu–Zn ferrites. J Alloy Compd 468:15–21CrossRef
Kim C, Lee J, Katoh S, Murakami R, Yoshimura M (2001) Synthesis of Co-, Co-Zn and Ni-Zn ferrite powders by the microwave-hydrothermal method. Mater Res Bull 36:2241–2250CrossRef
Kim T, Reis L, Rajan K, Shima M (2005) Magnetic behavior of iron oxide nanoparticle—biomolecule assembly. J Magn Magn Mater 295:132–138CrossRef
Klemm D, Kramer F, Moritz S, Lindström T, Ankerfors M, Gray D, Dorris A (2011) Nanocelluloses: a new family of nature-based materials. Angew Chem Int Ed 50:5438–5466CrossRef
Kucheryavy P, He J, John VT, Maharjan P, Spinu L, Goloverda GZ, Kolesnichenko VL (2013) Superparamagnetic iron oxide nanoparticles with variable size and an iron oxidation state as prospective imaging agents. Langmuir 29:710–716CrossRef
Laurent S, Forge D, Port M, Roch A, Robic C, Vander Elst L, Muller RN (2008) Magnetic iron oxide nanoparticles: synthesis, stabilization, vectorization, physicochemical characterizations, and biological applications. Chem Rev 108:2064–2110CrossRef
Lee N, Hyeon T (2012) Designed synthesis of uniformly sized iron oxide nanoparticles for efficient magnetic resonance imaging contrast agents. Chem Soc Rev 41:2575–2589CrossRef
Lee C, Jeong H, Lim ST, Sohn M, Kim DW (2010) Synthesis of iron oxide nanoparticles with control over shape using imidazolium-based ionic liquids. ACS Appl Mater Interfaces 2:756–759CrossRef
Li C, Wang X, Chen F, Zhang C, Zhi X, Wang K, Cui D (2013a) The antifungal activity of graphene oxide–silver nanocomposites. Biomaterials 34:3882–3890CrossRef
Li W, Zhao X, Liu S (2013b) Preparation of entangled nanocellulose fibers from APMP and its magnetic functional property as matrix. Carbohydr Polym 94:278–285CrossRef
Lin X, Ji G, Liu Y, Huang Q, Yang Z, Du Y (2012) Formation mechanism and magnetic properties of hollow Fe3O4 nanospheres synthesized without any surfactant. Cryst Eng Commun 14:8658–8663CrossRef
Liu C, Zou B, Rondinone AJ, Zhang ZJ (2000) Chemical control of superparamagnetic properties of magnesium and cobalt spinel ferrite nanoparticles through atomic level magnetic couplings. J Am Chem Soc 122:6263–6267CrossRef
Liu S, Zhou J, Zhang L (2011) In situ synthesis of plate-like Fe2O3 nanoparticles in porous cellulose films with obvious magnetic anisotropy. Cellulose 18:663–673CrossRef
Liu S, Yan Q, Tao D, Yu T, Liu X (2012) Highly flexible magnetic composite aerogels prepared by using cellulose nanofibril networks as templates. Carbohydr Polym 89:551–557CrossRef
Lüders U, Barthélémy A, Bibes M, Bouzehouane K, Fusil S, Jacquet E, Contour JP, Bobo JF, Fontcuberta J, Fert A (2006) NiFe2O4: a versatile spinel material brings new opportunities for spintronics. Adv Mater 18:1733–1736CrossRef
Mohamed RM, Rashad MM, Haraz FA, Sigmund W (2010) Structure and magnetic properties of nanocrystalline cobalt ferrite powders synthesized using organic acid precursor method. J Magn Magn Mater 322:2058–2064CrossRef
Nasir Baig RB, Varma RS (2014) Magnetic carbon-supported palladium nanoparticles: an efficient and sustainable catalyst for hydrogenation reactions. ACS Sustain Chem Eng 2:2155–2158CrossRef
Nata IF, Sureshkumar M, Lee C (2011) One-pot preparation of amine-rich magnetite/bacterial cellulose nanocomposite and its application for arsenate removal. RSC Adv 1:625–631CrossRef
Nypel T, Rodriguez-Abreu C, Rivas J, Dickey MD, Rojas OJ (2014) Magneto-responsive hybrid materials based on cellulose nanocrystals. Cellulose 21:2557–2566CrossRef
Olsson RT, Samir MA, Salazar-Alvarez G, Belova L, Ström V, Berglund LA, Ikkala O, Nogues J, Gedde UW (2010) Making flexible magnetic aerogels and stiff magnetic nanopaper using cellulose nanofibrils as templates. Nat Nanotechnol 5:584–588CrossRef
Pankhurst QA, Thanh N, Jones SK, Dobson J (2009) Progress in applications of magnetic nanoparticles in biomedicine. J Phys D Appl Phys 42:224001CrossRef
Park J, Joo J, Kwon SG, Jang Y, Hyeon T (2007) Synthesis of monodisperse spherical nanocrystals. Angew Chem Int Ed 46:4630–4660CrossRef
Reddy GK, Boolchand P, Smirniotis PG (2012) Unexpected behavior of copper in modified ferrites during high temperature WGS reaction—aspects of Fe3+ ↔ Fe2+ redox chemistry from mössbauer and XPS studies. J Phys Chem C 116:11019–11031CrossRef
Rezlescu N, Rezlescu E, Sava CL, Tudorache F, Popa PD (2004) Effects of some ionic substitutions on sintering, structure and humidity sensitivity of MgCu ferrite. Phys Status Solidi (a) 201:17–25CrossRef
Roy B, Bharali P, Konwar BK, Karak N (2013) Silver-embedded modified hyperbranched epoxy/clay nanocomposites as antibacterial materials. Bioresour Technol 127:175–180CrossRef
Salazar-Alvarez G, Olsson RT, Sort J, Macedo WA, Ardisson JD, Baró MD, Gedde UW, Nogués J (2007) Enhanced coercivity in co-rich near-stoichiometric CoxFe3−xO4 + δ nanoparticles prepared in large batches. Chem Mater 19:4957–4963CrossRef
Selvan RK, Krishnan V, Augustin CO, Bertagnolli H, Kim CS, Gedanken A (2007) Investigations on the structural, morphological, electrical, and magnetic properties of CuFe2O4–NiO nanocomposites. Chem Mater 20:429–439CrossRef
Sivakumar M, Takami T, Ikuta H, Towata A, Yasui K, Tuziuti T, Kozuka T, Bhattacharya D, Iida Y (2006) Fabrication of zinc ferrite nanocrystals by sonochemical emulsification and evaporation: observation of magnetization and its relaxation at low temperature. J Phys Chem B 110:15234–15243CrossRef
Srivastava M, Ojha AK, Chaubey S, Materny A (2009) Synthesis and optical characterization of nanocrystalline NiFe2O4 structures. J Alloy Compd 481:515–519CrossRef
Sudakar C, Subbanna GN, Kutty TN (2002) Synthesis of acicular hydrogoethite (α-FeOOH·xH2O; 0.1 < x < 0.22) particles using morphology controlling cationic additives and magnetic properties of maghemite derived from hydrogoethite. J Mater Chem 12:107–116CrossRef
Sureshkumar M, Siswanto DY, Lee C (2010) Magnetic antimicrobial nanocomposite based on bacterial cellulose and silver nanoparticles. J Mater Chem 20:6948–6955CrossRef
Tian C, Fu S, Chen J, Meng Q, Lucia LA (2014a) Graft polymerization of epsilon-caprolactone to cellulose nanocrystals and optimization of grafting conditions utilizing a response surface methodology. Nord Pulp Pap Res J 29:58–68CrossRef
Tian C, Fu S, Habibi Y, Lucia LA (2014b) Polymerization topochemistry of cellulose nanocrystals: a function of surface dehydration control. Langmuir 30:14670–14679CrossRef
Vaidyanathan G, Sendhilnathan S (2008) Characterization of Co1−xZnxFe2O4 nanoparticles synthesized by co-precipitation method. Phys B 403:2157–2167CrossRef
Veeramani H, Aruguete D, Monsegue N, Murayama M, Dippon U, Kappler A, Hochella MF (2013) Low-temperature green synthesis of multivalent manganese oxide nanowires. ACS Sustain Chem Eng 1:1070–1074CrossRef
Verma S, Pravarthana D (2011) One-pot synthesis of highly monodispersed ferrite nanocrystals: surface characterization and magnetic properties. Langmuir 27:13189–13197CrossRef
Visinescu D, Paraschiv C, Ianculescu A, Jurca B, Vasile B, Carp O (2010) The environmentally benign synthesis of nanosized CoxZn1−xAl2O4 blue pigments. Dyes Pigments 87:125–131CrossRef
Wang N, Ding E, Cheng R (2007) Thermal degradation behaviors of spherical cellulose nanocrystals with sulfate groups. Polymer 48:3486–3493CrossRef
Xiong R, Lu C, Wang Y, Zhou Z, Zhang X (2013) Nanofibrillated cellulose as the support and reductant for the facile synthesis of Fe3O4/Ag nanocomposites with catalytic and antibacterial activity. J Mater Chem A 1:14910–14918CrossRef
Xu S, Shen D, Wu P, Xu S, Shen D, Wu P (2013) Fabrication of water-repellent cellulose fiber coated with magnetic nanoparticles under supercritical carbon dioxide. J Nanoparticle Res 15:1–12
Metadaten
Titel
Magnetic Cu0.5Co0.5Fe2O4 ferrite nanoparticles immobilized in situ on the surfaces of cellulose nanocrystals
verfasst von
Chen Tian
Shiyu Fu
Lucian A. Lucia
Publikationsdatum
01.08.2015
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 4/2015
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-015-0658-3

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