nach oben

Cellulose

Erschienen in:

09.02.2019 | Original Research

Cellulose nanosheets formed by mild additive-free ball milling

verfasst von: Yunxiu Zhang, Shigenori Kuga, Min Wu, Yong Huang

Erschienen in: Cellulose | Ausgabe 5/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Cellulose nanosheets similar to those obtained by milling with silicone oil (Zhao et al. in Cellulose 23:2809–2818, 2016) were obtained by mild additive-free milling followed by dispersion in ethanol. Typical nanosheets were of 4 nm thickness, possibly formed by monolayer association of elementary fibrils. The thickness decreased with prolonged milling to 2 nm or less, and the thinnest sheets observed were about 0.4 nm, corresponding to monomolecular layer of cellulose. Further milling caused disappearance of nanosheets due to complete decrystallization. This observation indicates that nanosheet formation is an intermediate stage of decrystallization of cellulose.

Graphical abstract

Vorheriger Artikel Preparation of nanofibrillated cellulose and nanocrystalline cellulose from surgical cotton and cellulose pulp in hot-glycerol medium

Nächster Artikel Transparent konjac glucomannan/cellulose nanofibril composite films with improved mechanical properties and thermal stability

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Abe K (2016) Nanofibrillation of dried pulp in NaOH solutions using bead milling. Cellulose 23:1257–1261CrossRef

Agarwal UP, Reiner RS, Ralph SA (2010) Cellulose I crystallinity determination using FT-Raman spectroscopy: univariate and multivariate methods. Cellulose 17:721–733CrossRef

Ago M, Endo T, Okajima K (2007) Effect of solvent on morphological and structural change of cellulose under ball-milling. Polym J 39:435–441CrossRef

Avolio R, Bonadies I, Capitani D, Errico ME, Gentile G, Avella M (2012) A multitechnique approach to assess the effect of ball milling on cellulose. Carbohyd Polym 87:265–273CrossRef

Cervin NT, Aulin C, Larsson PT, Wagberg L (2012) Ultra porous nanocellulose aerogels as separation medium for mixtures of oil/water liquids. Cellulose 19:401–410CrossRef

Ding SY, Himmel ME (2006) The maize primary cell wall microfibril: a new model derived from direct visualization. J Agric Food Chem 54:597–606CrossRefPubMed

Edwards HGM, Farwell DW, Webster D (1997) FT Raman microscopy of untreated natural plant fibres. Spectrochim Acta A Mol Biomol Spectrosc 53:2383–2392CrossRef

Eronen P, Osterberg M, Jaaskelainen A-S (2009) Effect of alkaline treatment on cellulose supramolecular structure studied with combined confocal Raman spectroscopy and atomic force microscopy. Cellulose 16:167–178CrossRef

Fengel D (1992) Characterization of cellulose by deconvoluting the oh valency range in FTIR spectra. Holzforschung 46:283–288CrossRef

Fengel D (1993) Influence of water on the OH valency range in deconvoluted FTIR spectra of cellulose. Holzforschung 47:103–108CrossRef

Gierlinger N, Schwanninger M (2006) Chemical imaging of poplar wood cell walls by confocal Raman microscopy. Plant Physiol 140:1246–1254CrossRefPubMedPubMedCentral

Hamad WY (2008) Studies of deformation processes in cellulosics using Raman microscopy. In: Hu TQ (ed) Characterization of lignocellulosic materials. Blackwell Publishing Ltd., Oxford, pp 121–137

Huang P, Wu M, Kuga S, Wang D, Wu D, Huang Y (2012) One-step dispersion of cellulose nanofibers by mechanochemical esterification in an organic solvent. Chemsuschem 5:2319–2322CrossRefPubMed

Huang P, Zhao Y, Kuga S, Wu M, Huang Y (2016) A versatile method for producing functionalized cellulose nanofibers and their application. Nanoscale 8:3753–3759CrossRefPubMed

Isogai A, Saito T, Fukuzumi H (2011) TEMPO-oxidized cellulose nanofibers. Nanoscale 3:71–85CrossRefPubMed

Jiang F, Esker AR, Roman M (2010) Acid-catalyzed and solvolytic desulfation of H₂SO₄-hydrolyzed cellulose nanocrystals. Langmuir ACS J Surf Colloids 26:17919–17925CrossRef

Kang X, Sun P, Kuga S, Wang C, Zhao Y, Wu M, Huang Y (2017) Thin cellulose nanofiber from corncob cellulose and its performance in transparent nanopaper. ACS Sustain Chem Eng 5:2529–2534CrossRef

Klemm D, Heublein B, Fink HP, Bohn A (2005) Cellulose: fascinating biopolymer and sustainable raw material. Angew Chem Int Ed Engl 44:3358–3393CrossRefPubMed

Li Q, Renneckar S (2009) Molecularly thin nanoparticles from cellulose: isolation of sub-microfibrillar structures. Cellulose 16:1025–1032CrossRef

Li Q, Renneckar S (2011) Supramolecular structure characterization of molecularly thin cellulose I nanoparticles. Biomacromolecules 12:650–659CrossRefPubMed

Marechal Y, Chanzy H (2000) The hydrogen bond network in I-beta cellulose as observed by infrared spectrometry. J Mol Struct 523:183–196CrossRef

Mohan T, Spirk S, Kargl R, Doliska A, Vesel A, Salzmann I, Resel R, Ribitsch V, Stana-Kleinschek K (2012) Exploring the rearrangement of amorphous cellulose model thin films upon heat treatment. Soft Matter 8:9807–9815CrossRef

Moon RJ, Martini A, Nairn J, Simonsen J, Youngblood J (2011) Cellulose nanomaterials review: structure, properties and nanocomposites. Chem Soc Rev 40:3941–3994CrossRefPubMed

Nishiyama Y (2009) Structure and properties of the cellulose microfibril. J Wood Sci 55:241–249CrossRef

Nishiyama Y (2018) Molecular interactions in nanocellulose assembly. Philos Trans R Soc Math Phys Eng Sci 376(2112):20170047CrossRef

Oh SY, Yoo DI, Shin Y, Kim HC, Kim HY, Chung YS, Park WH, Youk JH (2005) Crystalline structure analysis of cellulose treated with sodium hydroxide and carbon dioxide by means of x-ray diffraction and FTIR spectroscopy. Carbohydr Res 340:2376–2391CrossRefPubMed

Qian XH, Ding SY, Nimlos MR, Johnson DK, Himmel ME (2005) Atomic and electronic structures of molecular crystalline cellulose I beta: a first-principles investigation. Macromolecules 38:10580–10589CrossRef

Rao X, Kuga S, Wu M, Huang Y (2015) Influence of solvent polarity on surface-fluorination of cellulose nanofiber by ball milling. Cellulose 22:2341–2348CrossRef

Sato K, Mochizuki H, Okajima K, Yamane C (2004) Effects of hydrophobic solvents on x-ray diffraction patterns of regenerated cellulose membrane. Polym J 36:478–482CrossRef

Schenzel K, Fischer S, Brendler E (2005) New method for determining the degree of cellulose I crystallinity by means of FT Raman spectroscopy. Cellulose 12:223–231CrossRef

Schwanninger M, Rodrigues JC, Pereira H, Hinterstoisser B (2004) Effects of short-time vibratory ball milling on the shape of FT-IR spectra of wood and cellulose. Vib Spectrosc 36:23–40CrossRef

Segal L, Creely JJ Jr, Martin AE (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the x-ray diffractometer. Text Res J 29:786–794CrossRef

Shopsowitz KE, Stahl A, Hamad WY, MacLachlan MJ (2012) Hard templating of nanocrystalline titanium dioxide with chiral nematic ordering. Angew Chem Int Ed Engl 51:6886–6890CrossRefPubMed

Siro I, Plackett D (2010) Microfibrillated cellulose and new nanocomposite materials: a review. Cellulose 17:459–494CrossRef

Viswanathan G, Murugesan S, Pushparaj V, Nalamasu O, Ajayan PM, Linhardt RJ (2006) Preparation of biopolymer fibers by electrospinning from room temperature ionic liquids. Biomacromolecules 7:415–418CrossRefPubMedPubMedCentral

Zhao M, Kuga S, Jiang S, Wu M, Huang Y (2016) Cellulose nanosheets induced by mechanical impacts under hydrophobic environment. Cellulose 23:2809–2818CrossRef

Zhu JY, Sabo R, Luo X (2011) Integrated production of nano-fibrillated cellulose and cellulosic biofuel (ethanol) by enzymatic fractionation of wood fibers. Green Chem 13:1339CrossRef

Titel: Cellulose nanosheets formed by mild additive-free ball milling
verfasst von: Yunxiu Zhang
Shigenori Kuga
Min Wu
Yong Huang
Publikationsdatum: 09.02.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 5/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02282-7

Springer Professional

Abstract

Graphical abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 5/2019

Enhanced strength, stiffness and elongation potential of paper by spray addition of polysaccharides

Development of fabric-based microfluidic devices by wax printing

Flame resistance behavior of cotton fabrics coated with bilayer assemblies of ammonium polyphosphate and casein

Polypyrrole@metal-organic framework (UIO-66)@cotton fabric electrodes for flexible supercapacitors

Reinforcement of layer-by-layer self-assembly coating modified cellulose nanofibers to reduce the flammability of polyvinyl alcohol

Choline chloride-based deep eutectic solvent systems as a pretreatment for nanofibrillation of ramie fibers