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31.01.2019 | Original Research

Transparent konjac glucomannan/cellulose nanofibril composite films with improved mechanical properties and thermal stability

verfasst von: Jinyu Wang, Xin Chen, Chenggang Zhang, Abdul Rehman Akbar, Zhuqun Shi, Quanling Yang, Chuanxi Xiong

Erschienen in: Cellulose | Ausgabe 5/2019

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Abstract

Development of renewable, biodegradable and biocompatible high-performance biomass materials is in great demand for the creation of a low-carbon society. Here, a series of konjac glucomannan (KGM) nanocomposite films reinforced by 2, 2, 6, 6-tetramethylpiperidine-1-oxyl (TEMPO)-oxidized cellulose nanofibrils (TOCNs) were fabricated from aqueous system by casting pathway. The composites exhibited nanolayered structure and intermolecular hydrogen bonds formed between KGM and TOCN, resulting in their good compatibility. Moreover, the incorporation of TOCN enhanced the mechanical properties of KGM significantly. Particularly, with an increase of TOCN content from 0 to 20 wt%, the tensile strength and Young’s modulus of the composites increased from 59 MPa and 1.18 GPa to 180 MPa and 2.51 GPa, respectively; the elongation at break reached a maximum of 42.9% with 10 wt% TOCN addition, much higher than 25.6% of the neat KGM film. In addition, the composites also possessed excellent transparency and thermal stability. These biomass-based nanocomposite films are promising in the field of high-performance packaging materials.

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Vorheriger Artikel Cellulose nanosheets formed by mild additive-free ball milling

Nächster Artikel Surface modification of cellulose nanocrystal using succinic anhydride and its effects on poly(butylene succinate) based composites

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Titel: Transparent konjac glucomannan/cellulose nanofibril composite films with improved mechanical properties and thermal stability
verfasst von: Jinyu Wang
Xin Chen
Chenggang Zhang
Abdul Rehman Akbar
Zhuqun Shi
Quanling Yang
Chuanxi Xiong
Publikationsdatum: 31.01.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 5/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02302-6

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