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09.02.2019 | Original Research

Preparation and characterization of physicochemical properties and application of novel ternary deep eutectic solvents

verfasst von: Michal Jablonsky, Veronika Majova, Katarina Ondrigova, Jozef Sima

Erschienen in: Cellulose | Ausgabe 5/2019

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Abstract

In this work preparation of 23 new three-component DESs is described. Based on their stability 15 of them were finally selected and subjected to further investigation. DESs are eco-friendly solvents and due to their involving in treatment of lignocellulosic materials, some properties related to this topic were determined in detail, among them density, electrical conductivity and viscosity. The potential of the selected 15 DESs in delignification of unbleached pulp was examined. It was manifested that the addition of a third component to classical two-component DESs allow to purposefully control density and viscosity of the ternary DESs and thus upgrade pulp delignification efficiency. The addition of an alcohol leads to a decrease of both DES density and viscosity. Contrary, the addition of an organic acid causes their increase. Moreover, DES properties can be purposefully governed via changing the structure and complexity of the chain of a given acid.

Vorheriger Artikel Preparation of oxidized celluloses in a TEMPO/NaBr system using different chlorine reagents in water

Nächster Artikel The chemical composition of silver birch (Betula pendula Roth.) wood in Poland depending on forest stand location and forest habitat type

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Abbott AP, Capper G, Davies DL et al (2003) Novel solvent properties of choline chloride/urea mixtures. Chem Commun 1:70–71CrossRef

Abbott AP, Capper G, Gray S (2006) Design of improved deep eutectic solvents using hole theory. ChemPhysChem 7:803–806CrossRefPubMed

Abbott AP, Barron JC, Ryder KS, Wilson D (2007a) Eutectic-based ionic liquids with metal-containing anions and cations. Chem Eur J 13:6495–6501CrossRefPubMed

Abbott AP, Capper G, Mckenzie KJ et al (2007b) Electrodeposition of zinc-tin alloys from deep eutectic solvents based on choline chloride. J Electroanal Chem 599:288–294CrossRef

Abbott AP, Harris RC, Ryder KS (2007c) Application of hole theory to define ionic liquids by their transport properties. J Phys Chem B 111:4910–4913CrossRefPubMed

Anastas P, Eghbali N (2010) Green chemistry: principles and practice. Chem Soc Rev 39:301–312CrossRefPubMed

Aroso IM, Paiva A, Reis RL, Duarte ARC (2017) Natural deep eutectic solvents from choline chloride and betaine—physicochemical properties. J Mol Liquids 241:654–661CrossRef

Bagh FSG, Shahbaz K, Mjalli FS et al (2013) Electrical conductivity of ammonium and phosphonium based deep eutectic solvents: measurements and artificial intelligence-based prediction. Fluid Phase Equilib 356:30–37CrossRef

Dai Y, Spronsen J, Witkamp GJ et al (2013) Natural deep eutectic solvents as new potential media for green technology. Anal Chim Acta 85:61–68CrossRef

Davis SJ (2015) Deep eutectic solvents derived from inorganic salts. Ph.D. dissertation. University of Leicester

Degam G (2017) Deep eutectic solvents synthesis, characterization and applications in pretreatment of lignocellulosic biomass. Ph.D. dissertation. South Dakota State University

Dios SLG (2013) Phase equilibria for extraction processes with designer solvents. Ph.D. dissertation. University of Santiago de Compostela

Durand E, Lecomte J, Baréa B et al (2012) Evaluation of deep eutectic solvents as new media for Candida antarctica B lipase catalyzed reactions. Process Biochem 47:2081–2089CrossRef

Francisco M, Bruinhorst A, Kroon MC (2013) Low-transition-temperature mixtures (LTTMs): a new generation of designer solvents. Angew Chem Int Ed 52:3074–3085CrossRef

Galbe M, Zacchi G (2007) Pretreatment of lignocellulosic materials for efficient bioethanol production. Adv Biochem Eng Biotechnol 108:41–65PubMed

Hayyan A, Mjalli FS, AlNashef IM et al (2012) Fruit sugar-based deep eutectic solvents and their physical properties. Termochim Acta 541:70–75CrossRef

Hayyan M, Hashim MA, Al-Saadi MA et al (2013) Assessment of cytotoxicity and toxicity for phosphonium-based deep eutectic solvents. Chemosphere 93:455–459CrossRefPubMed

Haz A, Strizincova P, Majova V et al (2016) Thermal stability of selected deep eutectic solvents. Int J Recent Sci Res 7:14441–14444

Hendriks AT, Zeeman G (2009) Pretreatments to enhance the digestibility of lignocellulosic biomass. Bioresour Technol 100:10–18CrossRefPubMed

Huddleston JG, Visser AE, Reichert WM et al (2001) Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation. Green Chem 3:156–164CrossRef

Jablonsky M, Skulcova A, Hascicova Z et al (2016) Contribution of deep eutectic solvents for separation processing. In: Application of analytical methods in environmental and fire engineering. Technical University in Zvolen, Zvolen

Jablonsky M, Majova V, Skulcova A, Haz A (2018a) Delignification of pulp using deep eutectic solvents. JHED 22:76–81

Jablonsky M, Skulcova A, Malvis A, Sima J (2018b) Extraction of value-added components from food industry based and agro-forest biowastes by deep eutectic solvents. J Biotechnol 282:46–66CrossRefPubMed

Kareem MA, Mjalli FS, Hashim MA, AlNashef IM (2010) Phosphonium-based ionic liquids analogues and their physical properties. J Chem Eng Data 55:4632–4637CrossRef

Khandelwal S, Tailor YK, Kumar M (2016) Deep eutectic solvents (DESs) as eco-friendly and sustainable solvent/catalyst systems in organic transformations. J Mol Liquids 215:345–386CrossRef

Kudłak B, Owczarek K, Namieśnik J (2015) Selected issues related to the toxicity of ionic liquids and deep eutectic solvents—a review. Environ Sci Pollut Res 22:11975–11992CrossRef

Kumar AK, Parikh BS, Pravakar M (2016a) Natural deep eutectic solvent mediated pretreatment of rice straw: bioanalytical characterization of lignin extract and enzymatic hydrolysis of pretreated biomass residue. Environ Sci Pollut Res 23:9265–9275CrossRef

Kumar AK, Parikh BS, Shah E, Liu LZ, Cotta MA (2016b) Cellulosic ethanol production from green solvent-pretreated rice straw. Biocatal Agric Biotechnol 7:14–23CrossRef

Li X, Row KH (2017) Application of novel ternary deep eutectic solvents as a functional monomer in molecularly imprinted polymers for purification of levofloxacin. J Chromatogr B 1068:56–63

Lindholm CA (1990) Effect of dissolved reaction products on pulp viscosity in low consistency ozone bleaching. Paper Timber 72:254–256

Liu TY, Chen YA, Xing YJ (2014) Synthesis and characterization of novel ternary deep eutectic solvents. Chin Chem Lett 25:104–106CrossRef

Loow YL, New EK, Yang GH et al (2017) Potential use of deep eutectic solvents to facilitate lignocellulosic biomass utilization and conversion. Cellulose 24:3591–3618CrossRef

Lynam JG, Kumar N, Wong MJ (2017) Deep eutectic solvents’ ability to solubilize lignin, cellulose, and hemicellulose; thermal stability; and density. Bioresour Technol 238:684–689CrossRefPubMed

Majova V, Horanova S, Skulcova A et al (2017) Deep eutectic solvent delignification: impact of initial lignin. BioResources 12:7301–7310

Osch DJGP, Kollau LJBM, Bruinhorst A et al (2017) Ionic liquids and deep eutectic solvents for lignocellulosic biomass fractionation. Phys Chem Chem Phys 19:2636–2665CrossRefPubMed

Rydholm SA (1966) Pulping processes, 2nd edn. Wiley, New York

Shahbaz K, Baroutian S, Mjalli FS (2012) Densities of ammonium and phosphonium based deep eutectic solvents: prediction using artificial intelligence and group contribution techniques. Thermochim Acta 527:59–66CrossRef

Shahbaz K, Mjalli FS, Vakili-Nezhaad G (2016) Thermogravimetric measurement of deep eutectic solvents vapor pressure. J Mol Liquids 222:61–66CrossRef

Smith EL, Abbot AP, Ryder KS (2014) Deep eutectic solvents (DESs) and their applications. Chem Rev 114:11060–11082CrossRefPubMed

Soares B, Tavares DJ, Amaral JL (2017) Enhanced solubility of lignin monomeric model compounds and technical lignins in aqueous solutions of deep eutectic solvents. ACS Sustain Chem Eng 5:4056–4065CrossRef

Steichen M, Thomassey M, Siebentritt S, Dale PJ (2011) Controlled electrodeposition of Cu–Ga from a deep eutectic solvent for low cost fabrication of CuGaSe2 thin film solar cells. Phys Chem Chem Phys 13:4292–4302CrossRefPubMed

TAPPI T236cm-85 (1996) Kappa number of pulp. TAPPI Press, Atlanta

Trajano HL, Wyman CE (2013) Fundamentals of biomass pretreatment at low pH. In: Wyman CE (ed) Aqueous pretreatment of plant biomass for biological and chemical conversion to fuels and chemical. Wiley, New York, pp 103–128CrossRef

Troter DZ, Todorovic Z, Dokić-Stojanović DR (2017) The physico-chemical and thermodynamic properties of the choline chloride-based deep eutectic solvents. J Serb Chem Soc 82:1039–1052CrossRef

Yan YC, Rashmi W, Khalid M et al (2017) Potential application of deep eutectic solvents in heat transfer application. JESTEC 12:1–14

Zhang Q, Vigier K, Royer S, Jérôme F (2012) Deep eutectic solvents: syntheses, properties and applications. Chem Soc Rev 41:7108–7146CrossRefPubMed

Titel: Preparation and characterization of physicochemical properties and application of novel ternary deep eutectic solvents
verfasst von: Michal Jablonsky
Veronika Majova
Katarina Ondrigova
Jozef Sima
Publikationsdatum: 09.02.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 5/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02322-2

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