nach oben

Erschienen in:

03.08.2019 | Original Research

Pickering emulsions stabilized by hydrophobically modified nanocellulose containing various structural characteristics

verfasst von: Chunxia Tang, Yumeng Chen, Jianhui Luo, May Yin Low, Zengqian Shi, Juntao Tang, Zhen Zhang, Baoliang Peng, Kam C. Tam

Erschienen in: Cellulose | Ausgabe 13-14/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Cellulose nanocrystals (CNCs) and cellulose nanofibrils (CNFs) extracted from renewable resources possess many attractive characteristics, making them ideal Pickering emulsion stabilizers. However, unmodified pristine CNCs with high surface charge density are not effective in stabilizing oil–water emulsions, thereby limiting their application as interfacial stabilizers. Grafting hydrophobic polymers onto CNCs enhanced their wettability by the oil phase, which reduced the interfacial tension. Thus, hydrophobic modification was performed by grafting cinnamoyl chloride or butyryl chloride to the surface of CNFs. The modified CNFs were further hydrolyzed for 1 or 2 h to produce nanocellulose of varying sizes and hydrophobicity, and they were effective Pickering emulsifiers. The effect of nanocellulose concentration, polarity of solvents, hydrophobicity, size and electrolyte on the characteristics of the Pickering emulsions were examined and elucidated.

Graphic abstract

Vorheriger Artikel Facile manufacture of cellulose nanoparticles in high yields by efficient cleavage of hydrogen bonds via mechanochemical synergy

Nächster Artikel Enhancing the redispersibility of TEMPO-mediated oxidized cellulose nanofibrils in N,N-dimethylformamide by modification with cetyltrimethylammonium bromide

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Ali M, McCoy TM, McKinnon IR et al (2017) Synthesis and characterization of graphene oxide-polystyrene composite capsules with aqueous cargo via a water–oil–water multiple emulsion templating route. ACS Appl Mater Interfaces. https://doi.org/10.1021/acsami.7b02576 CrossRefPubMed

Aveyard R, Binks BP, Clint JH (2003) Emulsions stabilised solely by colloidal particles. Adv Colloid Interface Sci 100–102:503–546. https://doi.org/10.1016/S0001-8686(02)00069-6 CrossRef

Bai L, Huan S, Xiang W, Rojas OJ (2018) Pickering emulsions by combining cellulose nanofibrils and nanocrystals: phase behavior and depletion stabilization. Green Chem. https://doi.org/10.1039/c8gc00134k CrossRef

Binks BP (2002) Particles as surfactants—similarities and differences. Curr Opin Colloid Interface Sci 7:21–41. https://doi.org/10.1016/S1359-0294(02)00008-0 CrossRef

Binks BP, Isa L, Tyowua AT (2013) Direct measurement of contact angles of silica particles in relation to double inversion of Pickering emulsions. Langmuir 29:4923–4927. https://doi.org/10.1021/la4006899 CrossRefPubMed

Capron I, Cathala B (2013) Surfactant-free high internal phase emulsions stabilized by cellulose nanocrystals. Biomacromol 14:291–296. https://doi.org/10.1021/bm301871k CrossRef

Chevalier Y, Bolzinger M-A (2013) Emulsions stabilized with solid nanoparticles: Pickering emulsions. Colloids Surf A Physicochem Eng Asp 439:23–34. https://doi.org/10.1016/j.colsurfa.2013.02.054 CrossRef

Cui Z-G, Shi K-Z, Cui Y-Z, Binks BP (2008) Double phase inversion of emulsions stabilized by a mixture of CaCO3 nanoparticles and sodium dodecyl sulphate. Colloids Surf A Physicochem Eng Asp 329:67–74. https://doi.org/10.1016/j.colsurfa.2008.06.049 CrossRef

Cunha AG, Mougel JB, Cathala B et al (2014) Preparation of double Pickering emulsions stabilized by chemically tailored nanocelluloses. Langmuir 30:9327–9335. https://doi.org/10.1021/la5017577 CrossRefPubMed

Destribats M, Gineste S, Laurichesse E et al (2014a) Pickering emulsions: what are the main parameters determining the emulsion type and interfacial properties? Langmuir 30:9313–9326. https://doi.org/10.1021/la501299u CrossRefPubMed

Destribats M, Rouvet M, Gehin-Delval C et al (2014b) Emulsions stabilised by whey protein microgel particles: towards food-grade Pickering emulsions. Soft Matter 10:6941–6954. https://doi.org/10.1039/C4SM00179F CrossRefPubMed

Gestranius M, Stenius P, Kontturi E et al (2017) Phase behaviour and droplet size of oil-in-water Pickering emulsions stabilised with plant-derived nanocellulosic materials. Colloids Surf A Physicochem Eng Asp 519:60–70. https://doi.org/10.1016/j.colsurfa.2016.04.025 CrossRef

Haaj SB, Thielemans W, Magnin A, Boufi S (2014) Starch nanocrystal stabilized Pickering emulsion polymerization for nanocomposites with improved performance. ACS Appl Mater Interfaces 6:8263–8273. https://doi.org/10.1021/am501077e CrossRefPubMed

Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110:3479–3500. https://doi.org/10.1021/cr900339w CrossRefPubMed

Hu Z, Ballinger S, Pelton R, Cranston ED (2015) Surfactant-enhanced cellulose nanocrystal Pickering emulsions. J Colloid Interface Sci 439:139–148. https://doi.org/10.1016/j.jcis.2014.10.034 CrossRefPubMed

Huang J, Cheng F, Binks BP, Yang H (2015) pH-responsive gas–water–solid interface for multiphase catalysis. J Am Chem Soc 137:15015–15025. https://doi.org/10.1021/jacs.5b09790 CrossRefPubMed

Jiao B, Shi A, Wang Q, Binks BP (2018) High-internal-phase Pickering emulsions stabilized solely by peanut-protein-isolate microgel particles with multiple potential applications. Angew Chem Int Ed. https://doi.org/10.1002/anie.201801350 CrossRef

Kalashnikova I, Bizot H, Cathala B, Capron I (2011) New Pickering emulsions stabilized by bacterial cellulose nanocrystals. Langmuir 27:7471–7479. https://doi.org/10.1021/la200971f CrossRefPubMed

Kalashnikova I, Bizot H, Bertoncini P et al (2013) Cellulosic nanorods of various aspect ratios for oil in water Pickering emulsions. Soft Matter 9:952–959. https://doi.org/10.1039/c2sm26472b CrossRef

Kumar V, Bollström R, Yang A et al (2014) Comparison of nano- and microfibrillated cellulose films. Cellulose 21:3443–3456. https://doi.org/10.1007/s10570-014-0357-5 CrossRef

Kumar V, Elfving A, Koivula H et al (2016) Roll-to-roll processed cellulose nanofiber coatings. Ind Eng Chem Res 55:3603–3613. https://doi.org/10.1021/acs.iecr.6b00417 CrossRef

Lee K, Blaker JJ, Murakami R et al (2014) Phase behavior of medium and high internal phase water-in-oil emulsions stabilized solely by hydrophobized bacterial cellulose nano fibrils. Langmuir. https://doi.org/10.1021/la4032514 CrossRefPubMedPubMedCentral

Pang B, Liu H, Liu P et al (2018) Water-in-oil Pickering emulsions stabilized by stearoylated microcrystalline cellulose. J Colloid Interface Sci 513:629–637. https://doi.org/10.1016/j.jcis.2017.11.079 CrossRefPubMed

Pecastaings G (2013) Dispersibility and emulsion-stabilizing effect of cellulose nanowhiskers esterified by vinyl acetate and vinyl cinnamate. Biomacromolecules. https://doi.org/10.1021/bm400854n CrossRefPubMed

Rayner M, Marku D, Eriksson M et al (2014) Biomass-based particles for the formulation of Pickering type emulsions in food and topical applications. Colloids Surf A Physicochem Eng Asp. https://doi.org/10.1016/j.colsurfa.2014.03.053 CrossRef

Saelices CJ, Capron I (2018) Design of Pickering micro-and nanoemulsions based on the structural characteristics of nanocelluloses. Biomacromolecules. https://doi.org/10.1021/acs.biomac.7b01564 CrossRef

Salas C, Nypelö T, Rodriguez-Abreu C et al (2014) Nanocellulose properties and applications in colloids and interfaces. Curr Opin Colloid Interface Sci 19:383–396. https://doi.org/10.1016/j.cocis.2014.10.003 CrossRef

Seìbe G, Ham-Pichavant F, Pecastaings G (2013) Dispersibility and emulsion-stabilizing effect of cellulose nanowhiskers esterified by vinyl acetate and vinyl cinnamate. Biomacromolecules 14:2937–2944. https://doi.org/10.1021/bm400854n CrossRef

Silmore KS, Gupta C, Washburn NR (2016) Tunable Pickering emulsions with polymer-grafted lignin nanoparticles (PGLNs). J Colloid Interface Sci 466:91–100. https://doi.org/10.1016/j.jcis.2015.11.042 CrossRefPubMed

Tang J, Lee MFX, Zhang W et al (2014) Dual responsive Pickering emulsion stabilized by poly[2-(dimethylamino)ethyl methacrylate] grafted cellulose nanocrystals. Biomacromolecules 15:3052–3060. https://doi.org/10.1021/bm500663w CrossRefPubMed

Tang J, Quinlan PJ, Tam KC (2015) Stimuli-responsive Pickering emulsions: recent advances and potential applications. Soft Matter 11:3512–3529. https://doi.org/10.1039/c5sm00247h CrossRefPubMed

Tang J, Sisler J, Grishkewich N, Tam KC (2017) Functionalization of cellulose nanocrystals for advanced applications. J Colloid Interface Sci 494:397–409. https://doi.org/10.1016/j.jcis.2017.01.077 CrossRefPubMed

Tang C, Spinney S, Shi Z et al (2018) Amphiphilic cellulose nanocrystals for enhanced Pickering emulsion stabilization. Langmuir 34:12897–12905. https://doi.org/10.1021/acs.langmuir.8b02437 CrossRefPubMed

Werner A (2017) Polymer chemistry by acetylated cellulose nanocrystals. Polym Chem 28:6064–6072. https://doi.org/10.1039/c7py01203a CrossRef

Whitby CP, Krebsz M (2014) Coalescence in concentrated Pickering emulsions under shear. Soft Matter 10:4848–4854. https://doi.org/10.1039/c4sm00491d CrossRefPubMed

Xu X, Liu F, Jiang L et al (2013) Cellulose nanocrystals vs. cellulose nano fibrils: a comparative study on their microstructures and effects as polymer reinforcing agents. ACS Appl Mater Interface. https://doi.org/10.1021/am302624t CrossRef

Xu HN, Li YH, Zhang L (2018) Driving forces for accumulation of cellulose nanofibrils at the oil/water interface. Langmuir 34:10757–10763. https://doi.org/10.1021/acs.langmuir.8b02310 CrossRefPubMed

Yang F, Liu S, Xu J et al (2006) Pickering emulsions stabilized solely by layered double hydroxides particles: the effect of salt on emulsion formation and stability. J Colloid Interface Sci 302:159–169. https://doi.org/10.1016/j.jcis.2006.06.015 CrossRefPubMed

Zhang Y, Karimkhani V, Makowski BT et al (2017) Nanoemulsions and nanolatexes stabilized by hydrophobically functionalized cellulose nanocrystals. Macromolecules. https://doi.org/10.1021/acs.macromol.7b00982 CrossRefPubMedPubMedCentral

Zhou J, Qiao X, Binks BP et al (2011) Magnetic Pickering emulsions stabilized by Fe₃O₄ nanoparticles. Langmuir 27:3308–3316. https://doi.org/10.1021/la1036844 CrossRefPubMed

Zoppe JO, Venditti RA, Rojas OJ (2012) Pickering emulsions stabilized by cellulose nanocrystals grafted with thermo-responsive polymer brushes. J Colloid Interface Sci 369:202–209. https://doi.org/10.1016/j.jcis.2011.12.011 CrossRefPubMed

Titel: Pickering emulsions stabilized by hydrophobically modified nanocellulose containing various structural characteristics
verfasst von: Chunxia Tang
Yumeng Chen
Jianhui Luo
May Yin Low
Zengqian Shi
Juntao Tang
Zhen Zhang
Baoliang Peng
Kam C. Tam
Publikationsdatum: 03.08.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 13-14/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02648-x

Springer Professional

Abstract

Graphic abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 13-14/2019

Fracture modes of bamboo fiber bundles in three-point bending

Facile fabrication of robust fluorine-free superhydrophobic cellulosic fabric for self-cleaning, photocatalysis and UV shielding

Subcritical CO2-assisted autohydrolysis for the co-production of oligosaccharides and fermentable sugar from corn straw

Procion Blue H-5R functionalized cellulose membrane with specific removal of bilirubin

Enriched mechanical, UV shielding and flame retarding properties of cotton fabric coated with graphite nano platelets filled polyaniline–gum arabic nanocomposites

Surface modification of oriented polysaccharide scaffolds using biotic nanofibers for epidermal cell culture