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15.11.2019 | Original Research

Preparation of fluorescent cellulose nanocrystal polymer composites with thermo-responsiveness through light-induced ATRP

verfasst von: Junyu Chen, Liucheng Mao, Hongxu Qi, Dazhuang Xu, Hongye Huang, Meiying Liu, Yuanqing Wen, Fengjie Deng, Xiaoyong Zhang, Yen Wei

Erschienen in: Cellulose | Ausgabe 2/2020

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Abstract

In recent years, cellulose nanocrystal (CNC) based materials have attracted great research attention for different applications owing to their unique properties and facile modification chemistry. In this work, CNC based thermo-responsive fluorescent composites were successfully prepared via the metal-free surface-initiated atom transfer radical polymerization (ATRP) of NIPAAm and a Schiff base containing dye (HDPAP). Results demonstrated CNC-poly (NIPAAm–HDPAP) composites display sensitive temperature-responsive coil-to-globule transition behavior at the temperature of lower critical solution temperature. The bright fluorescence offered by the Schiff base dye (HDPAP) was also confirmed by fluorescence spectra. Moreover, the preparation method of light meditated ATRP was proved to become the promising way in fabrication of multifunctional nanomaterials for its incomparable advantages, including low energy consumption, high efficiency, good monomer adaptation, free of transition metal ions.

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Vorheriger Artikel One-step hydrothermal synthesis of a flexible nanopaper-based Fe3+ sensor using carbon quantum dot grafted cellulose nanofibrils

Nächster Artikel Preparation of high molecular weight pH-responsive lignin-polyethylene glycol (L-PEG) and its application in enzymatic saccharification of lignocelluloses

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Titel: Preparation of fluorescent cellulose nanocrystal polymer composites with thermo-responsiveness through light-induced ATRP
verfasst von: Junyu Chen
Liucheng Mao
Hongxu Qi
Dazhuang Xu
Hongye Huang
Meiying Liu
Yuanqing Wen
Fengjie Deng
Xiaoyong Zhang
Yen Wei
Publikationsdatum: 15.11.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 2/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02845-8

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