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20.10.2020 | Original Research

Direct pretreatment of raw ramie fibers using an acidic deep eutectic solvent to produce cellulose nanofibrils in high purity

verfasst von: Wang Yu, Chaoyun Wang, Yongjian Yi, Hongying Wang, Yuanru Yang, Liangbin Zeng, Zhijian Tan

Erschienen in: Cellulose | Ausgabe 1/2021

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Abstract

Due to biomass recalcitrance, the pulping and bleaching processes are usually needed to break down the resistance of the lignocellulosic matrix for nanocellulose extraction. In this study, an acidic deep eutectic solvent (DES) based on choline chloride-oxalic acid dihydrate was used to directly pretreat raw ramie fibers (RFs) without further bleaching/purification steps for producing cellulose nanomaterials. Raw RFs, DES pretreated RFs, and degummed RFs were comparatively studied as starting materials for the preparation of cellulose nanofibrils (CNFs) by ball milling. There was no significant difference between CNF samples prepared from the DES pretreated RFs after 6 h of ball milling and those from the degummed RFs after 12 h of ball milling. After 4 h DES pretreatment at 100 °C, the obtained CNFs had a high purity of glucan up to 90.31% and an average width of 14.29 nm. They also showed high crystallinity (79.17%) and high thermal stability (> 316.7 °C). The tensile strength and elastic modulus for the CNF films were 98.071 MPa and 2.749 GPa, respectively. Overall, with the choline chloride-oxalic acid dihydrate DES pretreatment, no additional pulping/bleaching processes were required for the preparation of nanocellulose from raw cellulosic fibers while the properties of the as-prepared nanocellulose were preserved.

Graphic abstract

Vorheriger Artikel Exponential decay analysis: a flexible, robust, data-driven methodology for analyzing sorption kinetic data

Nächster Artikel Enhancing cellulose nanofibrillation of eucalyptus Kraft pulp by combining enzymatic and mechanical pretreatments

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Titel: Direct pretreatment of raw ramie fibers using an acidic deep eutectic solvent to produce cellulose nanofibrils in high purity
verfasst von: Wang Yu
Chaoyun Wang
Yongjian Yi
Hongying Wang
Yuanru Yang
Liangbin Zeng
Zhijian Tan
Publikationsdatum: 20.10.2020
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03538-3

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