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Journal of Materials Science
Erschienen in: Journal of Materials Science 20/2018

27.06.2018 | Biomaterials

Effective poly(ethylene glycol) methyl ether grafting technique onto Nylon 6 surface to achieve resistance against pathogenic bacteria Staphylococcus aureus and Pseudomonas aeruginosa

verfasst von: Sumita Swar, Veronika Zajícová, Jana Müllerová, Petra Šubrtová, Jana Horáková, Bohumil Dolenský, Michal Řezanka, Ivan Stibor

Erschienen in: Journal of Materials Science | Ausgabe 20/2018

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Abstract

Our study is focused on an efficient reduction of amide functional groups to secondary amine on Nylon 6 surface with borane–tetrahydrofuran (BH3–THF) complex, followed by N-alkylation with benzyl chloride (C6H5CH2Cl) which has been successfully used as a model system for further grafting of the reduced Nylon 6 surface by poly(ethylene glycol) methyl ether tosylate (Me-PEG-OTs). The amine-activated surface has been obtained by treatment of reduced Nylon 6 with n-butyllithium or tert-butyllithium in THF. Modified Nylon 6 has been found to be antibacterial particularly due to the presence of hydrophilic poly(ethylene glycol) methyl ether (H3C-PEG) chains. The surface modifications were successfully characterized by various techniques. Water contact angle and free surface energy analyses indicated a significant change in the surface morphology. It was further supported by scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy and Raman spectroscopy. Finally, antibacterial tests were performed against two pathogenic bacterial strains Pseudomonas aeruginosa (CCM 3955) and Staphylococcus aureus (CCM 3953).
Vorheriger Artikel Crosslinked fibroin nanoparticles using EDC or PEI for drug delivery: physicochemical properties, crystallinity and structure
Nächster Artikel Novel nanohybrid biocatalyst: application in the kinetic resolution of secondary alcohols

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Metadaten
Titel
Effective poly(ethylene glycol) methyl ether grafting technique onto Nylon 6 surface to achieve resistance against pathogenic bacteria Staphylococcus aureus and Pseudomonas aeruginosa
verfasst von
Sumita Swar
Veronika Zajícová
Jana Müllerová
Petra Šubrtová
Jana Horáková
Bohumil Dolenský
Michal Řezanka
Ivan Stibor
Publikationsdatum
27.06.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 20/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2636-2

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