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Journal of Materials Science
Erschienen in: Journal of Materials Science 5/2019

21.11.2018 | Composites

Improving the electroactive phase, thermal and dielectric properties of PVDF/graphene oxide composites by using methyl methacrylate-co-glycidyl methacrylate copolymers as compatibilizer

verfasst von: Shixin Song, Zaihang Zheng, Yuanjing Bi, Xue Lv, Shulin Sun

Erschienen in: Journal of Materials Science | Ausgabe 5/2019

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Abstract

In this work, graphene oxide sheets (GO) filled polyvinylidene fluoride (PVDF) nanodielectric composites with methyl methacrylate-co-glycidyl methacrylate copolymer (MG) as compatibilizer were fabricated by solution blend process. MG improved the dispersion of GO and enhanced the interface strength between GO and PVDF matrix. The strong dipolar interaction between MG on the surface of GO and PVDF resulted in the crystal transformation of PVDF from α-phase to β/γ-phase and nearly 81% β/γ-phase PVDF formed for PVDF/MG@GO7.0 composite. The thermal stability, mechanical property, melting and crystallization behaviors of PVDF/MG@GO composites were improved obviously due to the enhanced interface strength between GO and PVDF matrix with the aid of MG. MG copolymers not only contributed to the uniform dispersion of GO in PVDF, but also prevented the direct connection of GO and effectively inhibited the occurrence of leakage current in composites. Therefore, the dielectric properties of PVDF/MG@GO composites were also enhanced significantly with the addition of MG compared with the PVDF/GO composites, which supported the fact that the dielectric properties of resulted composites could be tailored by using MG copolymer as compatibilizer.
Vorheriger Artikel Preparation, characterization and catalytic performance of polyoxometalate immobilized on the surface of halloysite
Nächster Artikel Improvement of mechanical properties and thermal conductivity of carbon fiber laminated composites through depositing graphene nanoplatelets on fibers

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Metadaten
Titel
Improving the electroactive phase, thermal and dielectric properties of PVDF/graphene oxide composites by using methyl methacrylate-co-glycidyl methacrylate copolymers as compatibilizer
verfasst von
Shixin Song
Zaihang Zheng
Yuanjing Bi
Xue Lv
Shulin Sun
Publikationsdatum
21.11.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 5/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-3075-9

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