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Journal of Materials Science
Erschienen in: Journal of Materials Science 5/2019

26.11.2018 | Metals

Formulation of Al–Bi–Sn immiscible alloys versus the solidification behaviors and structures

verfasst von: Peng Jia, Yue Li, Xun Hu, Jinyang Zhang, Xinying Teng, Degang Zhao, Qifeng Chen, Min Zuo, Qing Liu, Cheng Yang

Erschienen in: Journal of Materials Science | Ausgabe 5/2019

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Abstract

In this work, the Al100−x(Bi45Sn55)x (x = 5, 15, 25 and 35) alloys with varied elemental compositions were prepared to understand the correlations of the elemental composition with the solidification behaviors and structures of the alloys. The results showed that the Sfh, Smc, S c-s 2 (Sn–Bi-rich, Al-rich) and S c-s 3 (Sn–Bi-rich, Al-rich, Sn–Bi-rich) structures were formed successively with the decreasing aluminum content, due to the increased aggregation degree of droplets. The increased aggregation resulted from (1) the increased width of the miscibility gap (from 0 to 146 K); (2) the increased volumetric fraction of the minority phase particles (from 8.91 to 49.98%); (3) the increased time of the L–LPS (from 0 to 0.46 s); (4) the decreased solidification rate (from 10.2 to 4.6 mm s−1). The exchange of core and shell occurred in as-cast Al–Bi–Sn immiscible alloys. The quantitative relationship between the composition and the collision probability of droplets was established to reveal the inner reasons for structural evolution. In addition, the hot-spot effect of the lower melting point droplets was responsible for the coarser monotectic structure around the lower melting point particles. The results from this work are a useful reference for regulating structural configuration of immiscible alloys via manipulating the composition.
Vorheriger Artikel Characterization of hot deformation behavior and constitutive modeling of Al–Mg–Si–Mn–Cr alloy
Nächster Artikel The role of Cu content on structure and magnetic properties of Fe–Si–B–P–Cu nanocrystalline alloys

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Metadaten
Titel
Formulation of Al–Bi–Sn immiscible alloys versus the solidification behaviors and structures
verfasst von
Peng Jia
Yue Li
Xun Hu
Jinyang Zhang
Xinying Teng
Degang Zhao
Qifeng Chen
Min Zuo
Qing Liu
Cheng Yang
Publikationsdatum
26.11.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 5/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-3128-0

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