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Journal of Materials Science
Erschienen in: Journal of Materials Science 7/2020

22.11.2019 | Materials for life sciences

Synthesis and physico-chemical properties of poly(N-vinyl pyrrolidone)-based hydrogels with titania nanoparticles

verfasst von: Olesya Timaeva, Igor Pashkin, Sergey Mulakov, Galina Kuzmicheva, Petr Konarev, Raisa Terekhova, Natalia Sadovskaya, Orsolya Czakkel, Sylvain Prevost

Erschienen in: Journal of Materials Science | Ausgabe 7/2020

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Abstract

Poly(N-vinyl pyrrolidone) (PVP)-based hydrogels with titania nanoparticles (TN) were synthesized by the sol–gel method for the first time and were characterized in different states (native, freeze-dried, air-dried to constant weight and ground to powder, or swollen to constant weight in H2O or D2O) by various methods such as wide-angle and small-angle X-ray and neutron scattering, neutron spin-echo (NSE) spectroscopy, and scanning electron microscopy. The static (static polymer–polymer correlation length (mesh size), associates of cross-links and PVP microchains) and dynamic (polymer chain relaxation rate, hydrodynamic polymer–polymer correlation length) structural elements were determined. The incorporation of titania nanoparticles into PVP hydrogel slightly increases the size of structural inhomogeneities (an increase in the static and dynamic polymer–polymer correlation length, the formation of associates of cross-links and PVP chains). Titania nanoparticles have an impact on the microstructure of the composite hydrogel and form associates with sizes from 0.5 to 2 µm attached to PVP hydrogel pore walls. The PVP and TN/PVP hydrogels show a high degree of water swelling. Moreover, the presence of titania nanoparticles in TN/PVP increases the number of water adsorption cycles compared to PVP hydrogel. The high swelling degree, bacteria-resistant and antimicrobial properties against Staphylococcus aureus allow considering NT/PVP hydrogels for medical applications as wound coatings.
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Metadaten
Titel
Synthesis and physico-chemical properties of poly(N-vinyl pyrrolidone)-based hydrogels with titania nanoparticles
verfasst von
Olesya Timaeva
Igor Pashkin
Sergey Mulakov
Galina Kuzmicheva
Petr Konarev
Raisa Terekhova
Natalia Sadovskaya
Orsolya Czakkel
Sylvain Prevost
Publikationsdatum
22.11.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 7/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-04230-z

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