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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 2/2018

12.10.2017

Effect of Ni2+ substitution on crystal structure and microwave dielectric properties for MgZrNb2O8 ceramics

verfasst von: Mi Xiao, Jie Lou, Yanshuang Wei, Hongrui Sun, Lei Li, Ping Zhang

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 2/2018

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Abstract

Monoclinic structured Mg1−xNixZrNb2O8 (0 ≤ x ≤ 0.12) ceramics were synthesized for the first time through traditional solid-state reaction process and pure phase were obtained in all range. Rietveld refinement was used to analyze the crystal structure. With the increase of Ni2+ substitution amount, ε r decreased, Q × f rose first then fell, τ f shifted for the positive direction. Bond ionicity, lattice energy and bond energy were separately calculated to investigate the correlations with microwave dielectric properties. Typically, ceramics samples with the composition of Mg0.92Ni0.08ZrNb2O8 sintered at 1280 °C for 4 h exhibited the optimum microwave dielectric properties: ε r  = 24.58, Q × f = 74534.1 GHz, τ f  = − 49.11 ppm/°C, which could be a promising material for application.
Vorheriger Artikel Ultrasonic-assisted synthesis of ZnO/NiO nanocomposites and kinetic study of their photocatalytic activity
Nächster Artikel Sintering behaviors and microwave dielectric properties of Ti-modified Ba3Ti5Nb6O28 ceramics with 35BaO–35ZnO–30B2O3 addition

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Metadaten
Titel
Effect of Ni2+ substitution on crystal structure and microwave dielectric properties for MgZrNb2O8 ceramics
verfasst von
Mi Xiao
Jie Lou
Yanshuang Wei
Hongrui Sun
Lei Li
Ping Zhang
Publikationsdatum
12.10.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 2/2018
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-7996-x

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