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Journal of Materials Science: Materials in Electronics

Erschienen in:

17.05.2018

Carbon modified porous γ-Fe₂O₃ as anode for high performance Li-ion batteries

verfasst von: Chaoyu Duan, Yanshuang Meng, Mengqi Du, Lei Wang, Yue Zhang

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 14/2018

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Abstract

Carbon modified porous γ-Fe₂O₃ particles (PFe₂O₃–C) are synthesized by a high temperature calcination method using sodium chloride as a template. During the nucleation and carbonation process, the Fe(NO₃)₃–C₁₀H₁₅N₅ complex uniformly dispersed on the surface of NaCl particles which can limit its longitudinal growth, thus forming independent and homogeneous nanoparticles with a diameter of about 30 nm. Because of this special structure, the γ-Fe₂O₃ particles have a sufficient interspace between them, which can not only provide a large number of active sites for storing lithium ions, but also shorten diffusion length for lithium ion transport. The introduction of carbon can offer additional lithium ion storage and improve overall electrical conductivity. This PFe₂O₃–C electrode exhibits excellent rate performance (1139, 1067, and 972 mAh g⁻¹ at 2, 5, and 10 C, respectively, 1 C = 924 mAh g⁻¹) and cycle performance (up to 2100 mAh g⁻¹ after 200 cycles at 0.3 C).

Vorheriger Artikel Luminescent property and application research of red molybdate phosphors for W-LEDs

Nächster Artikel Hydrothermal synthesis of mesoporous TiO2–ZnO nanocomposite for photocatalytic degradation of methylene blue under UV and visible light

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Titel: Carbon modified porous γ-Fe2O3 as anode for high performance Li-ion batteries
verfasst von: Chaoyu Duan
Yanshuang Meng
Mengqi Du
Lei Wang
Yue Zhang
Publikationsdatum: 17.05.2018
Verlag: Springer US
Erschienen in: Journal of Materials Science: Materials in Electronics / Ausgabe 14/2018
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-018-9295-6

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