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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 5/2020

28.01.2020

Investigation on acetone sensing properties and mechanism of p-type Cr2WO6 nanoparticles

verfasst von: Chen Tian, Min Zhou, Zhongqiu Hua, Wenjing Yuan, Yi Wu, Xuemin Tian, Tao Song

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 5/2020

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Abstract

In the present work, gas sensors based on Cr2WO6 nanoparticles were fabricated by a screen-printing technique, and the sensing properties were characterized with acetone and other typical reducing gases under both dry and humid air backgrounds. Interestingly, it was found that Cr2WO6 sensors showed a p-type conduction characteristic with a highly sensitive response to acetone vapor in a relatively low concentration. In the presence of humidity, resistances of Cr2WO6 sensors were significantly increased; nevertheless, sensor responses were obviously inhibited. In addition, the basic sensing mechanism of Cr2WO6 sensor was also investigated based on oxygen adsorption behavior and catalytic properties of Cr2WO6 surface. According to experimental results, it is proposed that the resistive responses of Cr2WO6 sensor to reducing gases were highly oxygen-dependent, indicating that the surface oxygen adsorption and reaction also played the basic role in the sensing process as that observed in typical n-type MOS sensors. Additionally, sensors also suffered from a high cross-sensitivity to water vapor due to the competition of chemisorption of water and oxygen on the surface of Cr2WO6.
Vorheriger Artikel Preparation and electrical properties of 4-acetoxystyrene grafted polypropylene for HVDC cable insulation
Nächster Artikel Electron migration between inter and intra particles in the soft-template processed titania nanospheres and its influences in the photovoltaic performance of the dye-sensitized solar cells

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Literatur
1.
A. Mirzaei, S.G. Leonardi, G. Neri, Detection of hazardous volatile organic compounds (VOCs) by metal oxide nanostructures-based gas sensors: a review. Cream. Int. 42, 15119–15141 (2016)
2.
K. Wetchakuna, T. Samerjaia, N. Tamaekonga, C. Liewhirana, C. Siriwonga et al., Semiconducting metal oxides as sensors for environmentally hazardous gases. Sens. Actuators B 160, 580–591 (2011)
3.
A. Turner, C. Walton, S. Hoashi, M. Evans, Breath acetone concentration decreases with blood glucose concentration in type I diabetes mellitus patients during hypoglycaemic clamps. J. Breath Res. 3, 046004 (2009)
4.
N. Teshima, J. Li, K. Toda, P.K. Dasgupta, Determination of acetone in breath. Anal. Chim. Acta 535, 189–199 (2005)
5.
M. Hübner, C.E. Simion, A. Haensch, N. Bârsan, U. Weimar, CO sensing mechanism with WO3 based gas sensors. Sens. Actuators B 151, 103–106 (2010)
6.
Y. Zeng, Z.Q. Hua, X.M. Tian, X. Li, Z.L. Qiu, et al., Selective detection of methanol by zeolite/Pd-WO3 gas sensors. Sens. Actuators B 273, 1291–1299 (2018)
7.
H. Steffes, C. Imawan, F. Solzbacher, E. Obermeier, Enhancement of NO2 sensing properties of In2O3-based thin films using an Au or Ti surface modification. Sens. Actuators B 78, 106–112 (2001)
8.
V. Oison, L. Saadi, C. Lambert-Mauriat, R. Hayn, Mechanism of CO and O3 sensing on WO3 surfaces: first principle study. Sens. Actuators B 160, 505–510 (2011)
9.
A. Ponzoni, V. Russo, A. Bailini, C.S. Casari, M. Ferroni et al., Structural and gas-sensing characterization of tungsten oxide nanorods and nanoparticles. Sens. Actuators B 153, 340–346 (2011)
10.
S.F. Bamsaoud, S.B. Rane, R.N. Karekar, R.C., Aiyer, Nano particulate SnO2 based resistive films as a hydrogen and acetone vapour sensor. Sens. Actuators B 153, 382–391 (2011)
11.
Z.Q. Hua, Y. Li, Y. Zeng, Y. Wu, A theoretical investigation of the power-law response of metal oxide semiconductor gas sensors Ι: Schottky barrier control. Sens. Actuators B 255, 1911–1919 (2018)
12.
N. Bârsan, U. Weimar, Conduction model of metal oxide gas sensors. J. Electroceram. 7, 143–167 (2001)
13.
Z.Q. Hua, Z.L. Qiu, Y. Li, Y. Zeng, Y. Wu et al., A theoretical investigation of the power-law response of metal oxide semiconductor gas sensors ΙI: Size and shape effects. Sens. Actuators B 255, 3541–3549 (2018)
14.
N. Yamazoe, K. Shimanoe, Receptor function of small semiconductor crystals with clean and electron-traps dispersed surfaces. Thin Solid Films 517, 6148–6155 (2009)
15.
N. Yamazoe, K. Suematsu, K. Shimanoe, Two types of moisture effects on the receptor function of neat tin oxide gas sensor to oxygen. Sens. Actuators B 176, 443–452 (2011)
16.
N. Yamazoe, K. Suematsu, K. Shimanoe, Extension of receptor function theory to include two types of adsorbed oxygen for oxide semiconductor gas sensors. Sens. Actuators B 163, 128–135 (2012)
17.
L.L. Wang, J.N. Deng, Z. Lou, T. Zhang, Nanoparticles-assembled Co3O4 nanorods p-type nanomaterials: one-pot synthesis and toluene-sensing properties. Sens. Actuators B 201, 1–6 (2014)
18.
N. Bârsan, C. Simion, T. Heine, S. Pokhrel, U. Weimar, Modeling of sensing and transduction for p-type semiconducting metal oxide based gas sensors. J. Electroceram. 25, 11–19 (2010)
19.
J. Du, Y.Q. Wu, K.L. Choy, P.H. Shipway, Structure, properties and gas sensing behavior of Cr2−xTixO3 films fabricated by electrostatic spray assisted vapour deposition. Thin Solid Films 519, 1293–1299 (2010)
20.
G. S. Henshaw, D. H. Dawson, D. E. Williams, selectivity and composition dependence of response of gas-sensitive resistors Part 2.-hydrogen sulfide response of Cr2-xTixO3+y. J. Mater. Chem. 5, 1791–1800 (1995)
21.
J.W. Yoona, J.H. Lee, Toward breath analysis on a chip for disease diagnosis using semiconductor-based chemiresistors: recent progress and future perspectives. Lab Chip. 17, 3537–3557 (2017)
22.
Z.Y. Zhang, Z. Wen, Z.Z. Ye, L.P. Zhu, Gas sensors based on ultrathin porous Co3O4 nanosheets to detect acetone at low temperature. RSC Adv. 5, 59976–59982 (2015)
23.
S. Wicker, K. Großmann, N. Bârsan, U. Weimar, Co3O4-A systematic investigation of catalytic and gas sensing performance under variation of temperature, humidity, test gas and test gas concentration. Sens. Actuators B 185, 644–650 (2013)
24.
M. Hübner, C.E. Simion, A. Tomescu- Stănoiu, S. Pokhrel, N. Bârsan, U. Weimar, Influence of humidity on CO sensing with p-type CuO thick film gas sensors. Sens. Actuators B 153, 347–353 (2011)
25.
A. Luyo, R. Ionescu, L.F. Reyes, Z. Topalian, W. Estrada et al., Gas sensing response of NiO nanoparticle films made by reactive gas deposition. Sens. Actuators B 138, 14–20 (2009)
26.
H.J. Kim, J.H. Lee, Highly sensitive and selective gas sensors using p-type oxide semiconductors: overview. Sens. Actuators B 192, 607–627 (2014)
27.
S. Pokhrel, C.E. Simion, V. Quemener, N. Bârsan, U. Weimar, Investigations of conduction mechanism in Cr2O3 gas sensing thick films by ac impedance spectroscopy and work function changes measurements. Sens. Actuators B 133, 78–83 (2008)
28.
G. Chabanis, I.P. Parkin, D.E. Williams, Microspheres of the gas sensor material Cr2-2xTixO3 prepared by the sol–emulsion–gel route. J. Mater. Chem. 11, 1651–1655 (2001)
29.
G.A. Shaw, K.F.E. Pratt, I.P. Parkin, D.E. Williams, Gas sensing properties of thin film (≤3m) Cr2−xTixO3(CTO) prepared by atmospheric pressure chemical vapour deposition (APCVD), compared with that prepared by thick film screen-printing. Sens. Actuators B 104, 151–162 (2005)
30.
G.A. Shaw, I.P. Parkin, D.E. Williams, Atmospheric pressure chemical vapour deposition of Cr2-xTi xO3 (CTO) thin films (≤3μm) on to gas sensing substrates. Mater. Chem. 13, 2957–2962 (2003)
31.
D.E. Williams, Semiconducting oxides as gas-sensitive resistors. Sens. Actuators B 57, 1–16 (1999)
32.
W.M. Zhou, J.F. Huang, J.Y. Li, Z.W. Xu, L.Y. Cao, C.Y. Yao, J. Lu, Cr2WO6 nanoparticles prepared by hydrothermal assisted method with selective adsorption properties for methylene blue in water. Mater. Sci. Semicond. Process. 34, 170–174 (2015)
33.
S. Walia, R. Weber, S. Sriram, M. Bhaskaran, K. Latham, S. Zhuiykov, K. Kalantar-zadeh, Sb2Te3 and Bi2Te3 based thermopower wave sources. Energy Environ. Sci. 4, 3558–3564 (2011)
34.
I. Grohmann, E. Kemnitz, A. Lippitz, W.E.S. Unger, Curve fitting of Cr 2p photoelectron spectra of Cr2O3 and CrF3. Surf. Interface Anal. 23, 887–891 (1995)
35.
X.H. Ding, D.W. Zeng, S.P. Zhang, C.S. Xie, C-doped WO3 microtubes assembled by nanoparticles with ultrahigh sensitivity to toluene at low operating temperature. Sens. Actuators B 155, 86–92 (2011)
36.
J. Zhang, X.H. Liu, M. Xu, X.Z. Guo, S.H. Wu, S.M. Zhang, S.R. Wang, Pt clusters supported on WO3 for ethanol detection. Sens. Actuators B 147, 185–190 (2010)
37.
J.C. Dupin, D. Gonbeau, P. Vinatier, A. Levasseur, Sea, hydroxides and peroxides. Phys. Chem. Chem. Phys. 2, 1319–1324 (2000)
38.
L. Fang, B. Davis, H.Y. Lu, J.R. Lombardi, Resonance Raman spectroscopy of mass selected chromium trimers in an argon matrix. J. Phys. Chem. A 105, 9375–9378 (2001)
39.
T. Baer, P.M. Guyon, Autoionization and isotope effect in the threshold photoelectron spectrum of 12CO2 and 13CO2. J. Chem. Phys. 85(9), 4765–4778 (1986)
40.
A. Baserga, V. Russo, F. Di Fonzo, A. Bailini, D. Cattaneo, C.S. Casari, A. Li Bassi, C.E. Bottani, Nanostructured tungsten oxide with controlled properties: synthesis and Raman characterization. Thin Solid Films 515, 6465–6469 (2007)
41.
Z.L. Qiu, X.M. Tian, Y. Li, Y. Zeng, C. Fan, M.J. Wang, Z.Q. Hua, NH3 sensing properties and mechanism of Ru-loaded WO3 nanosheets. J. Mater. Sci. Mater. Electron. 29, 11336–11344 (2018)
42.
Z.Q. Hua, M. Yuasa, T. Kida, N. Yamazoe, K. Shimanoe, H2 sensing mechanism of Pd-loaded WO3 nanoparticle gas sensors. Chem. Lett. 43, 1435–1437 (2014)
43.
M. Epifani, T. Andreu, C.R. Magana, R. Diaz, J. Arbiol, P. Siciliano, J.R. Morante, From doping to phase transformation: ammonia sensing performances of chloroalkoxide-derived WO3 powders modified with chromium. Sens. Actuators B 148, 200–206 (2010)
44.
Y. Li, Z.Q. Hua, Y. Wu, Y. Zeng, X.M. Tian, M.J. Wang, E.P. Li, Modified impregnation synthesis of Ru-loaded WO3 nanoparticles for acetone sensing. Sens. Actuators B 265, 249–256 (2018)
45.
Y. Li, Z.Q. Hua, Y. Wu, Y. Zeng, Z.L. Qiu, X.M. Tian, M.J. Wang, Surface modification of Pt-loaded WO3 nanosheets for acetone sensing application. Chem. Lett. 47, 167–170 (2018)
46.
S.M. Li, L.X. Zhang, M.Y. Zhu, G.J. Ji, L.X. Zhao, J. Yin, L.J. Bie, Acetone sensing of ZnO nanosheets synthesized using room-temperature precipitation. Sens. Actuators B 249, 611–623 (2017)
47.
P. Gao, H.M. Ji, Y.G. Zhou, X.L. Li, Selective acetone gas sensors using porous WO3–Cr2O3 thin films prepared by sol–gel method. Thin Solid Films 520, 3100–3106 (2012)
48.
T.T. Zhou, T. Zhang, J.A. Deng, R. Zhang, Z. Lou, L.L. Wang, P-type Co3O4 nanomaterials-based gas sensor: preparation and acetone sensing performance. Sens. Actuators B 242, 369–377 (2017)
49.
S.F. Xia, H.C. Zhu, H.T. Cai, J.Q. Zhang, J. Yu, Z.A. Tang, 2014, Hydrothermal synthesized CuO based volatile organic compound gas sensor. RSC Adv. 4, 57975–57982 (2014)
50.
L.C. Sun, Z.J. Yao, A.A. Haidry, Z. Li, Q. Fatima, L.J. Xie, Facile one-step synthesis of TiO2 microrods surface modified with Cr2O3 nanoparticles for acetone sensor applications. J. Mater. Sci. Mater. Electron. 29, 14546–14556 (2018)
51.
S. Pitchera, J.A. Thielea, H. Renb, J.F. Vetelino, Current/voltage characteristics of a semiconductor metal oxide gas sensor. Sens. Actuators B 93, 454–462 (2003)
52.
N. Bârsan, U. Weimar, Understanding the fundamental principles of metal oxide based gas sensors; the example of CO sensing with SnO2 sensors in the presence of humidity. J. Phys. 15, 813–839 (2003)
53.
N. Ma, K. Suematsu, M. Yuasa, T. Kida, K. Shimanoe, Effect of water vapor on Pd-loaded SnO2 nanoparticles gas sensor. ACS Appl. Mater. Interfaces 7, 5863–5869 (2015)
54.
Z.Q. Hua, C. Tian, D. Huang, W.J. Yuan, C.S. Zhang et al., Power-law response of metal oxide semiconductor gas sensors to oxygen in presence of reducing gases. Sens. Actuators B 267, 510–518 (2018)
55.
P.K. Clifford, D.T. Tuma, Characteristics of semiconductor gas sensors I. Steady state gas response. Sens. Actuators B 3, 233–254 (1983)
56.
A. Staerz, C. Berthold, T. Russ, S. Wicker, U. Weimar, N. Bârsan, The oxidizing effect of humidity on WO3 based sensors. Sens. Actuators B Chem. 237, 54–58 (2016)
Metadaten
Titel
Investigation on acetone sensing properties and mechanism of p-type Cr2WO6 nanoparticles
verfasst von
Chen Tian
Min Zhou
Zhongqiu Hua
Wenjing Yuan
Yi Wu
Xuemin Tian
Tao Song
Publikationsdatum
28.01.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 5/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-02935-5

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