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Journal of Polymer Research

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01.08.2016 | Original Paper

Synthesis and characterization of poly (ethyl methacrylate)-b-poly(dimethyl siloxane)-b-poly(ethyl methacrylate) triblock copolymer: the effect of solvent on morphology

verfasst von: Mohammad Ali Semsarzadeh, Maral Ghahramani

Erschienen in: Journal of Polymer Research | Ausgabe 8/2016

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Abstract

Atom transfer radical polymerization (ATRP) of ethyl methacrylate (EMA) was carried out at 80 °C using poly(dimethyl siloxane) (PDMS) bifunctional macroinitiator, copper chloride (CuCl) catalyst, and N, N, N^′, N^″, N^″-penta methyl diethyl triamine (PMDETA) ligand in toluene solvent. The final microstructure and kinetic of polymerization of the PEMA-b-PDMS-b-PEMA block copolymer were analyzed by ¹H-NMR, FT-IR and gel permeation chromatography (GPC) techniques. The effect of solvent on self-assembly and morphology of PEMA-b-PDMS-b-PEMA triblock copolymer is reported. Intrinsic viscosity measurements, UV absorption and thermodynamic properties evaluations were indicated that certain interactions existed between this block copolymer and acetone, toluene and dichloromethane (DCM) solvents before film formation. The effect of solvent on the final morphology of PEMA-b-PDMS-b-PEMA block copolymer was studied by transmission electron microscopy (TEM) and atomic force microscopy (AFM) analyses. The morphology of the block copolymer was transformed from circular into cylindrical and branched as the solvent was changed from DCM into the toluene and acetone, respectively.

Vorheriger Artikel Study on the capacitive performance of polyaniline/activated carbon nanocomposite for supercapacitor application

Nächster Artikel Metal-polymer composites at liquid/liquid interfaces: new morphological investigations using ex situ and in situ studies

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Titel: Synthesis and characterization of poly (ethyl methacrylate)-b-poly(dimethyl siloxane)-b-poly(ethyl methacrylate) triblock copolymer: the effect of solvent on morphology
verfasst von: Mohammad Ali Semsarzadeh
Maral Ghahramani
Publikationsdatum: 01.08.2016
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 8/2016
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-016-1032-3

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