Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Polymer Research
Erschienen in: Journal of Polymer Research 10/2017

01.09.2017 | ORIGINAL PAPER

Research on methanol permeation of proton exchange membranes with incorporating ionic liquids

verfasst von: Quantong Che, Lei Liu, Ziyun Li, Yifu Wang, Lulu Wang, Jilin Wang, Lin Ma

Erschienen in: Journal of Polymer Research | Ausgabe 10/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Methanol permeation and conductivity of membrane materials are important factors to evaluate the feasibility of application as proton exchange membranes (PEMs) in direct methanol fuel cell (DMFC). The methanol permeation values of these composite membranes based on ionic liquids of trifluoroacetic propylamine (TFAPA) and the disubstituted imidazolium cations with different anions were summarized, and the methanol permeation behaviors were investigated in this work. Although these polymer/ionic liquid composite membranes displayed satisfactory conductivities, the relative selectivity values of conductivity to methanol permeability were lower than the value of Nafion® membrane. Moreover, polymerized ionic liquids (PILs) membranes showed the strong ability to hinder methanol permeation with a value around 10−11 cm2/s at 10 M methanol solution. The maximum relative selectivity value reached (2.23–1.76) × 106 S·s/cm3 for PVC-MIMCl membrane, which was near two orders of magnitude higher than the reported 2.47 × 104 S·s/cm3 for Nafion-117 membrane at 2 M methanol solution.
Vorheriger Artikel Fabrication of hydrophilic and hydrophobic site on polypropylene nonwoven for removal of bisphenol a from water: explorations on adsorption behaviors, mechanisms and configurational influence
Nächster Artikel Melt processing of biodegradable poly(lactic acid)/functionalized chitosan nanocomposite films: mechanical modeling with improved oxygen barrier and thermal properties

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Neves LA, Coelhoso IM, Crespo JG (2010) Methanol and gas crossover through modified Nafion membranes by incorporation of ionic liquid cations. J Membr Sci 360:363–370CrossRef
2.
Lin HD, Sun WM, Zhao CJ, Na H (2013) Self-assembly of multiwall carbon nanotubes on sulfonated poly (arylene ether ketone) as a proton exchange membrane. J Polym Res 20:306CrossRef
3.
Li PC, Liao GM, Kumar SR, Shih CM, Yang CC, Wang DM, Jessie Lue SJ (2016) Fabrication and characterization of chitosan nanoparticle-incorporated quaternized poly(vinyl alcohol) composite membranes as solid electrolytes for direct methanol alkaline fuel cells. Electrochim Acta 187:616–628CrossRef
4.
Pulido Ayazo JC, Suleiman D (2012) Supercritical fluid processing of Nafion® membranes: methanol permeability and proton conductivity. J Appl Polym Sci 124:145–154CrossRef
5.
Gao L, Kong TF, Guo GQ, Huo YP (2016) Proton conductive and low methanol permeable PVA-based zwitterionic membranes. Int J Hydrog Energy 41:20373–20384CrossRef
6.
Gloukhovski R, Tsur Y, Freger V (2017) A Nafion-filled polycarbonate tack-etched cmposite mmbrane with ehanced slectivity for drect mthanol fel clls. Fuel Cell 17:56–66CrossRef
7.
Martínez de Yuso MV, Cuberes MT, Romero V, Neves L, Coelhoso I, Crespo JG, Rodríguez-Castellón E, Benavente J (2014) Modification of a Nafion membrane by n-dodecyltrimethylammonium cation inclusion for potential application in DMFC. Int J Hydrog Energy 39:4023–4029CrossRef
8.
Almeida TP, Miyazaki CM, Paganin VA, Ferreira M, Saeki MJ, Perez J, Riul Jr A (2014) PEDOT:PSS self-assembled films to methanol crossover reduction in Nafion® membranes. Appl Surf Sci 323:7–12CrossRef
9.
Parthiban V, Akula S, Peera SG, Islam N, Sahu AK (2016) Proton conducting Nafion-sulfonated graphene hybrid membranes for direct methanol fuel cells with reduced methanol crossover. Energ Fuel 30:725–734CrossRef
10.
Li T, Zhong GM, Yang Y (2012) Methanol-blocking perfluorosulfonic acid composite membranes in direct methanol fuel cells. Prog Chem 22:522–536
11.
Yang CW, Chen CC, Chen KH, Cheng S (2017) Effect of pore-directing agents in SBA-15 nanoparticles on the performance of Nafion®/SBA-15n composite membranes for DMFC. J Membr Sci 526:106–117CrossRef
12.
Shen Y, Xi JY, Qiu XP, Zhu WT, Chen LQ (2007) PVDF-g-PSSA and SiO2 composite proton exchange membranes. Acta Chim Sin 65:1318–1324
13.
Bahavan Palani P, Kannan R, Rajashabala S, Rajendran S, Velraj G (2015) Effect of nano-composite on polyvinyl alcohol-based proton conducting membrane for direct methanol fuel cell applications. Ionics 21:507–513CrossRef
14.
Wu QX, Wang HN, Lu SF, Xu X, Liang DW, Xiang Y (2016) Novel methanol-blocking proton exchange membrane achieved via self-anchoring phosphotungstic acid into chitosan membrane with submicro-pores. J Membr Sci 500:203–210CrossRef
15.
Wang SH, Lin HL (2014) Poly (vinylidene fluoride-co-hexafluoropropylene)/polybenzimidazole blend nanofiber supported Nafion membranes for direct methanol fuel cells. J Power Sources 257:254–263CrossRef
16.
Dutta K, Das S, Patit PK (2016) Highly methanol resistant and selective ternary blend membrane composed of sulfonated PVdF-co-HFP, sulfonated polyaniline and nafion. J Appl Polym Sci 133:43294CrossRef
17.
Diaz LA, Abuin GC, Corti HR (2012) Methanol sorption and permeability in Nafion and acid-doped PBI and ABPBI membranes. J Membr Sci 411-412:35–44CrossRef
18.
Mahajan CV, Ganesan V (2013) Influence of hydrogen bonding effects on methanol and water diffusivities in acid−base polymer blend membranes of sulfonated poly(ether ether ketone) and base tethered polysulfone. J Phys Chem B 117:5315–5329CrossRef
19.
Li J, Cai WW, Ma LY, Zhang YF, Chen ZX, Cheng HS (2015) Towards neat methanol operation of direct methanol fuel cells: a novel self-assembled proton exchange membrane. Chem Commun 51:6556–6559CrossRef
20.
Mondal S, Soam S, Kundu PP (2015) Reduction of methanol crossover and improved electrical efficiency in direct methanol fuel cell by the formation of a thin layer on Nafion 117 membrane: Effect of dip-coating of a blend of sulphonated PVdF-co-HFP and PBI. J Membr Sci 474:140–147CrossRef
21.
Kim JH, Kim SK, Nam K, Kim DW (2012) Composite proton conducting membranes based on Nafion and sulfonated SiO2 nanoparticles. J Membr Sci 415-416:696–701CrossRef
22.
De Bonis C, Cozzi D, Mecheri B, D’Epifanio A, Rainer A, De Porcellinis D, Licoccia S (2014) Effect of filler surface functionalization on the performance of Nafion/Titanium oxide composite membranes. Electrochim Acta 147:418–425CrossRef
23.
Guzmán C, Alvarez A, Godínez LA, Ledesma-García J, Arriaga LG (2012) Evaluation of ZrO2 composite membrane operating at high temperature (100 °C) in direct methanol fuel cells. Int J Electrochem Sci 7:6106–6117
24.
Arbizzani C, Donnadio A, Pica M, Sganappa M, Varzi A, Casciolab M, Mastragostino M (2010) Methanol permeability and performance of Nafion–zirconium phosphate composite membranes in active and passive direct methanol fuel cells. J Power Sources 195:7751–7756CrossRef
25.
Cui YH, Baker AP, Xu X, Xiang Y, Wang L, Lavorgna M, Wu JW (2015) Enhancement of Nafion based membranes for direct methanol fuel cell applications through the inclusion of ammonium-X zeolite fillers. J Power Sources 294:369–376CrossRef
26.
Escudero-Cid R, Montiel M, Sotomayor L, Loureiro B, Fatás E, Ocón P (2015) Evaluation of polyaniline-Nafion® composite membranes for direct methanol fuel cells durability tests. Int J Hydrog Energy 40:8182–8192CrossRef
27.
Welton T (1999) Room-temperature ionic liquids. solvents for synthesis and catalysis. Chem Rev 99:2071–2083CrossRef
28.
Che QT, Chen N, Yu JM, Cheng SC (2016) Sulfonated poly(ether ether) ketone/polyurethane composites doped with phosphoric acids for proton exchange membranes. Solid State Ionics 289:199–206CrossRef
29.
Le Bideau J, Viau L, Vioux A (2011) Ionogels, ionic liquid based hybrid materials. Chem Soc Rev 42:907–925CrossRef
30.
Tseng LC, Kuo M, Lee RH (2016) An imidazolium iodide-containing hyperbranched polymer ionic liquid that improves the performance of dye-sensitized solar cells. J Polym Res 23:157CrossRef
31.
Zhao ZP, Zhou ZP, Zhong MQ (2015) Electrochemical properties of imidazole tetrafluoroborate ionic liquid grafted SPEEK proton exchange membrane doped by La2O3. Int J Electrochem Sci 10:5026–5035
32.
Che QT, Sun BY, He RH (2008) Preparation and characterization of new anhydrous, conducting membranes based on composites of ionic liquid trifluoroacetic propylamine and polymers of sulfonated poly (ether ether) ketone or polyvinylidenefluoride. Electrochim Acta 53:4428–4434CrossRef
33.
Che QT, He RH, Yang JS, Feng L, Savinell RF (2010) Phosphoric acid doped high temperature proton exchange membranes based on sulfonated polyetheretherketone incorporated with ionic liquids. Electrochem Commun 12:647–649CrossRef
34.
Che QT, Zhou L, Wang JL (2015) Fabrication and characterization of phosphoric acid doped imidazoliumionic liquid polymer composite membranes. J Mol Liq 206:10–18CrossRef
35.
Che QT, Zhu ZF, Chen N, Zhai X (2015) Methylimidazolium group-modified polyvinyl chloride (PVC) doped with phosphoric acid for high temperature proton exchange membranes. Mater Design 87:1047–1055CrossRef
36.
Tang JK, Wan LQ, Zhou Y, Ye LY, Zhou XH, Huang FR (2017) Synthesis and performance study of a novel sulfonated polytriazole proton exchange membrane. J Solid State Electrochem 21:725–734CrossRef
37.
Xu D, Xu JM, Wang XQ, Wang Z (2016) Excellent performance of resistance methanol of a novel sulfonated poly (aryl ether ketone sulfone)/poly (vinylalcohol) composite membrane for direct methanol fuel cell applications. Int J Hydrog Energy 41:20536–20548CrossRef
38.
Xu GX, Li J, Ma LY, Xiong J, Mansoor M, Cai WW, Cheng HS (2017) Performance dependence of swelling-filling treated Nafion membrane on nano-structure of macromolecular filler. J Membr Sci 534:68–72CrossRef
39.
Chi NTQ, Bae B, Kim D (2013) Electro-osmotic drag effect on the methanol permeation for sulfonated poly(ether ether ketone) and Nafion117 membranes. J Nanosci Nanotechnol 13:7529–7534CrossRef
40.
Ayazo JCP, Suleiman D (2012) Supercritical fluid processing of Nafion (R) membranes: Methanol permeability and proton conductivity. J Appl Polym Sci 124:145–154CrossRef
41.
Paneri A, Heo Y, Ehlert G, Cottrill A, Sodano H, Pintauro P, Moghaddam S (2014) Proton selective ionic graphene-based membrane for high concentration direct methanol fuel cells. J Membr Sci 467:217–225CrossRef
42.
Dang HS, Kim D (2012) Cross-linked poly(arylene ether ketone) electrolyte membranes with enhanced proton conduction for fuel cells. Int J Hydrog Energy 37:19007–19016CrossRef
43.
Li L, Zhang J, Wang YX (2003) Sulfonated poly(ether ether ketone) membranes for direct methanol fuel cell. J Membr Sci 226:159–167CrossRef
44.
Wei YS, Shen LB, Wang ZM, Yang WD, Zhu H, Liu HT (2011) A novel membrane for DMFC -Na2Ti3O7 nanotubes/Nafion® composite membrane. Int J Hydrog Energy 36:5088–5095CrossRef
45.
Sekhon SS, Park JS, Cho EK, Yoon YG, Kim CS, Lee WY (2009) Morphology studies of high temperature proton conducting membranes containing hydrophilic/hydrophobic ionic liquids. Macromolecules 42:2054–2062CrossRef
46.
Das S, Kumar P, Dutta K, Kundu PP (2014) Partial sulfonation of PVdF-co-HFP: A preliminary study and characterization for application in direct methanol fuel cell. Appl Energ 113:169–177CrossRef
47.
Yuan JY, Antonietti M (2011) Poly(ionic liquid)s: polymers expanding classical property profiles. Polymer 52:1469–1482CrossRef
48.
Díaz M, Ortiz A, Ortiz I (2014) Progress in the use of ionic liquids as electrolyte membranes in fuel cells. J Membr Sci 469:379–396CrossRef
49.
Lemus J, Eguizábal A, Pina MP (2015) UV polymerization of room temperature ionic liquids for high temperature PEMs: Study of ionic moieties and crosslinking effects. Int J Hydrog Energy 40:5416–5424CrossRef
50.
Jessie Lue SJ, Chen WW, Wu SY, Wang LD, Kuo CH (2008) Vapor permeation modeling of multi-component systems using a poly(dimethylsiloxane) membrane. J Membr Sci 311:380–389CrossRef
51.
Li X, Roberts EPL, Holmes SM (2006) Evaluation of composite membranes for direct methanol fuel cells. J Power Sources 154:115–123CrossRef
52.
Neelakandan S, Kanagaraj P, Sabarathinam RM, Nagendran A (2015) Polypyrrole layered SPEES/TPA proton exchange membrane for direct methanol fuel cells. Appl Surf Sci 359:272–279CrossRef
53.
Mack F, Aniol K, Ellwein C, Kerres J, Zeis R (2015) Novel phosphoric acid-doped PBI-blends as membranes for high-temperature PEM fuel cells. J Mater Chem A 3:10864–10874CrossRef
54.
Yue ZY, Cai YB, Xu SA (2016) Phosphoric acid-doped cross-linked sulfonated poly (imide-benzimidazole) for proton exchange membrane fuel cell applications. J Membr Sci 501:220–227CrossRef
55.
Aili D, Hansen MK, Pan C, Li QF, Christensen E, Jensen JO, Bjerrum NJ (2011) Phosphoric acid doped membranes based on Nafion (R), PBI and their blends - Membrane preparation, characterization and steam electrolysis testing. Int J Hydrogen Energ 36:6985–6993CrossRef
Metadaten
Titel
Research on methanol permeation of proton exchange membranes with incorporating ionic liquids
verfasst von
Quantong Che
Lei Liu
Ziyun Li
Yifu Wang
Lulu Wang
Jilin Wang
Lin Ma
Publikationsdatum
01.09.2017
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 10/2017
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-017-1331-3

Weitere Artikel der Ausgabe 10/2017

Journal of Polymer Research 10/2017 Zur Ausgabe

ORIGINAL PAPER

Nano-assembly of intertwining lamellae of opposite bending senses in poly(ethylene oxide) co-crystallizing with poly(p-vinyl phenol)

ORIGINAL PAPER

Identification of Cellulosimicrobium sp., a poly(3-hydroxybutyrate)-degrading bacterium isolated from washed rind cheese, Pont-l’évêque lait cru

ORIGINAL PAPER

Novel phosphorus-containing polyhedral Oligomeric Silsesquioxane functionalized Graphene oxide: preparation and its performance on the mechanical and flame-retardant properties of Bismaleimide composite

ORIGINAL PAPER

Non-cytotoxic poly(amino acid) with excellent thermo-sensitivity from L-lysine and L-aspartic acid as a hydrophobic drug carrier

ORIGINAL PAPER

An antibacterial composite system based on multi-responsive microgels hosting monodisperse gold nanoparticles

ORIGINAL PAPER

Preparation of random poly(butylene alkylate-co-terephthalate)s with different methylene group contents: crystallization and degradation kinetics

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise