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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 8/2018

01.08.2018 | ORIGINAL PAPER

Effect of interface on bulk polymer: control of glass transition temperature of rubber

verfasst von: Ya Wei, Haitao Wu, Gengsheng Weng, Yongqiang Zhang, Xijuan Cao, Zhouzhou Gu, Yong Liu, Rongjuan Liu, Zhiping Zhou, Yijing Nie

Erschienen in: Journal of Polymer Research | Ausgabe 8/2018

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Abstract

In current paper, we demonstrated that molecular dynamics and glass transition of rubber can be controlled by constructing attractive interface between rubber matrix and fillers. Based on a combination of experiments and molecular simulations, it was revealed that interfacial segmental mobility was reduced and glass transition temperatures (Tgs) of epoxidized natural rubber (ENR) were significantly improved due to in situ polymerization of zinc dimethacrylate (ZDMA). During curing, ZDMA polymerizes in rubber matrix, resulting in the appearance of nanodispersion phases of poly-ZDMA (PZDMA). It was demonstrated that coordination interaction exists between epoxy groups and PZDMA in interfacial regions. Furthermore, using dynamic Monte Carlo simulations, it was observed that the interfacial regions that have highest content of epoxy groups exhibit lowest segmental mobility. Then, the increase of ZDMA content leads to the rise of the fraction of absorbed interfacial segments, and thus the Tgs of filled rubbers are improved.
Vorheriger Artikel Chemical and in vitro characterization of epoxidized natural rubber blends for biomedical applications
Nächster Artikel Thermal, conductivity, and dielectric properties of poly(2-ethyl-2-oxazoline)-polyvinylpyrrolidone blends

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Metadaten
Titel
Effect of interface on bulk polymer: control of glass transition temperature of rubber
verfasst von
Ya Wei
Haitao Wu
Gengsheng Weng
Yongqiang Zhang
Xijuan Cao
Zhouzhou Gu
Yong Liu
Rongjuan Liu
Zhiping Zhou
Yijing Nie
Publikationsdatum
01.08.2018
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 8/2018
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-018-1566-7

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