Spectroscopic and electrical sensing mechanism in oxidant-mediated polypyrrole nanofibers/nanoparticles for ammonia gas

Ammonia gas sensing mechanism in oxidant-mediated polypyrrole (PPy) nanofibers/nanoparticles has been studied through spectroscopic and electrical investigations. PPy nanofibers/nanoparticles have been synthesized by chemical oxidation method in the presence of various oxidizing agents such as ammonium persulfate (APS), potassium persulfate (PPS), vanadium pentoxide (V₂O₅), and iron chloride (FeCl₃). Scanning electron microscopy study revealed that PPy nanofibers of about 63, 71 and 79 nm diameters were formed in the presence of APS, PPS, V₂O₅, respectively, while PPy nanoparticles of about 100–110 nm size were obtained in the presence of FeCl₃ as an oxidant. The structural investigations and confirmation of synthesis of PPy were established through Fourier transform infrared and Raman spectroscopy. The gas sensing behavior of the prepared PPy samples is investigated by measuring the electrical resistance in ammonia environment. The observed gas sensing response \( \left( {{{\Updelta R} \mathord{\left/ {\vphantom {{\Updelta R} R}} \right. \kern-0pt} R} \times 100} \right) \) at 100 ppm level of ammonia is ~4.5 and 18 % for the samples prepared with oxidizing agents FeCl₃ and APS, respectively, and by changing the ammonia level from 50 to 300 ppm, the sensing response varies from ~4.5 to 11 % and ~10 to 39 %, respectively. Out of all four samples, the PPy nanofibers prepared in the presence of APS have shown the best sensing response. The mechanism of gas sensing response of the PPy samples has been investigated through Raman spectroscopy study. The decrease of charge carrier concentration through reduction of polymeric chains has been recognized through Raman spectroscopic measurements recorded in ammonia environment.