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Tribology Letters
Erschienen in: Tribology Letters 1/2018

01.03.2018 | Original Paper

Direct Formation of Lubricious and Wear-Protective Carbon Films from Phosphorus- and Sulfur-Free Oil-Soluble Additives

verfasst von: Blake Johnson, Hongxing Wu, Michael Desanker, David Pickens, Yip-Wah Chung, Q. Jane Wang

Erschienen in: Tribology Letters | Ausgabe 1/2018

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Abstract

Extreme pressure (EP) lubricant additives form protective tribofilms at the site of contact using the heat and pressure of contact and relative motion. Common EP additives contain undesirable elements such as phosphorus and sulfur. A novel EP lubricant additive, which contains no phosphorus and sulfur, is presented for generating lubricious carbon films. The additive consists of a surface-active molecule with a metastable cycloalkane ring, which dissociates readily during tribological contact to form lubricious carbon films. Friction and wear performance of PAO4 with this additive under a range of loads and speeds were shown to be superior to that without the additive. Optical and scanning electron microscopy and Raman spectroscopy were used to analyze the tribofilms formed on post-test contact surfaces, providing direct evidence for the formation of carbon films. Quantitative kinetics for the carbon tribofilm formation was analyzed as a function of temperature and stress, from which the activation energy for carbon tribofilm formation was obtained.
Vorheriger Artikel The Role of the Counterbody’s Oxide on the Wear Behavior of HSS and Hi-Cr
Nächster Artikel Barrel Friction in Sport Rifles

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Metadaten
Titel
Direct Formation of Lubricious and Wear-Protective Carbon Films from Phosphorus- and Sulfur-Free Oil-Soluble Additives
verfasst von
Blake Johnson
Hongxing Wu
Michael Desanker
David Pickens
Yip-Wah Chung
Q. Jane Wang
Publikationsdatum
01.03.2018
Verlag
Springer US
Erschienen in
Tribology Letters / Ausgabe 1/2018
Print ISSN: 1023-8883
Elektronische ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-017-0945-2

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