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Erschienen in: Journal of Materials Engineering and Performance 7/2016

10.06.2016

A Novel Emulsion Flow Loop for Investigating the Corrosion of X65 Steel in Emulsions with H2S/CO2

verfasst von: Rihan Rihan, Muhammad Nauman Zafar, Luai Al-Hadhrami

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 7/2016

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Abstract

Corrosion resistance (R P) of X65 steel was investigated in an oil-in-water emulsion containing H2S and CO2 at several oil concentrations and different flow regions using a novel emulsion flow loop. One working electrode was mounted in the flow developing region while the other one was mounted in a region where the flow is fully developed. The experimental results show that the addition of CO2 to an H2S containing emulsion decreases the corrosion rate. The R P in the flow developing region is less than that in the fully developed region and it increases with increasing oil concentration. This flow loop is a promising tool for investigating the R P of engineering materials in a simulated environment similar to that encountered in the petroleum industry.

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Literatur
1.
Zurück zum Zitat L. Schramm, Emulsions: Fundamentals and Applications in the Petroleum Industry, The American Chemical Society, Washington, 1992CrossRef L. Schramm, Emulsions: Fundamentals and Applications in the Petroleum Industry, The American Chemical Society, Washington, 1992CrossRef
2.
Zurück zum Zitat A.O. Omer, Pipeline Flow Behavior of Water-in-Oil Emulsions, Ph.D. Dissertation, University of Waterloo, Ontario, 2009 A.O. Omer, Pipeline Flow Behavior of Water-in-Oil Emulsions, Ph.D. Dissertation, University of Waterloo, Ontario, 2009
3.
Zurück zum Zitat W.P. Jepson, and R. Menezes, The Effects of Oil Viscosity on Sweet Corrosion in Multiphase Oil, Water/Gas Horizontal Pipelines, NACE International Corrosion Conference and Expo, 1995 W.P. Jepson, and R. Menezes, The Effects of Oil Viscosity on Sweet Corrosion in Multiphase Oil, Water/Gas Horizontal Pipelines, NACE International Corrosion Conference and Expo, 1995
4.
Zurück zum Zitat M. Koteeswaran, CO2 and H2S Corrosion in Pipelines, University of Stavanger, M.S. Thesis, 2010 M. Koteeswaran, CO2 and H2S Corrosion in Pipelines, University of Stavanger, M.S. Thesis, 2010
5.
Zurück zum Zitat M. A. Kappes, Evaluation of Thiosulphate as a Substitute for Hydrogen Sulphide in Sour Corrosion Fatigue Studies, Ohio State University, Ohio, Ph.D. Dissertation, 2011 M. A. Kappes, Evaluation of Thiosulphate as a Substitute for Hydrogen Sulphide in Sour Corrosion Fatigue Studies, Ohio State University, Ohio, Ph.D. Dissertation, 2011
6.
Zurück zum Zitat B. Brown, S.R. Parakala, and S. Nesic, CO2 Corrosion in the Presence of Trace Amounts of H2S, NACE International Corrosion Conference and Expo, 2004 B. Brown, S.R. Parakala, and S. Nesic, CO2 Corrosion in the Presence of Trace Amounts of H2S, NACE International Corrosion Conference and Expo, 2004
7.
Zurück zum Zitat A.G. Wikjord, T.E. Rummery, F.E. Doern, and D.G. Owen, Corrosion and Deposition Duringthe Exposure of Carbon Steel to Hydrogen Sulphide-Water Solutions, Corros. Sci., 1980, 20, p 651–671CrossRef A.G. Wikjord, T.E. Rummery, F.E. Doern, and D.G. Owen, Corrosion and Deposition Duringthe Exposure of Carbon Steel to Hydrogen Sulphide-Water Solutions, Corros. Sci., 1980, 20, p 651–671CrossRef
8.
Zurück zum Zitat B.J. Berkowitz and F.H. Heubaum, The Role of Hydrogen in Sulfide Stress Cracking of Low Alloy Steels, Corrosion, 1984, 40, p 240–245CrossRef B.J. Berkowitz and F.H. Heubaum, The Role of Hydrogen in Sulfide Stress Cracking of Low Alloy Steels, Corrosion, 1984, 40, p 240–245CrossRef
9.
Zurück zum Zitat C. Zhou, S. Zheng, C. Chen, and G. Lu, The Effect of Partial Pressure of H2S on the Permeation of Hydrogen in Low Carbon Pipeline Steel, Corros. Sci., 2013, 67, p 184–192CrossRef C. Zhou, S. Zheng, C. Chen, and G. Lu, The Effect of Partial Pressure of H2S on the Permeation of Hydrogen in Low Carbon Pipeline Steel, Corros. Sci., 2013, 67, p 184–192CrossRef
10.
Zurück zum Zitat R.O. Rihan, Electrochemical Corrosion Behavior of X52 and X60 Steels in Carbon Dioxide Containing Saltwater Solution, Mater. Res., 2013, 16, p 227–236CrossRef R.O. Rihan, Electrochemical Corrosion Behavior of X52 and X60 Steels in Carbon Dioxide Containing Saltwater Solution, Mater. Res., 2013, 16, p 227–236CrossRef
11.
Zurück zum Zitat H. Li, J. Huang, D. Sormaz, and S. Nesic, A Free Open Source Mechanistic Model for Prediction of Mild Steel Corrosion, 17th International Corrosion Congress, Paper No. 2659, Las Vegas, 2008 H. Li, J. Huang, D. Sormaz, and S. Nesic, A Free Open Source Mechanistic Model for Prediction of Mild Steel Corrosion, 17th International Corrosion Congress, Paper No. 2659, Las Vegas, 2008
12.
Zurück zum Zitat S. Nesic, H. Li, J. Huang, and D. Sormaz, An Open Source Mechanistic Model for CO2/H2S Corrosion of Carbon Steel. NACE International Corrosion Conference and Expo, Paper No. 09572, Atlanta, 2009 S. Nesic, H. Li, J. Huang, and D. Sormaz, An Open Source Mechanistic Model for CO2/H2S Corrosion of Carbon Steel. NACE International Corrosion Conference and Expo, Paper No. 09572, Atlanta, 2009
13.
Zurück zum Zitat G.A. Zhang, Y. Zeng, X.P. Guo, F. Jiang, D.Y. Shi, and Z.Y. Chen, Electrochemical Corrosion Behaviour of Carbon Steel Under Dynamic High Pressure H2S/CO2 Environment, Corros. Sci., 2012, 65, p 37–47CrossRef G.A. Zhang, Y. Zeng, X.P. Guo, F. Jiang, D.Y. Shi, and Z.Y. Chen, Electrochemical Corrosion Behaviour of Carbon Steel Under Dynamic High Pressure H2S/CO2 Environment, Corros. Sci., 2012, 65, p 37–47CrossRef
14.
Zurück zum Zitat Y. Chen and W.P. Jepson, EIS Measurement for Corrosion Monitoring Under Multiphase Flow Conditions, Electrochim. Acta., 1999, 44, p 4453–4464CrossRef Y. Chen and W.P. Jepson, EIS Measurement for Corrosion Monitoring Under Multiphase Flow Conditions, Electrochim. Acta., 1999, 44, p 4453–4464CrossRef
15.
Zurück zum Zitat X. Zhou, and W.P. Jepson, Corrosion in Three Phase Oil/Water/Gas Slug Flow in Horizontal Pipes, NACE International Corrosion Conference & Expo, Paper No. 94026, Baltimore, 1994 X. Zhou, and W.P. Jepson, Corrosion in Three Phase Oil/Water/Gas Slug Flow in Horizontal Pipes, NACE International Corrosion Conference & Expo, Paper No. 94026, Baltimore, 1994
16.
Zurück zum Zitat Q.Y. Liu, L.J. Mao, and S.W. Zhou, Effects of Chloride Content on CO2 Corrosion of Carbon Steel in Simulated Oil and Gas Well Environments, Corros. Sci., 2014, 84, p 165–171CrossRef Q.Y. Liu, L.J. Mao, and S.W. Zhou, Effects of Chloride Content on CO2 Corrosion of Carbon Steel in Simulated Oil and Gas Well Environments, Corros. Sci., 2014, 84, p 165–171CrossRef
17.
Zurück zum Zitat S. Hassani, Erosion-Corrosion in CO2 Saturated Systems in Presence of Sand, Inhibitor, Oil and High Concentration of Salt, University of Tulsa, Ph.D. Dissertation, 2012 S. Hassani, Erosion-Corrosion in CO2 Saturated Systems in Presence of Sand, Inhibitor, Oil and High Concentration of Salt, University of Tulsa, Ph.D. Dissertation, 2012
18.
Zurück zum Zitat Y. Yang, B. Brown, and S. Nesic, Study of Protective Iron Carbonate Layer Dissolution in a CO2 Corrosion Environment, NACE Corrosion Conference and Expo, Salt Lake City, 2012 Y. Yang, B. Brown, and S. Nesic, Study of Protective Iron Carbonate Layer Dissolution in a CO2 Corrosion Environment, NACE Corrosion Conference and Expo, Salt Lake City, 2012
19.
Zurück zum Zitat S. Tsujikawa, T. Yamada, A. Miyasaka, M. Ueda, and S. Ando, Alternative for Evaluating Sour Gas Resistance of Low Alloy Steels and Corrosion Resistant Alloys, Corrosion, 1993, 34, p 409–419CrossRef S. Tsujikawa, T. Yamada, A. Miyasaka, M. Ueda, and S. Ando, Alternative for Evaluating Sour Gas Resistance of Low Alloy Steels and Corrosion Resistant Alloys, Corrosion, 1993, 34, p 409–419CrossRef
20.
Zurück zum Zitat M. Kappes, G.S. Frankel, N. Sridhar, and R.M. Carranza, Reaction Paths of Thiosulphate During Corrosion of Carbon Steel in Acidified Brines, J. Electrochem. Soc., 2012, 4, p C195–C204CrossRef M. Kappes, G.S. Frankel, N. Sridhar, and R.M. Carranza, Reaction Paths of Thiosulphate During Corrosion of Carbon Steel in Acidified Brines, J. Electrochem. Soc., 2012, 4, p C195–C204CrossRef
21.
Zurück zum Zitat F. Zanotto, V. Grassi, A. Balbo, C. Monticelli, and F. Zuccchi, Stress Corrosion Cracking of LDX 2101 Duplex Stainless Steel in Chloride Solutions in the Presence of Thiosulphate, Corros. Sci., 2014, 80, p 205–212CrossRef F. Zanotto, V. Grassi, A. Balbo, C. Monticelli, and F. Zuccchi, Stress Corrosion Cracking of LDX 2101 Duplex Stainless Steel in Chloride Solutions in the Presence of Thiosulphate, Corros. Sci., 2014, 80, p 205–212CrossRef
22.
Zurück zum Zitat M. Mullet, S. Boursiquot, and M. Abdelmoula, Surface Chemistry and Structural Properties of Mackinawite, Geochim. Cosmochim. Acta, 2002, 5, p 829–836CrossRef M. Mullet, S. Boursiquot, and M. Abdelmoula, Surface Chemistry and Structural Properties of Mackinawite, Geochim. Cosmochim. Acta, 2002, 5, p 829–836CrossRef
23.
Zurück zum Zitat M. Singer, J. Khamis, and S. Nesic, Experimental Study of Sour Top of the Line Corrosion Using a Novel Experimental Setup, Corrosion, 2013, 69, p 624–638CrossRef M. Singer, J. Khamis, and S. Nesic, Experimental Study of Sour Top of the Line Corrosion Using a Novel Experimental Setup, Corrosion, 2013, 69, p 624–638CrossRef
24.
Zurück zum Zitat W. Sun, S. Nesic, and S. Papavinasam, Kinetics of Iron Sulphide and Mixed Iron Sulphide/Carbonate Scale Precipitation in CO2/H2S Corrosion, NACE International Corrosion Conference and Expo, Paper No. 06644, New Orleans, 2006. W. Sun, S. Nesic, and S. Papavinasam, Kinetics of Iron Sulphide and Mixed Iron Sulphide/Carbonate Scale Precipitation in CO2/H2S Corrosion, NACE International Corrosion Conference and Expo, Paper No. 06644, New Orleans, 2006.
25.
Zurück zum Zitat Y.S. Choi, S. Nesic, and S. Ling, Effect of H2S on the CO2 Corrosion of Carbon Steel in Acidic Solutions, Electrochim. Acta., 2011, 56, p 1752–1760CrossRef Y.S. Choi, S. Nesic, and S. Ling, Effect of H2S on the CO2 Corrosion of Carbon Steel in Acidic Solutions, Electrochim. Acta., 2011, 56, p 1752–1760CrossRef
26.
Zurück zum Zitat M. Kappes, G.S. Frankel, N. Sridhar, and R.M. Carranza, Corrosion Behaviour of Carbon Steel in Acidified, Thiosulphate Containing Brines, Corrosion, 2012, 10, p 872–884CrossRef M. Kappes, G.S. Frankel, N. Sridhar, and R.M. Carranza, Corrosion Behaviour of Carbon Steel in Acidified, Thiosulphate Containing Brines, Corrosion, 2012, 10, p 872–884CrossRef
27.
Zurück zum Zitat Standard Operating Procedure for Dissolved Oxygen Micro Method, Winkler Titration, LG501, Revision 06, January 2007 Standard Operating Procedure for Dissolved Oxygen Micro Method, Winkler Titration, LG501, Revision 06, January 2007
28.
Zurück zum Zitat J. Villarreal, D. Laverde, and C. Fuentes, Carbon-Steel Corrosion in Multiphase Slug Flow and CO2, Corros. Sci., 2006, 48, p 2363–2379CrossRef J. Villarreal, D. Laverde, and C. Fuentes, Carbon-Steel Corrosion in Multiphase Slug Flow and CO2, Corros. Sci., 2006, 48, p 2363–2379CrossRef
29.
Zurück zum Zitat A. Davoodi, M. Pakshir, M. Babaiee, and G.R. Ebrahimi, A Comparative H2S Corrosion Study of 304L and 316L Stainless Steel in Acidic Media, Corros. Sci., 2011, 53, p 399–408CrossRef A. Davoodi, M. Pakshir, M. Babaiee, and G.R. Ebrahimi, A Comparative H2S Corrosion Study of 304L and 316L Stainless Steel in Acidic Media, Corros. Sci., 2011, 53, p 399–408CrossRef
30.
Zurück zum Zitat Q. Zhichao, X. Chunming, C. Zeliang, Z. Zhihong, and Z. Chun, Major Corrosion Factors in the CO2 and H2S Coexistent Environment and the Relative Anti-Corrosion Method: Taking Tazhongi Gas Field, Tarim Basin, Petrol. Explor. Dev., 2012, 39, p 256–260CrossRef Q. Zhichao, X. Chunming, C. Zeliang, Z. Zhihong, and Z. Chun, Major Corrosion Factors in the CO2 and H2S Coexistent Environment and the Relative Anti-Corrosion Method: Taking Tazhongi Gas Field, Tarim Basin, Petrol. Explor. Dev., 2012, 39, p 256–260CrossRef
31.
Zurück zum Zitat H. Takabe, and M. Ueda, The Formation Behaviour of Corrosion Protective Films of Low Cr Bearing Steels in CO2 Environments, NACE Corrosion Conference and Expo, Houston, 2001 H. Takabe, and M. Ueda, The Formation Behaviour of Corrosion Protective Films of Low Cr Bearing Steels in CO2 Environments, NACE Corrosion Conference and Expo, Houston, 2001
32.
Zurück zum Zitat K.L.J. Lee, and S. Nesic, EIS Investigation of CO2/H2S Corrosion, NACE Corrosion Conference and Expo, Houston, 2004 K.L.J. Lee, and S. Nesic, EIS Investigation of CO2/H2S Corrosion, NACE Corrosion Conference and Expo, Houston, 2004
33.
Zurück zum Zitat J.L. Li, H.X. Ma, S.D. Zhu, C.T. Qu, and Z.F. Yin, Erosion Resistance of Corrosion Scales Formed on API, P110 Carbon Steel, Corros. Sci., 2014, 86, p 101–107CrossRef J.L. Li, H.X. Ma, S.D. Zhu, C.T. Qu, and Z.F. Yin, Erosion Resistance of Corrosion Scales Formed on API, P110 Carbon Steel, Corros. Sci., 2014, 86, p 101–107CrossRef
34.
Zurück zum Zitat G.A. Zhang and Y.F. Cheng, Electrochemical Corrosion of X65 Pipe Steel in Oil/Water Emulsion, Corros. Sci., 2009, 51, p 901–907CrossRef G.A. Zhang and Y.F. Cheng, Electrochemical Corrosion of X65 Pipe Steel in Oil/Water Emulsion, Corros. Sci., 2009, 51, p 901–907CrossRef
35.
Zurück zum Zitat Z.L. Wang, J. Zhang, Z.M. Wang, L. Zhou, X. Han, Q.F. Li, and S. Gao, Emulsification Reducing the Corrosion Risk of Mild Steel in Oil-Brine Mixtures, Corros. Sci., 2014, 86, p 310–317CrossRef Z.L. Wang, J. Zhang, Z.M. Wang, L. Zhou, X. Han, Q.F. Li, and S. Gao, Emulsification Reducing the Corrosion Risk of Mild Steel in Oil-Brine Mixtures, Corros. Sci., 2014, 86, p 310–317CrossRef
Metadaten
Titel
A Novel Emulsion Flow Loop for Investigating the Corrosion of X65 Steel in Emulsions with H2S/CO2
verfasst von
Rihan Rihan
Muhammad Nauman Zafar
Luai Al-Hadhrami
Publikationsdatum
10.06.2016
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 7/2016
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-016-2031-6

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