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Journal of Materials Engineering and Performance
Erschienen in: Journal of Materials Engineering and Performance 9/2019

21.08.2019

Few-Layers Graphene Film and Copper Surface Morphology for Improved Corrosion Protection of Copper

verfasst von: Sultan Akhtar, Tahar Laoui, Ahmed Ibrahim, A. Madhan Kumar, Junaid Ahmed, Ihsan-ul-Haq Toor

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 9/2019

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Abstract

Graphene has shown excellent corrosion protection of copper (Cu). The corrosion protection of Cu is governed by the characteristics of the deposited graphene and Cu surface morphology underneath. In this work, graphene films (1-2, 4-5 layers) were deposited on Cu using a chemical vapor deposition by changing hydrogen (H2) concentration during the annealing stage. The chemical structure and surface microstructural features of graphene/Cu were inspected by Raman spectroscopy, scanning electron microscopy, transmission electron microscopy, and atomic force microscopy. The electrochemical corrosion performance of graphene/Cu was studied in 0.5 M sodium chloride solution using potentiodynamic polarization and electrochemical impedance spectroscopic measurements. The 1-2 layers of graphene and rough Cu surface were obtained for low H2 concentrations (0 and 2.5%), whereas high H2 concentrations, 20 and 50%, resulted in a smooth Cu surface and 4-5 layers of graphene. Our results showed that Cu with a smooth surface and multilayer graphene film exhibited the best corrosion resistance against electrochemical degradation. Tafel analysis revealed that Cu with 4-5 layers of graphene coating corroded nearly three orders of magnitude slower than the annealed Cu, without graphene coating. The results of this study can be useful for several applications where Cu is in close contact with salt species.
Vorheriger Artikel Effect of Process Parameters on the Mechanical Properties of Hastelloy X Alloy Fabricated by Selective Laser Melting
Nächster Artikel Effect of Powder Shape and Size on Rheological, Thermal, and Segregation Properties of Low-Pressure Powder Injection Molding Feedstocks

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Literatur
1.
B.P. Singh et al., The Production of a Corrosion Resistant Graphene Reinforced Composite Coating on Copper by Electrophoretic Deposition, Carbon, 2013, 61, p 47–56CrossRef
2.
V.K. Mittal et al., Formation and Characterization of Bi-layer Oxide Coating on Carbon-Steel for Improving Corrosion Resistance, Thin Solid Films, 2009, 517(5), p 1672–1676CrossRef
3.
Y. Chen et al., Fabrication and Anti-corrosion Property of Superhydrophobic Hybrid Film on Copper Surface and Its Formation Mechanism, Surf. Interface Anal., 2009, 41(11), p 872–877CrossRef
4.
J.S. Bunch et al., Impermeable Atomic Membranes from Graphene Sheets, Nano Lett., 2008, 8(8), p 2458–2462CrossRef
5.
O. Leenaerts, B. Partoens, and F.M. Peeters, Water on Graphene: Hydrophobicity and Dipole Moment Using Density Functional Theory, Phys. Rev. B, 2009, 79(23), p 235440CrossRef
6.
T. Kim, S. Lee, and H. Park, A Study of Water Transport as a Function of the Micro-Porous Layer Arrangement in PEMFCs, Int. J. Hydrog. Energy, 2010, 35(16), p 8631–8643CrossRef
7.
N.T. Kirkland et al., Exploring Graphene as a Corrosion Protection Barrier, Corros. Sci., 2012, 56, p 1–4CrossRef
8.
C. Liang et al., Hydrogen Etching Effect on Single-Crystal Graphene Domains. In: 2013 8th Annual IEEE International Conference on Nano/Micro Engineered and Molecular Systems (IEEE NEMS 2013), 2013: p 697–700
9.
D. Prasai et al., Graphene: Corrosion-Inhibiting Coating, ACS Nano, 2012, 6(2), p 1102–1108CrossRef
10.
R.K.S. Raman et al., Protecting Copper from Electrochemical Degradation by Graphene Coating, Carbon, 2012, 50(11), p 4040–4045CrossRef
11.
Y.H. Dong, Q.Q. Liu, and Q. Zhou, Corrosion Behavior of Cu during Graphene Growth by CVD, Corros. Sci., 2014, 89, p 214–219CrossRef
12.
A. Reina et al., Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition, Nano Lett., 2009, 9(1), p 30–35CrossRef
13.
Y.Q. Liang et al., Large-Scale Synthetic Graphene on Cu as Anti-Corrosion Coating by Chemical Vapor Deposition Approach, Sci. Adv. Mater., 2014, 6(3), p 545–549CrossRef
14.
A. Ibrahim et al., Effects of Annealing on Copper Substrate Surface Morphology and Graphene Growth by Chemical Vapor Deposition, Carbon, 2015, 94, p 369–377CrossRef
15.
W. Liu et al., Synthesis of High-Quality Monolayer and Bilayer Graphene on Copper Using Chemical Vapor Deposition, Carbon, 2011, 49(13), p 4122–4130CrossRef
16.
H. Kim et al., Activation Energy Paths for Graphene Nucleation and Growth on Cu, ACS Nano, 2012, 6(4), p 3614–3623CrossRef
17.
H. Wang et al., Controllable Synthesis of Submillimeter Single-Crystal Monolayer Graphene Domains on Copper Foils by Suppressing Nucleation (vol 134, pg 3627, 2012), J. Am. Chem. Soc., 2012, 134(44), p 18476–18476CrossRef
18.
S. Bhaviripudi et al., Role of Kinetic Factors in Chemical Vapor Deposition Synthesis of Uniform Large Area Graphene Using Copper Catalyst, Nano Lett., 2010, 10(10), p 4128–4133CrossRef
19.
Y.C. Shin and J. Kong, Hydrogen-Excluded Graphene Synthesis via Atmospheric Pressure Chemical Vapor Deposition, Carbon, 2013, 59, p 439–447CrossRef
20.
L. Gan and Z.T. Luo, Turning Off Hydrogen to Realize Seeded Growth of Subcentimeter Single-Crystal Graphene Grains on Copper, ACS Nano, 2013, 7(10), p 9480–9488CrossRef
21.
Z.J. Wang et al., Direct Observation of Graphene Growth and Associated Copper Substrate Dynamics by In Situ Scanning Electron Microscopy, ACS Nano, 2015, 9(2), p 1506–1519CrossRef
22.
X.F. Zhang et al., Hydrogen-Induced Effects on the CVD Growth of High-Quality Graphene Structures, Nanoscale, 2013, 5(18), p 8363–8366CrossRef
23.
D.H. Jung et al., Effects of Hydrogen Partial Pressure in the Annealing Process on Graphene Growth, J. Phys. Chem. C, 2014, 118(7), p 3574–3580CrossRef
24.
J. Song, T.Y. Ko, and S. Ryu, Raman Spectroscopy Study of Annealing-Induced Effects on Graphene Prepared by Micromechanical Exfoliation, Bull. Korean Chem. Soc., 2010, 31(9), p 2679–2682CrossRef
25.
Z.Z. Sun et al., Growth of Graphene from Solid Carbon Sources, Nature, 2010, 468(7323), p 549–552CrossRef
26.
X.C. Dong et al., Growth of Large-Sized Graphene Thin-Films by Liquid Precursor-Based Chemical Vapor Deposition under Atmospheric Pressure, Carbon, 2011, 49(11), p 3672–3678CrossRef
27.
J.C. Meyer et al., The Structure of Suspended Graphene Sheets, Nature, 2007, 446(7131), p 60–63CrossRef
28.
E. Widenkvist et al., Mild Sonochemical Exfoliation of Bromine-Intercalated Graphite: A New Route Towards Graphene, J. Phys. D Appl. Phys., 2009, 42, p 112003CrossRef
29.
A. Madhankumar et al., EIS Evaluation of Protective Performance and Surface Characterization of Epoxy Coating with Aluminum Nanoparticles After Wet and Dry Corrosion Test, J. Solid State Electrochem., 2012, 16(6), p 2085–2093CrossRef
30.
S. Akhtar et al., Enhancement of Anticorrosion Property of 304 Stainless Steel Using Silane Coatings, Appl. Surf. Sci., 2018, 440, p 1286–1297CrossRef
31.
A.V. Benedeti et al., Electrochemical Studies of Copper, Copper-Aluminium and Copper-Aluminium-Silver Alloys: Impedance Results in 0.5 M NaCl, Electrochim. Acta, 1995, 40(16), p 2657–2668CrossRef
32.
P.G. Pawar et al., Polystyrene Assisted Superhydrophobic Silica Coatings with Surface Protection and Self-Cleaning Approach, Prog. Org. Coat., 2017, 105, p 235–244CrossRef
33.
A.Y. Adesina, Z.M. Gasem, and A.M. Kumar, Corrosion Resistance Behavior of Single-Layer Cathodic Arc PVD Nitride-Base Coatings in 1 M HCl and 3.5 pct NaCl Solutions, Metall. Mater. Trans. B, 2017, 48(2), p 1321–1332CrossRef
34.
A.M. Kumar et al., Fabrication of Nitrogen Doped Graphene Oxide Coatings: Experimental and Theoretical Approach for Surface Protection, RSC Adv., 2015, 5(25), p 19264–19272CrossRef
35.
A.M. Kumar et al., Promising Hard Carbon Coatings on Cu Substrates: Corrosion and Tribological Performance with Theoretical Aspect, J. Mater. Eng. Perform., 2018, 27(5), p 2306–2316CrossRef
36.
S.D. Costa et al., Resonant Raman Spectroscopy of Graphene Grown on Copper Substrates, Solid State Commun., 2012, 152(15), p 1317–1320CrossRef
Metadaten
Titel
Few-Layers Graphene Film and Copper Surface Morphology for Improved Corrosion Protection of Copper
verfasst von
Sultan Akhtar
Tahar Laoui
Ahmed Ibrahim
A. Madhan Kumar
Junaid Ahmed
Ihsan-ul-Haq Toor
Publikationsdatum
21.08.2019
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 9/2019
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-019-04268-9

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