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International Journal of Plastics Technology

Erschienen in:

01.06.2015 | Research Article

Proton conducting solid polymer electrolytes based carboxymethyl cellulose doped ammonium chloride: ionic conductivity and transport studies

verfasst von: Nur Hidayah Binti Ahmad, Mohd Ikmar Nizam Bin Mohamad Isa

Erschienen in: International Journal of Plastics Technology | Ausgabe 1/2015

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Abstract

The present work focuses on the preparation of solid polymer electrolytes (SPEs) based carboxymethyl cellulose, CMC as host polymer doped with ammonium chloride, AC (0–20 wt.%) as ionic dopant via solution casting technique. The ionic conductivity and transport parameter of SPEs films were analyzed using electrical impedance spectroscopy in the frequency range of 1 Hz–50 MHz at selected temperature of 303–383 K. The highest ionic conductivity of 1.43 × 10⁻³ S/cm was obtained at 16 wt.% AC. Temperature-dependent ionic conductivity showed that the ionic conductivity obeys Arrhenius rule where R²~1 and thermally assisted. Transport studies showed that the ionic conductivity was influenced by the ionic mobility and diffusion coefficient.

Vorheriger Artikel Mechanical, thermal and fire properties of sustainable rigid polyurethane foam derived from cashew nut shell liquid

Nächster Artikel Study of the effect of natural weathering on degradation of Polypropylene/starch filled polymer containing photo initiators by spectroscopic methods

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Woo HJ, Majid SR, Arof AK (2012) Dielectric properties and morphology of polymer electrolyte based on poly(ε–caprolactone) and ammonium thiocyanate. Mater Chem Phys 134:755–761CrossRef

Samsudin AS, Lai HM, Isa MIN (2014) Biopolymer materials based carboxymethyl cellulose as a proton conducting biopolymer electrolyte for application in rechargeable proton battery. Electrochim Acta 129:1–13CrossRef

Samsudin AS, Isa MIN (2012) Characterization of carboxy methylcellulose doped with DTAB as new types of biopolymer electrolytes. Bull Mater Sci 35:1123–1131CrossRef

Samsudin AS, Isa MIN (2012) Structural and electrical properties of carboxy methylcellulose- dodecyltrimethyl ammonium bromide-based biopolymer electrolytes system. Int J Polym Mater 61:30–40CrossRef

Du JF, Bai Y, Chu WY, Qiao LJ (2010) The structure and electric characters of proton-conducting chitosan membranes with various ammonium salts as complexant. J Polym Sci 10:880–885CrossRef

Kamarudin KH, Isa MIN (2013) Structural and DC Ionic conductivity studies of carboxy methylcellulose doped with ammonium nitrate as solid polymer electrolytes. Int J Phys Sci 8:1581–1587

Rani MSA, Rudhziah S, Ahmad A, Mohamed NS (2014) Biopolymer electrolyte based on derivatives of cellulose from Kenaf Bast fiber. Polymers 6:2371–2385CrossRef

Hema M, Selvasekerapandian S, Sakunthala A, Arunkumar D, Nithya H (2008) Structural, vibrational and electrical characterization of PVA-NH₄Br polymer electrolyte system. Physica B 403:2740–2747CrossRef

Winie T, Arof AK (2006) FT-IR studies on interactions among components in hexanoyl chitosan-based polymer electrolytes. J Spectrochem Acta Part A 63:677–684CrossRef

10.

Idris NK, Nik Aziz NA, Zambri MSM, Zakaria NA, Isa MIN (2009) Ionic conductivity studies of chitosan-based polymer electrolytes doped with adipic acid. Ionics 15:643–646CrossRef

11.

Selvasekarapandiana S, Hirankumara G, Kawamurab J, Kuwatab N, Hattorib T (2005) H solid state NMR studies on the proton conducting polymer electrolyte. Mater Lett 59:2741–2745CrossRef

12.

Buraidah MH, Teo LP, Majid SR, Arof AK (2009) Ionic conductivity by correlated barrier hopping in NH₄I doped chitosan solid electrolyte. Physica B 404:1373–1379CrossRef

13.

Majid SR, Arof AK (2004) Proton-conducting polymer electrolyte films based on chitosan acetate complexed with NH₄NO₃ salt. Physica B 355:78–82CrossRef

14.

Yokota S, Ueno T, Kitaoka T, Wariishi H (2007) Molecular imaging of single cellulose chains aligned on a highly oriented pyrolytic graphite surface. Carbohydr Res 342:2593–2598CrossRef

15.

Shuhaimi NEA, Teo LP, Majid SR, Arof AK (2010) Transport studies of NH₄NO₃ doped methyl cellulose electrolyte. Synth Met 160:1040–1044CrossRef

16.

Samsuddin AS, Kuan ECH, Isa MIN (2011) Investigation of the potential of proton-conducting biopolymer electrolytes based methyl cellulose-glycolic acid. J Polym Anal Charact 16:477–485CrossRef

17.

Nik Aziz NA, Idris NK, Isa MIN (2010) Solid polymer electrolytes based on methylcellulose: FT-IR and ionic conductivity studies. Polym Anal Charact 15:319–327CrossRef

18.

Chai MN, Ramli MA, Isa MIN (2013) Proton conductor of propylene carbonate–plasticized carboxyl methylcellulose–based solid polymer electrolyte. Int J Polym Anal Charact 18:297–302CrossRef

Titel: Proton conducting solid polymer electrolytes based carboxymethyl cellulose doped ammonium chloride: ionic conductivity and transport studies
verfasst von: Nur Hidayah Binti Ahmad
Mohd Ikmar Nizam Bin Mohamad Isa
Publikationsdatum: 01.06.2015
Verlag: Springer India
Erschienen in: International Journal of Plastics Technology / Ausgabe 1/2015
Print ISSN: 0972-656X
Elektronische ISSN: 0975-072X
DOI: https://doi.org/10.1007/s12588-015-9110-7

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