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Rare Metals
Erschienen in: Rare Metals 7/2019

11.04.2019

Corrosion resistance of Mg(OH)2/Mg–Al-layered double hydroxide coatings on magnesium alloy AZ31: influence of hydrolysis degree of silane

verfasst von: Qing-Song Yao, Zhong-Chao Li, Zai-Meng Qiu, Fen Zhang, Xiao-Bo Chen, Dong-Chu Chen, Shao-Kang Guan, Rong-Chang Zeng

Erschienen in: Rare Metals | Ausgabe 7/2019

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Abstract

Mg(OH)2/Mg–Al-layered double hydroxide (LDH) coatings were modified with methyltrimethoxysilane (MTMS) on magnesium alloys. Effect of hydrolysis degree of silane solution on coating formation was investigated. Chemical compositions and surface morphologies of the coatings were examined using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and field-emission scanning electronic microscopy (FESEM). Results indicated that the composite coatings consisted of polymethyltrimethoxysilane (PMTMS), LDH and Mg(OH)2. Electrochemical and hydrogen evolution measurements revealed that the composite coatings possessed good corrosion resistance, especially the ones prepared in a high hydrolysis degree of silane. The optimum corrosion resistance of the composite coating was LDH/PMTMS-3 coating, which had the lowest value of corrosion current density (5.537 × 10−9 A·cm−2) and a dense surface. Plausible mechanism for coating formation and corrosion process of MTMS-modified Mg(OH)2/Mg–Al-LDH coatings were discussed.
Vorheriger Artikel In vitro biodegradability of Mg–2Gd–xZn alloys with different Zn contents and solution treatments
Nächster Artikel Mechanism of high-temperature oxidation effects in fatigue crack propagation and fracture mode for FGH97 superalloy

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Metadaten
Titel
Corrosion resistance of Mg(OH)2/Mg–Al-layered double hydroxide coatings on magnesium alloy AZ31: influence of hydrolysis degree of silane
verfasst von
Qing-Song Yao
Zhong-Chao Li
Zai-Meng Qiu
Fen Zhang
Xiao-Bo Chen
Dong-Chu Chen
Shao-Kang Guan
Rong-Chang Zeng
Publikationsdatum
11.04.2019
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 7/2019
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-019-01234-1

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