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Sustainable Water Resources Management

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01.10.2023 | Original Article

Liquid-phase adsorption modeling of Eosin Y and Erythrosin B dyes onto nanoscale zero-valent iron using response surface and computational methodologies

verfasst von: Soumya Ghosh, Shabnam Ahmadi, Alhadji Malloum, Leili Mohammadi, Chinenye Adaobi Igwegbe

Erschienen in: Sustainable Water Resources Management | Ausgabe 5/2023

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Abstract

Dyes present a significant environmental challenge as major pollutants in wastewater. Their presence in wastewater not only contaminates surface and groundwater but also poses a threat to human health and disrupts the ecological balance. To address this issue, this study investigates the efficacy of nanoscale zero-valent iron (nZVI) in removing Eosin Y (Eo-Y) and Erythrosin B (Er-B) from aqueous solutions. The central composite design (CCD) plan combined with response surface methodology (RSM) is employed to assess its predictive capability. Utilizing nZVI as an adsorbent, the maximum adsorption capacity (qmax) is determined to be 10.81 mg/g for Eo-Y and 10.35 mg/g for Er-B. The adsorption process of Eo-Y and Er-B on nZVI follows a pseudo-second-order kinetic model, indicating chemisorption mechanisms. The removal of Eo-Y and Er-B on nZVI is accurately described by Langmuir and Freundlich adsorption isotherm models. Furthermore, density functional theory (DFT) modeling uncovers the presence of hydrogen bonds and dipole–dipole interactions between the dyes and the adsorbent. Based on the calculated DFT-based descriptors, both Eo-Y and Er-B exhibit small chemical hardness values, suggesting their reactivity. Notably, Eo-Y demonstrates higher hardness compared to Er-B. Overall, the study’s findings demonstrate the remarkable effectiveness of nZVI in removing Eo-Y and Er-B from aqueous solutions.

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Vorheriger Artikel Evaluation of surface water quality using hydro-chemical, bacteriological characters and water quality index: a case study on sacred ponds of Kurukshetra, Haryana, India

Nächster Artikel Assessment of baseflow estimates using ArcSWAT and digital filter method in Mago River Basin of Arunachal Pradesh

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Titel: Liquid-phase adsorption modeling of Eosin Y and Erythrosin B dyes onto nanoscale zero-valent iron using response surface and computational methodologies
verfasst von: Soumya Ghosh
Shabnam Ahmadi
Alhadji Malloum
Leili Mohammadi
Chinenye Adaobi Igwegbe
Publikationsdatum: 01.10.2023
Verlag: Springer International Publishing
Erschienen in: Sustainable Water Resources Management / Ausgabe 5/2023
Print ISSN: 2363-5037
Elektronische ISSN: 2363-5045
DOI: https://doi.org/10.1007/s40899-023-00940-0

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