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Erschienen in: Cellulose 1/2011

01.02.2011

Mechanical properties of natural rubber nanocomposites reinforced with cellulosic nanoparticles obtained from combined mechanical shearing, and enzymatic and acid hydrolysis of sisal fibers

verfasst von: Gilberto Siqueira, Sandra Tapin-Lingua, Julien Bras, Denilson da Silva Perez, Alain Dufresne

Erschienen in: Cellulose | Ausgabe 1/2011

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Abstract

In a previous work (Siqueira et al. 2010b) the preparation of cellulosic nanoparticles from sisal fibers using different processing routes, viz. a combination of mechanical shearing, acid and enzymatic hydrolysis was reported. It was shown that the pre-enzymatic hydrolysis treatment of bleached sisal pulp helps the preparation of well individualized rod-like nanocrystals. An amorphous polymer (natural rubber—NR) was chosen as model matrix to investigate the effect of these nanoparticles on the thermo-mechanical properties of nanocomposites. Both tensile tests and dynamic mechanical analyses showed improved stiffness for all nanocomposites. The enzymatic treatment allowed production of a huge range of cellulosic nanoparticles which provided completely different mechanical properties to NR matrix.

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Literatur
Zurück zum Zitat Azizi Samir MAS, Alloin F, Paillet M, Dufresne A (2004) Tangling effect in fibrillated cellulose reinforced nanocomposites. Macromolecules 37:4313–4316CrossRef Azizi Samir MAS, Alloin F, Paillet M, Dufresne A (2004) Tangling effect in fibrillated cellulose reinforced nanocomposites. Macromolecules 37:4313–4316CrossRef
Zurück zum Zitat Azizi Samir MAS, Alloin F, Dufresne A (2005) A review of recent research into cellulosic whiskers, their properties and their application in nanocomposite field. Biomacromolecules 6:612–626CrossRef Azizi Samir MAS, Alloin F, Dufresne A (2005) A review of recent research into cellulosic whiskers, their properties and their application in nanocomposite field. Biomacromolecules 6:612–626CrossRef
Zurück zum Zitat Bendahou A, Habibi Y, Kaddami H, Dufresne A (2009) Physico-chemical characterization of palm from Phoenix Dactylifera—L, preparation of cellulose whiskers and natural rubber–based nanocomposites. J Biobas Mat Bioenergy 3:81–90CrossRef Bendahou A, Habibi Y, Kaddami H, Dufresne A (2009) Physico-chemical characterization of palm from Phoenix Dactylifera—L, preparation of cellulose whiskers and natural rubber–based nanocomposites. J Biobas Mat Bioenergy 3:81–90CrossRef
Zurück zum Zitat Bendahou A, Kaddami H, Dufresne A (2010) Investigation on the effect of cellulosic nanoparticles’ morphology on the properties of natural rubber based nanocomposites. Eur Polym J 46:609–620CrossRef Bendahou A, Kaddami H, Dufresne A (2010) Investigation on the effect of cellulosic nanoparticles’ morphology on the properties of natural rubber based nanocomposites. Eur Polym J 46:609–620CrossRef
Zurück zum Zitat Dufresne A (2006) Comparing the mechanical properties of high performances polymer nanocomposites from biological sources. J Nanosci Nanotechnol 6:322–330 Dufresne A (2006) Comparing the mechanical properties of high performances polymer nanocomposites from biological sources. J Nanosci Nanotechnol 6:322–330
Zurück zum Zitat Dufresne A (2008) Polysaccharide nanocrystals reinforced nanocomposites. Can J Chem 86:484–494CrossRef Dufresne A (2008) Polysaccharide nanocrystals reinforced nanocomposites. Can J Chem 86:484–494CrossRef
Zurück zum Zitat Henriksson M (2008). Cellulose nanofibril networks and composites. PhD Thesis, KTH Chemical Science and Engineering, Stockholm, Sweden, 51p Henriksson M (2008). Cellulose nanofibril networks and composites. PhD Thesis, KTH Chemical Science and Engineering, Stockholm, Sweden, 51p
Zurück zum Zitat Henriksson M, Henriksson G, Berglund LA, Lindström T (2007) An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers. Europ Polym J 43:3434–3441CrossRef Henriksson M, Henriksson G, Berglund LA, Lindström T (2007) An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers. Europ Polym J 43:3434–3441CrossRef
Zurück zum Zitat Hubbe MA, Rojas OJ, Lucia LA, Sain M (2008) Cellulosic nanocomposites: a review. BioRes 3:929–980 Hubbe MA, Rojas OJ, Lucia LA, Sain M (2008) Cellulosic nanocomposites: a review. BioRes 3:929–980
Zurück zum Zitat Siqueira G, Bras J, Dufresne A (2009) Cellulose whiskers vs. microfibrils: influence of the nature of the nanoparticle and its surface functionalization on the thermal and mechanical properties of nanocomposites. Biomacromolecules 10:425–432CrossRef Siqueira G, Bras J, Dufresne A (2009) Cellulose whiskers vs. microfibrils: influence of the nature of the nanoparticle and its surface functionalization on the thermal and mechanical properties of nanocomposites. Biomacromolecules 10:425–432CrossRef
Zurück zum Zitat Siqueira G, Abdillahi H, Bras J, Dufresne A (2010a) High reinforcing capability cellulose nanocrystals extracted from Syngonanthus nitens (Capim Dourado). Cellulose 17:289–298CrossRef Siqueira G, Abdillahi H, Bras J, Dufresne A (2010a) High reinforcing capability cellulose nanocrystals extracted from Syngonanthus nitens (Capim Dourado). Cellulose 17:289–298CrossRef
Zurück zum Zitat Siqueira G, Tapin-Lingua S, Bras J, da Silva Perez D, Dufresne A (2010b) Morphological investigation of nanoparticles obtained from enzymatic and acid hydrolysis of sisal fibers. Cellulose. doi:10.1007/s10570-010-9449-z Siqueira G, Tapin-Lingua S, Bras J, da Silva Perez D, Dufresne A (2010b) Morphological investigation of nanoparticles obtained from enzymatic and acid hydrolysis of sisal fibers. Cellulose. doi:10.​1007/​s10570-010-9449-z
Zurück zum Zitat Šturcova A, Davies GR, Eichhorn SJ (2005) Elastic modulus and stress-transfer properties of tunicate cellulose whiskers. Biomacromolecules 6:1055–1061CrossRef Šturcova A, Davies GR, Eichhorn SJ (2005) Elastic modulus and stress-transfer properties of tunicate cellulose whiskers. Biomacromolecules 6:1055–1061CrossRef
Metadaten
Titel
Mechanical properties of natural rubber nanocomposites reinforced with cellulosic nanoparticles obtained from combined mechanical shearing, and enzymatic and acid hydrolysis of sisal fibers
verfasst von
Gilberto Siqueira
Sandra Tapin-Lingua
Julien Bras
Denilson da Silva Perez
Alain Dufresne
Publikationsdatum
01.02.2011
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 1/2011
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-010-9463-1

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