Skip to main content
Erschienen in: Cellulose 1/2011

01.02.2011

Thermogravimetric measurement of amorphous cellulose content in flax fibre and flax pulp

verfasst von: Agustín García Barneto, Carlos Vila, José Ariza, Teresa Vidal

Erschienen in: Cellulose | Ausgabe 1/2011

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Usually the raw material for flax pulp production is a blend which contains fibres and shives. In order to better understanding the structure of these materials and the effects of flax pulping, X-ray diffraction and thermogravimetry analysis under air atmosphere have been used. There was a significant effect of the fibre size on the composition, crystallinity, and thermal behaviour of the flax pulps. On the other hand, data obtained from thermogravimetric analysis have been modelled on the basis of two cellulose types characterized by different crystallinity levels, using kinetics equations based on the nucleation concept. As a result of these simulations, composition of the samples, pulp crystallinity and the proportion of amorphous cellulose are calculated.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Alves SS, Figueiredo JL (1988) Pyrolysis kinetics of lignocellulosic materials by multisatge isothermal thermogravimetry. J Anal Appl Pyrolysis 13:123–134CrossRef Alves SS, Figueiredo JL (1988) Pyrolysis kinetics of lignocellulosic materials by multisatge isothermal thermogravimetry. J Anal Appl Pyrolysis 13:123–134CrossRef
Zurück zum Zitat Antal M, Varhegyi G, Jakab E (1998) Cellulose pyrolysis kinetics: revisited. Ind Eng Chem Res 37:1267–1275CrossRef Antal M, Varhegyi G, Jakab E (1998) Cellulose pyrolysis kinetics: revisited. Ind Eng Chem Res 37:1267–1275CrossRef
Zurück zum Zitat Barneto AG, Ariza J, Martín JE, Sánchez R (2010) Simulation of the thermogravimetry analysis of three non-wood pulps. Bioresour Technol 101:3220–3229CrossRef Barneto AG, Ariza J, Martín JE, Sánchez R (2010) Simulation of the thermogravimetry analysis of three non-wood pulps. Bioresour Technol 101:3220–3229CrossRef
Zurück zum Zitat Buranov A, Mazza G (2008) Lignin in straw of herbaceous crops. Ind Crops Prod 28:237–259CrossRef Buranov A, Mazza G (2008) Lignin in straw of herbaceous crops. Ind Crops Prod 28:237–259CrossRef
Zurück zum Zitat Buranov A, Mazza G (2010) Extraction and characterization of hemicelluloses from flax shives by different methods. Carbohydr Polym 79:17–25CrossRef Buranov A, Mazza G (2010) Extraction and characterization of hemicelluloses from flax shives by different methods. Carbohydr Polym 79:17–25CrossRef
Zurück zum Zitat Burnham AK (2000) Application of the Sestak-Berggren equation to organic and inorganic materials of practical interest. J Therm Anal Calorim 60:895–908CrossRef Burnham AK (2000) Application of the Sestak-Berggren equation to organic and inorganic materials of practical interest. J Therm Anal Calorim 60:895–908CrossRef
Zurück zum Zitat Burnham AK, Braun RL, Coburn TT, Sandvik EI, Curry DJ, Schmidt BJ, Noble RA (1996) An appropriate kinetic model for well-preserved algal kerogens. Energy Fuels 10:49–59CrossRef Burnham AK, Braun RL, Coburn TT, Sandvik EI, Curry DJ, Schmidt BJ, Noble RA (1996) An appropriate kinetic model for well-preserved algal kerogens. Energy Fuels 10:49–59CrossRef
Zurück zum Zitat Capart R, Khezami L, Burnham A (2004) Assessment of various kinetic models for the pyrolysis of a microgranular cellulose. Thermochimica Acta 417:79–89CrossRef Capart R, Khezami L, Burnham A (2004) Assessment of various kinetic models for the pyrolysis of a microgranular cellulose. Thermochimica Acta 417:79–89CrossRef
Zurück zum Zitat Day A, Ruel K, Neutelings G, Cronier D, David H, Hawkins S, Chabbert B (2005) Lignification in the flax stem: evidence for an unusual lignin in bast fibers. Planta 222:234–245CrossRef Day A, Ruel K, Neutelings G, Cronier D, David H, Hawkins S, Chabbert B (2005) Lignification in the flax stem: evidence for an unusual lignin in bast fibers. Planta 222:234–245CrossRef
Zurück zum Zitat Di Blasi C, Lanzetta M (1997) Intrinsic kinetics of isothermal xylan degradation in inert atmosphere. J Anal Appl Pyrolysis 40:287–303CrossRef Di Blasi C, Lanzetta M (1997) Intrinsic kinetics of isothermal xylan degradation in inert atmosphere. J Anal Appl Pyrolysis 40:287–303CrossRef
Zurück zum Zitat Evans RJ, Milne TA (1987) Molecular characterization of the pyrolysis of biomass. 1. fundamentals. Energy Fuels 2:123–137CrossRef Evans RJ, Milne TA (1987) Molecular characterization of the pyrolysis of biomass. 1. fundamentals. Energy Fuels 2:123–137CrossRef
Zurück zum Zitat Evans R, Newman RH, Roick UC, Suckling ID, Wallis AF (1995) Changes in cellulose crystallinity during kraft pulping. Comparison of infrared, X-Ray diffraction and solid state NMR results. Holzforschung 49:498–504CrossRef Evans R, Newman RH, Roick UC, Suckling ID, Wallis AF (1995) Changes in cellulose crystallinity during kraft pulping. Comparison of infrared, X-Ray diffraction and solid state NMR results. Holzforschung 49:498–504CrossRef
Zurück zum Zitat Faix O, Jakab E, Till F, Szekely T (1988) Study on low mass thermal degradation products of milled woods lignins by thermogravimetry-mass spectrometry. Wood Sci Technol 22:323–334CrossRef Faix O, Jakab E, Till F, Szekely T (1988) Study on low mass thermal degradation products of milled woods lignins by thermogravimetry-mass spectrometry. Wood Sci Technol 22:323–334CrossRef
Zurück zum Zitat Fengel D (1971) Ideas on ultrastructural organisation of cell-wall components. J.Polymer Science: Part C 36:383–392 Fengel D (1971) Ideas on ultrastructural organisation of cell-wall components. J.Polymer Science: Part C 36:383–392
Zurück zum Zitat Grønli MG, Varhegyi G, Di Blassi C (2002) Thermogravimetric analysis and devolatization kinetics of wood. Ind Eg Chem Res 41:4201–4208CrossRef Grønli MG, Varhegyi G, Di Blassi C (2002) Thermogravimetric analysis and devolatization kinetics of wood. Ind Eg Chem Res 41:4201–4208CrossRef
Zurück zum Zitat Gutierrez A, del Rio JC (2003) Lipids from flax fibers and their fate in alkaline pulping. J Agric Food Chem 51:4965–4971CrossRef Gutierrez A, del Rio JC (2003) Lipids from flax fibers and their fate in alkaline pulping. J Agric Food Chem 51:4965–4971CrossRef
Zurück zum Zitat Hult E, Iversen T, Sugiyama J (2003) Characterization of the supramolecular structure in wood pulp fibres. Cellulose 10:103–110CrossRef Hult E, Iversen T, Sugiyama J (2003) Characterization of the supramolecular structure in wood pulp fibres. Cellulose 10:103–110CrossRef
Zurück zum Zitat Jauhiainen J, Conesa JA, Font R, Martin-Gullon I (2004) Kinetics of the pyrolysis and combustion of olive solid waste. J Anal Appl Pyrolysis 72:9–15CrossRef Jauhiainen J, Conesa JA, Font R, Martin-Gullon I (2004) Kinetics of the pyrolysis and combustion of olive solid waste. J Anal Appl Pyrolysis 72:9–15CrossRef
Zurück zum Zitat Kim JW, Mazza G (2009) Extraction and separation of carbohydrates and phenolic compounds in flax shives with pH-controlled pressurized low polarity water. J Agric Food Chem 57:1805–1813CrossRef Kim JW, Mazza G (2009) Extraction and separation of carbohydrates and phenolic compounds in flax shives with pH-controlled pressurized low polarity water. J Agric Food Chem 57:1805–1813CrossRef
Zurück zum Zitat Leppänen K, Anderson S, Torkkeli M, Knaapila M, Kotelnikova N, Serimaa R (2009) Structure of cellulose and microcrystalline cellulose from various wood species, cotton and flax studied by X-Ray scaterring. Cellulose 16:999–1015CrossRef Leppänen K, Anderson S, Torkkeli M, Knaapila M, Kotelnikova N, Serimaa R (2009) Structure of cellulose and microcrystalline cellulose from various wood species, cotton and flax studied by X-Ray scaterring. Cellulose 16:999–1015CrossRef
Zurück zum Zitat Mamleev V, Bourbigot S, Le Bras M, Yvon J, Lefebvre J (2006) Model-free method for evaluation of activation energies in modulated thermogravimetry and analysis of cellulose decomposition. J Chem Eng Sci 61:1272–1288CrossRef Mamleev V, Bourbigot S, Le Bras M, Yvon J, Lefebvre J (2006) Model-free method for evaluation of activation energies in modulated thermogravimetry and analysis of cellulose decomposition. J Chem Eng Sci 61:1272–1288CrossRef
Zurück zum Zitat Mamleev V, Bourbigot S, Le Bras M, Yvon J (2009) The facts and hypotheses relating to the phenomenological model of cellulose pyrolysis. Interdependence of the steps. J Anal Appl Pyrolysis 84:1–17CrossRef Mamleev V, Bourbigot S, Le Bras M, Yvon J (2009) The facts and hypotheses relating to the phenomenological model of cellulose pyrolysis. Interdependence of the steps. J Anal Appl Pyrolysis 84:1–17CrossRef
Zurück zum Zitat Marshall W, Wartelle L, Akin D (2007) Flax shive as a source of activated carbon for metals remediaton. Bioresources 2(1):82–90 Marshall W, Wartelle L, Akin D (2007) Flax shive as a source of activated carbon for metals remediaton. Bioresources 2(1):82–90
Zurück zum Zitat Meszaros E, Varhegyi G, Jakab E, Marosvölgyi B (2004) Thermogravimetric and reaction kinetic analysis of biomass samples from an energy plantation. Energy Fuels 18:497–507CrossRef Meszaros E, Varhegyi G, Jakab E, Marosvölgyi B (2004) Thermogravimetric and reaction kinetic analysis of biomass samples from an energy plantation. Energy Fuels 18:497–507CrossRef
Zurück zum Zitat Meszaros E, Jakab E, Varhegyi G, Tovari P (2007) Thermogravimetry/mass spectrometry analysis of energy crops. J Therm Anal Calorim 88:477–482CrossRef Meszaros E, Jakab E, Varhegyi G, Tovari P (2007) Thermogravimetry/mass spectrometry analysis of energy crops. J Therm Anal Calorim 88:477–482CrossRef
Zurück zum Zitat Morvan C, Andeme-Onzighi C, Girault R, Himmelsbach D, Driouich A, Akin D (2003) Building flax fibres: more than one brick in the walls. Plant Physiol Biochem 41:935–944CrossRef Morvan C, Andeme-Onzighi C, Girault R, Himmelsbach D, Driouich A, Akin D (2003) Building flax fibres: more than one brick in the walls. Plant Physiol Biochem 41:935–944CrossRef
Zurück zum Zitat Naredi P, Pisupati SV (2007) Interpretation of char reactivity profiles obtained using a thermogravimetric analyzer. Energy Fuels 22:317–320CrossRef Naredi P, Pisupati SV (2007) Interpretation of char reactivity profiles obtained using a thermogravimetric analyzer. Energy Fuels 22:317–320CrossRef
Zurück zum Zitat Newman RH (1999) Estimation of the lateral dimensions of cellulose crystallites using 13C NMR signal strengths. Solid State Nucl Magn Reson 15:21–29CrossRef Newman RH (1999) Estimation of the lateral dimensions of cellulose crystallites using 13C NMR signal strengths. Solid State Nucl Magn Reson 15:21–29CrossRef
Zurück zum Zitat Nishiyama Y, Kim U, Kim D, Katsumata K, May RP, Langan P (2003) Periodic disorder along ramie cellulose microfibrils. Biomacromolecules 4:1013–1017CrossRef Nishiyama Y, Kim U, Kim D, Katsumata K, May RP, Langan P (2003) Periodic disorder along ramie cellulose microfibrils. Biomacromolecules 4:1013–1017CrossRef
Zurück zum Zitat O’Sullivan AC (1997) Cellulose: the structure slowly unravels. Cellulose 4:173–206CrossRef O’Sullivan AC (1997) Cellulose: the structure slowly unravels. Cellulose 4:173–206CrossRef
Zurück zum Zitat Orfao JJ, Antunes F, Figueiredo JL (1999) Pyrolysis kinetics of lignocellulosic materials three-component reactions model. Fuel 78:349–358CrossRef Orfao JJ, Antunes F, Figueiredo JL (1999) Pyrolysis kinetics of lignocellulosic materials three-component reactions model. Fuel 78:349–358CrossRef
Zurück zum Zitat Prout EG, Tompkins FC (1944) The thermal decomposition of potassium permanganate. Trans Faraday Soc 40:488–498CrossRef Prout EG, Tompkins FC (1944) The thermal decomposition of potassium permanganate. Trans Faraday Soc 40:488–498CrossRef
Zurück zum Zitat Prout EG, Tompkins FC (1946) The thermal decomposition of silver permanganate.Trans. Faraday Soc 42:468–472CrossRef Prout EG, Tompkins FC (1946) The thermal decomposition of silver permanganate.Trans. Faraday Soc 42:468–472CrossRef
Zurück zum Zitat Roberts GA (1991) Accessibility of cellulose. In: Roberts JC (ed) Paper chemistry. Blackie & Son Ltd, New York, pp 9–24 Roberts GA (1991) Accessibility of cellulose. In: Roberts JC (ed) Paper chemistry. Blackie & Son Ltd, New York, pp 9–24
Zurück zum Zitat Roncero MB, Torres AL, Colom JF, Vidal T (2003a) TCF bleaching of wheat straw pulp using ozone and xylanase. Part A: paper quality assessment. Bioresour Technol 87:305–314CrossRef Roncero MB, Torres AL, Colom JF, Vidal T (2003a) TCF bleaching of wheat straw pulp using ozone and xylanase. Part A: paper quality assessment. Bioresour Technol 87:305–314CrossRef
Zurück zum Zitat Roncero MB, Colom JF, Vidal T (2003b) Influencia de los tratamientos enzimáticos con xilanasas en la composición de hidratos de carbono de pastas para papel. Afinidad 60(503):8–15 Roncero MB, Colom JF, Vidal T (2003b) Influencia de los tratamientos enzimáticos con xilanasas en la composición de hidratos de carbono de pastas para papel. Afinidad 60(503):8–15
Zurück zum Zitat Roncero MB, Torres AL, Colom JF, Vidal T (2005) The effect of xylanase on lignocellulosic components during the bleaching of wood pulps. Bioresour Technol 96:21–30CrossRef Roncero MB, Torres AL, Colom JF, Vidal T (2005) The effect of xylanase on lignocellulosic components during the bleaching of wood pulps. Bioresour Technol 96:21–30CrossRef
Zurück zum Zitat Senneca O (2007) Kinetics of pyrolysis, combustion and gasification of three biomass fuels. Fuel Process Technol 88:87–97CrossRef Senneca O (2007) Kinetics of pyrolysis, combustion and gasification of three biomass fuels. Fuel Process Technol 88:87–97CrossRef
Zurück zum Zitat Valls C, Vidal T, Gallardo O, Diaz P, Pastor FJ, Roncero MB (2010) Obtaining low-HexA-content cellulose from eucalypt fibres: which glycosil hydrolase family is more efficient? Carbohydr Polym 80:154–160CrossRef Valls C, Vidal T, Gallardo O, Diaz P, Pastor FJ, Roncero MB (2010) Obtaining low-HexA-content cellulose from eucalypt fibres: which glycosil hydrolase family is more efficient? Carbohydr Polym 80:154–160CrossRef
Zurück zum Zitat Varhegyi G, Antal MJ, Szekely T, Szabó P (1989) Kinetics of the thermal decomposition of cellulose, hemicellulose, and sugar cane bagasse. Energy Fuels 3:329–335CrossRef Varhegyi G, Antal MJ, Szekely T, Szabó P (1989) Kinetics of the thermal decomposition of cellulose, hemicellulose, and sugar cane bagasse. Energy Fuels 3:329–335CrossRef
Zurück zum Zitat Varhegyi G, Jakob E, Antal MJ (1994) Is the Broido-Shafizadeh model for cellulose pyrolysis true? Energy Fuels 8:1345–1352CrossRef Varhegyi G, Jakob E, Antal MJ (1994) Is the Broido-Shafizadeh model for cellulose pyrolysis true? Energy Fuels 8:1345–1352CrossRef
Zurück zum Zitat Verlhac C, Dedier J, Chanzy H (1990) Availability of surface hydroxyl groups in valonia and bacterial cellulose. J Polym Sci A Polym Chem 28:1171–1177CrossRef Verlhac C, Dedier J, Chanzy H (1990) Availability of surface hydroxyl groups in valonia and bacterial cellulose. J Polym Sci A Polym Chem 28:1171–1177CrossRef
Zurück zum Zitat Viëtor R, Newman R, Ha MA, Apperley D, Jarvis MC (2002) Conformational features of crystal-surface cellulose from higher plants. Plant J 30(6):721–731CrossRef Viëtor R, Newman R, Ha MA, Apperley D, Jarvis MC (2002) Conformational features of crystal-surface cellulose from higher plants. Plant J 30(6):721–731CrossRef
Zurück zum Zitat Wood S, Layzell D.B (2003) A Canadian Biomass Inventory: Feedstocks for a Bio-based Economy. BIOCAP Canada Foundation, 18–24 Wood S, Layzell D.B (2003) A Canadian Biomass Inventory: Feedstocks for a Bio-based Economy. BIOCAP Canada Foundation, 18–24
Zurück zum Zitat Zickler G, Wagermaier W, Funari S, Burghammer M, Paris O (2007) Insitu X-ray diffraction investigation of thermal decomposition of wood cellulose. J Anal Appl Pyrolysis 80:134–140CrossRef Zickler G, Wagermaier W, Funari S, Burghammer M, Paris O (2007) Insitu X-ray diffraction investigation of thermal decomposition of wood cellulose. J Anal Appl Pyrolysis 80:134–140CrossRef
Metadaten
Titel
Thermogravimetric measurement of amorphous cellulose content in flax fibre and flax pulp
verfasst von
Agustín García Barneto
Carlos Vila
José Ariza
Teresa Vidal
Publikationsdatum
01.02.2011
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 1/2011
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-010-9472-0

Weitere Artikel der Ausgabe 1/2011

Cellulose 1/2011 Zur Ausgabe