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Cellulose

Erschienen in:

01.02.2011

Protonation behavior of 6-deoxy-6-(2-aminoethyl)amino cellulose: a potentiometric titration study

verfasst von: Lidija Fras Zemljič, Duško Čakara, Nico Michaelis, Thomas Heinze, Karin Stana Kleinschek

Erschienen in: Cellulose | Ausgabe 1/2011

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Abstract

The protonation behavior of 6-deoxy-6-(2-aminoethyl)amino cellulose as a novel soluble aminated derivate of cellulose was studied by means of the potentiometric titration technique. The resulting proton binding isotherms exhibit two equivalent steps, which can be described by the standard macroscopic two-pK model, in which the degree of protonation is averaged over all the amine groups. In addition, a microscopic proton binding model was applied, in which the protonation sites are distinguished and the protonation free energy is expanded into an intrinsic term and an electrostatic repulsion between the primary and secondary amine groups. The protonation behavior of 6-deoxy-6-(2-aminoethyl)amino cellulose was compared with a model compound (N-methylethylenediamine).

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Titel: Protonation behavior of 6-deoxy-6-(2-aminoethyl)amino cellulose: a potentiometric titration study
verfasst von: Lidija Fras Zemljič
Duško Čakara
Nico Michaelis
Thomas Heinze
Karin Stana Kleinschek
Publikationsdatum: 01.02.2011
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2011
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-010-9467-x

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