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Journal of Materials Science
Erschienen in: Journal of Materials Science 25/2020

12.05.2020 | Chemical routes to materials

Mesoporous N-doped carbon nanofibers with surface nanocavities for enhanced catalytic activity toward oxygen reduction reaction

verfasst von: Minggui Wang, Yanan Li, Jie Han

Erschienen in: Journal of Materials Science | Ausgabe 25/2020

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Abstract

Mesoporous N-doped carbon (m-N-Carbon) nanofibers with controlled numerous surface nanocavities as efficient oxygen reduction reaction electrocatalysts have been fabricated through carbonization polyaniline (PANI) nanofibers decorated with different sizes of SiO2 nanoparticles. The prepared m-N-Carbon nanofibers possess tunable mesopores, high surface area and desired nitrogen moieties. Among these, the sample m-N-Carbon (M-900) exhibits the highest electrocatalytic performance with high onset potential (0.941), half-wave potential (0.713 V), superior catalytic stability with slightly attenuated after 20000-s continuous operation and well tolerance to methanol. The enhanced electrocatalytic activities are associated with high-nitrogen content and the rational design of mesoporous structure N-Carbon nanofibers, which are contributed to the mass/electron transfer and exposure of active sites.
Vorheriger Artikel Umbrella-like CdS single crystal: exposed (002) facets and enhanced photocatalytic properties
Nächster Artikel Preparation of graphene oxide/silica hybrid composite membranes and performance studies in water treatment

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Metadaten
Titel
Mesoporous N-doped carbon nanofibers with surface nanocavities for enhanced catalytic activity toward oxygen reduction reaction
verfasst von
Minggui Wang
Yanan Li
Jie Han
Publikationsdatum
12.05.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 25/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-04772-7

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