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Microsystem Technologies
Erschienen in: Microsystem Technologies 5/2019

20.11.2017 | Technical Paper

Metal to semimetal conversion by band structure engineering of SWCNT by DNA nucleobase functionalization

verfasst von: Swati Sinha, Kunal Biswas, Debashis De, Jaya Bandyopadhyay, Angsuman Sarkar

Erschienen in: Microsystem Technologies | Ausgabe 5/2019

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Abstract

Pristine metallic single-walled carbon nanotubes (6, 0), surface engineered with pyrimidine type DNA nucleobases, thymine and cytosine respectively, are transformed into semimetal forms by band structure engineering of the nanotubes. The hybrid systems are designed using ATK–VNL simulation software. Band structure and zero bias transmission spectra analysis witness a very small overlap between the conduction and valence bands around the Fermi level. IV-characteristic curves also support the semimetallic nature of SWCNT–DNA nucleobase coupling. The altered electronic structure of SWCNT is achieved due to strong chemisorption imparted by hydrogenation of DNA nucleobases which induce partial sp3 hybridization in the nanotube structure. Metal to semimetal conversion results in conductivity modulation in SWCNT and it has several applications in various fields like nano-electronics including NEMS design.
Vorheriger Artikel Development of noise model for InAsSb MOSFETs and their application in low noise amplifiers
Nächster Artikel A CMOS active inductor based digital and analog dual tuned voltage-controlled oscillator

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Metadaten
Titel
Metal to semimetal conversion by band structure engineering of SWCNT by DNA nucleobase functionalization
verfasst von
Swati Sinha
Kunal Biswas
Debashis De
Jaya Bandyopadhyay
Angsuman Sarkar
Publikationsdatum
20.11.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Microsystem Technologies / Ausgabe 5/2019
Print ISSN: 0946-7076
Elektronische ISSN: 1432-1858
DOI
https://doi.org/10.1007/s00542-017-3628-x

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