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Erschienen in: Rare Metals 1/2023

17.05.2017

Microstructure and mechanical properties of Cr films deposited with different peak powers by high-power impulse magnetron sputtering

verfasst von: Yu Wang, Bao-Hua Wu, Fan Jiang, Dong-Lin Ma, Yan Yu, Hong Sun, Nan Huang, Yong-Xiang Leng

Erschienen in: Rare Metals | Ausgabe 1/2023

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Abstract

For high-power impulse magnetron sputtering (HIPIMS), the peak power applied to the target is of great importance for regulating the ionization degree of the metal target and ion/atom flux ratio. In this work, chromium (Cr) films were deposited on 316-L stainless steel substrates and silicon (100) wafers with different peak powers by HIPIMS. The relationship between peak target power and properties of Cr films was explored in detail. The resulting structure and mechanical properties of deposited Cr films were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), atomic force microscopy (AFM), indentation hardness and scratch tester. The results indicate that the ionization degree of metal target and ion/atom flux ratio increase with the increase in peak power but without the loss of deposition rate at the same time. At low ionization degree, the deposited Cr film has low compressive residual stress and low hardness but good adhesion strength. When the ionization degree of target metal increases with increasing peak power, Cr film exhibits finer size and smoother surface with improved hardness but decreased adhesion strength.

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Literatur
[1]
Zurück zum Zitat Seok JW, Jadeed NM, Lin RY. Sputter-deposited nanocrystalline Cr and CrN coatings on steels. Surf Coat Technol. 2001;138(1):14.CrossRef Seok JW, Jadeed NM, Lin RY. Sputter-deposited nanocrystalline Cr and CrN coatings on steels. Surf Coat Technol. 2001;138(1):14.CrossRef
[2]
Zurück zum Zitat Walter KC, Scheuer JT, McIntyre PC, Kodali P, Yu N, Nastasi M. Increased wear resistance of electrodeposited chromium through applications of plasma source ion implantation techniques. Surf Coat Technol. 1996;85(1–2):1.CrossRef Walter KC, Scheuer JT, McIntyre PC, Kodali P, Yu N, Nastasi M. Increased wear resistance of electrodeposited chromium through applications of plasma source ion implantation techniques. Surf Coat Technol. 1996;85(1–2):1.CrossRef
[3]
Zurück zum Zitat Mazille HMJ. Chemical vapour deposition of chromium onto nickel. Thin Solid Films. 1980;65(1):67.CrossRef Mazille HMJ. Chemical vapour deposition of chromium onto nickel. Thin Solid Films. 1980;65(1):67.CrossRef
[4]
Zurück zum Zitat Pérez FJ, Pedraza F, Hierro MP, Carpintero MC, Gómez C. Chromising of stainless steels by the use of the CVD-FBR technology. Surf Coat Technol. 2004;184(1):47.CrossRef Pérez FJ, Pedraza F, Hierro MP, Carpintero MC, Gómez C. Chromising of stainless steels by the use of the CVD-FBR technology. Surf Coat Technol. 2004;184(1):47.CrossRef
[5]
Zurück zum Zitat Bolelli G, Cannillo V, Lusvarghi L, Riccò S. Mechanical and tribological properties of electrolytic hard chrome and HVOF-sprayed coatings. Surf Coat Technol. 2006;200(9):2995.CrossRef Bolelli G, Cannillo V, Lusvarghi L, Riccò S. Mechanical and tribological properties of electrolytic hard chrome and HVOF-sprayed coatings. Surf Coat Technol. 2006;200(9):2995.CrossRef
[6]
Zurück zum Zitat Vetushka A, Ehiasarian AP. Plasma dynamic in chromium and titanium HIPIMS discharges. J Phys D Appl Phys. 2008;41(1):015.CrossRef Vetushka A, Ehiasarian AP. Plasma dynamic in chromium and titanium HIPIMS discharges. J Phys D Appl Phys. 2008;41(1):015.CrossRef
[7]
Zurück zum Zitat Theiß S, Bibinov N, Bagcivan N, Ewering M, Awakowicz P, Bobzin K. Time resolved optical emission spectroscopy of an HPPMS coating process. J Phys D Appl Phys. 2010;43(7):075.CrossRef Theiß S, Bibinov N, Bagcivan N, Ewering M, Awakowicz P, Bobzin K. Time resolved optical emission spectroscopy of an HPPMS coating process. J Phys D Appl Phys. 2010;43(7):075.CrossRef
[8]
Zurück zum Zitat Macák K, Kouznetsov V, Schneider J, Helmersson U, Petrov I. Ionized sputter deposition using an extremely high plasma density pulsed magnetron discharge. J Vac Sci Technol A: Vac Surf Films. 2000;18(4):1533.CrossRef Macák K, Kouznetsov V, Schneider J, Helmersson U, Petrov I. Ionized sputter deposition using an extremely high plasma density pulsed magnetron discharge. J Vac Sci Technol A: Vac Surf Films. 2000;18(4):1533.CrossRef
[9]
Zurück zum Zitat Hecimovic A, Burcalova KM, Ehiasarian AP. Origins of ion energy distribution function (IEDF) in high power impulse magnetron sputtering (HIPIMS) plasma discharge. J Phys D Appl Phys. 2008;41(9):095.CrossRef Hecimovic A, Burcalova KM, Ehiasarian AP. Origins of ion energy distribution function (IEDF) in high power impulse magnetron sputtering (HIPIMS) plasma discharge. J Phys D Appl Phys. 2008;41(9):095.CrossRef
[10]
Zurück zum Zitat Vlček J, Kudláček P, Burcalová K, Musil J. Ion flux characteristics in high-power pulsed magnetron sputtering discharges. Europhys Lett (EPL). 2007;77(4):45002.CrossRef Vlček J, Kudláček P, Burcalová K, Musil J. Ion flux characteristics in high-power pulsed magnetron sputtering discharges. Europhys Lett (EPL). 2007;77(4):45002.CrossRef
[11]
Zurück zum Zitat Lattemann M, Ehiasarian AP, Bohlmark J, Persson PÅO, Helmersson U. Investigation of high power impulse magnetron sputtering pretreated interfaces for adhesion enhancement of hard coatings on steel. Surf Coat Technol. 2006;200(22–23):6495.CrossRef Lattemann M, Ehiasarian AP, Bohlmark J, Persson PÅO, Helmersson U. Investigation of high power impulse magnetron sputtering pretreated interfaces for adhesion enhancement of hard coatings on steel. Surf Coat Technol. 2006;200(22–23):6495.CrossRef
[12]
Zurück zum Zitat Sarakinos K, Alami J, Konstantinidis S. High power pulsed magnetron sputtering: a review on scientific and engineering state of the art. Surf Coat Technol. 2010;204(11):1661.CrossRef Sarakinos K, Alami J, Konstantinidis S. High power pulsed magnetron sputtering: a review on scientific and engineering state of the art. Surf Coat Technol. 2010;204(11):1661.CrossRef
[13]
Zurück zum Zitat Olaya JJ, Rodil SE, Muhl S, Sánchez E. Comparative study of chromium nitride coatings deposited by unbalanced and balanced magnetron sputtering. Thin Solid Films. 2005;474(1–2):119.CrossRef Olaya JJ, Rodil SE, Muhl S, Sánchez E. Comparative study of chromium nitride coatings deposited by unbalanced and balanced magnetron sputtering. Thin Solid Films. 2005;474(1–2):119.CrossRef
[14]
Zurück zum Zitat Olaya JJ, Wei G, Rodil SE, Muhl S, Bhushan B. Influence of the ion–atom flux ratio on the mechanical properties of chromium nitride thin films. Vacuum. 2007;81(5):610.CrossRef Olaya JJ, Wei G, Rodil SE, Muhl S, Bhushan B. Influence of the ion–atom flux ratio on the mechanical properties of chromium nitride thin films. Vacuum. 2007;81(5):610.CrossRef
[15]
Zurück zum Zitat Kim K, Park M, Lee W, Kim HW, Lee JG, Lee C. Effects of sputtering power on mechanical properties of Cr films deposited by magnetron sputtering. Mater Sci Technol. 2008;24(7):838.CrossRef Kim K, Park M, Lee W, Kim HW, Lee JG, Lee C. Effects of sputtering power on mechanical properties of Cr films deposited by magnetron sputtering. Mater Sci Technol. 2008;24(7):838.CrossRef
[16]
Zurück zum Zitat Ehiasariana AP, Newa R, Munz WD, Hultmanb L, Helmerssonb U, Kouznetsov V. Influence of high power densities on the composition of pulsed magnetron plasmas. Vacuum. 2002;65(2):147.CrossRef Ehiasariana AP, Newa R, Munz WD, Hultmanb L, Helmerssonb U, Kouznetsov V. Influence of high power densities on the composition of pulsed magnetron plasmas. Vacuum. 2002;65(2):147.CrossRef
[17]
Zurück zum Zitat Jing FJ, Yin TL, Yukimura K, Sun H, Leng YX, Huang N. Titanium film deposition by high-power impulse magnetron sputtering: influence of pulse duration. Vacuum. 2012;86(12):2114.CrossRef Jing FJ, Yin TL, Yukimura K, Sun H, Leng YX, Huang N. Titanium film deposition by high-power impulse magnetron sputtering: influence of pulse duration. Vacuum. 2012;86(12):2114.CrossRef
[18]
Zurück zum Zitat Yukimura K, Mieda R, Tamagaki H, Okimoto T. Electrical characteristics of arc-free high-power pulsed sputtering glow plasma. Surf Coat Technol. 2008;202(22–23):5246.CrossRef Yukimura K, Mieda R, Tamagaki H, Okimoto T. Electrical characteristics of arc-free high-power pulsed sputtering glow plasma. Surf Coat Technol. 2008;202(22–23):5246.CrossRef
[19]
Zurück zum Zitat Horwat D, Anders A. Spatial distribution of average charge state and deposition rate in high power impulse magnetron sputtering of copper. J Phys D Appl Phys. 2008;41(13):135.CrossRef Horwat D, Anders A. Spatial distribution of average charge state and deposition rate in high power impulse magnetron sputtering of copper. J Phys D Appl Phys. 2008;41(13):135.CrossRef
[20]
Zurück zum Zitat Shefford PB, William DN. Mechanical properties of compositionally modulated Au-Ni thin films: nanoindentation and microcantilever deflection experiments. Mater Res Soc. 1994;9(12):3131.CrossRef Shefford PB, William DN. Mechanical properties of compositionally modulated Au-Ni thin films: nanoindentation and microcantilever deflection experiments. Mater Res Soc. 1994;9(12):3131.CrossRef
[21]
Zurück zum Zitat Sibillano T, Ancona A, Rizzi D, Rodil SS, Nieto JR, Konuk AR, Aarts R, Huis AJ. Study on the correlation between plasma electron temperature and penetration depth in laser welding processes. Phys Procedia. 2010;5(Part B):429.CrossRef Sibillano T, Ancona A, Rizzi D, Rodil SS, Nieto JR, Konuk AR, Aarts R, Huis AJ. Study on the correlation between plasma electron temperature and penetration depth in laser welding processes. Phys Procedia. 2010;5(Part B):429.CrossRef
[22]
Zurück zum Zitat Christou C, Barber ZH. Ionization of sputtered material in a planar magnetron discharge. J Vac Sci Technol A: Vac Surf Films. 2000;18(6):2897.CrossRef Christou C, Barber ZH. Ionization of sputtered material in a planar magnetron discharge. J Vac Sci Technol A: Vac Surf Films. 2000;18(6):2897.CrossRef
[23]
Zurück zum Zitat Christie DJ. Target material pathways model for high power pulsed magnetron sputtering. J Vac Sci Technol A: Vac Surf Films. 2005;23(2):330.CrossRef Christie DJ. Target material pathways model for high power pulsed magnetron sputtering. J Vac Sci Technol A: Vac Surf Films. 2005;23(2):330.CrossRef
[24]
Zurück zum Zitat Christie DJ. Fundamentals of high power pulsed magnetron sputtering: visualization of mechanisms for rate reduction and increased ion fraction. Czech J Phys. 2006;56(2):B93.CrossRef Christie DJ. Fundamentals of high power pulsed magnetron sputtering: visualization of mechanisms for rate reduction and increased ion fraction. Czech J Phys. 2006;56(2):B93.CrossRef
[25]
Zurück zum Zitat Alami J, Gudmundsson JT, Bohlmark J, Birch J, Helmersson U. Plasma dynamics in a highly ionized pulsed magnetron discharge. Plasma Sources Sci Technol. 2005;14(3):525.CrossRef Alami J, Gudmundsson JT, Bohlmark J, Birch J, Helmersson U. Plasma dynamics in a highly ionized pulsed magnetron discharge. Plasma Sources Sci Technol. 2005;14(3):525.CrossRef
[26]
Zurück zum Zitat Wu BH, Wang Y, Yu Y, Jiang F, Sun H, Jing FJ, Zhu SF, Wu YP, Leng YX, Huang N. Modulate the deposition rate through changing the combination of frequency and pulse width at constant duty cycle. Surf Coat Technol. 2015;281(3):27.CrossRef Wu BH, Wang Y, Yu Y, Jiang F, Sun H, Jing FJ, Zhu SF, Wu YP, Leng YX, Huang N. Modulate the deposition rate through changing the combination of frequency and pulse width at constant duty cycle. Surf Coat Technol. 2015;281(3):27.CrossRef
[27]
Zurück zum Zitat Pauleau Y. Generation and evolution of residual stresses in physical vapour-deposited thin films. Vacuum. 2001;61(2):175.CrossRef Pauleau Y. Generation and evolution of residual stresses in physical vapour-deposited thin films. Vacuum. 2001;61(2):175.CrossRef
[28]
Zurück zum Zitat Windischmann H. Intrinsic stress in sputter-deposited thin films. Crit Rev Solid State Mater Sci. 1992;17(6):547.CrossRef Windischmann H. Intrinsic stress in sputter-deposited thin films. Crit Rev Solid State Mater Sci. 1992;17(6):547.CrossRef
[29]
Zurück zum Zitat Feng YC, Laughlin DE, Lambeth DN. Formation of crystallographic texture in rf sputter-deposited Cr thin films. J Appl Phys. 1994;76(11):7311.CrossRef Feng YC, Laughlin DE, Lambeth DN. Formation of crystallographic texture in rf sputter-deposited Cr thin films. J Appl Phys. 1994;76(11):7311.CrossRef
[30]
Zurück zum Zitat Ferrec A, Keraudy J, Jacq S, Schuster F, Jouan PY, Djouadi MA. Correlation between mass-spectrometer measurements and thin film characteristics using dcMS and HiPIMS discharges. Surf Coat Technol. 2014;250(18):52.CrossRef Ferrec A, Keraudy J, Jacq S, Schuster F, Jouan PY, Djouadi MA. Correlation between mass-spectrometer measurements and thin film characteristics using dcMS and HiPIMS discharges. Surf Coat Technol. 2014;250(18):52.CrossRef
[31]
Zurück zum Zitat Chiang KTK, Wei RH. Growth morphology and corrosion resistance of magnetron sputtered Cr films. Surf Coat Technol. 2011;206(7):1660.CrossRef Chiang KTK, Wei RH. Growth morphology and corrosion resistance of magnetron sputtered Cr films. Surf Coat Technol. 2011;206(7):1660.CrossRef
[32]
Zurück zum Zitat Lee JW, Tien SK, Kuo YC, Chen CM. The mechanical properties evaluation of the CrN coatings deposited by the pulsed DC reactive magnetron sputtering. Surf Coat Technol. 2006;200(10):3330.CrossRef Lee JW, Tien SK, Kuo YC, Chen CM. The mechanical properties evaluation of the CrN coatings deposited by the pulsed DC reactive magnetron sputtering. Surf Coat Technol. 2006;200(10):3330.CrossRef
[33]
Zurück zum Zitat LaFontaine WR, Yost B, Li CY. Effect of residual stress and adhesion on the hardness of copper films deposited on silicon. Mat Res Soc. 1990;5(4):776.CrossRef LaFontaine WR, Yost B, Li CY. Effect of residual stress and adhesion on the hardness of copper films deposited on silicon. Mat Res Soc. 1990;5(4):776.CrossRef
[34]
Zurück zum Zitat Sellers J. Asymmetric bipolar pulsed DC: the enabling technology for reactive PVD. Surf Coat Technol. 1998;98(1):1245.CrossRef Sellers J. Asymmetric bipolar pulsed DC: the enabling technology for reactive PVD. Surf Coat Technol. 1998;98(1):1245.CrossRef
[35]
Zurück zum Zitat Lin JL, Moore JJ, Sproul WD, Mishra B, Wu ZL. Modulated pulse power sputtered chromium coatings. Thin Solid Films. 2009;518(5):1566.CrossRef Lin JL, Moore JJ, Sproul WD, Mishra B, Wu ZL. Modulated pulse power sputtered chromium coatings. Thin Solid Films. 2009;518(5):1566.CrossRef
[36]
Zurück zum Zitat Janssen GCAM. Stress and strain in polycrystalline thin films. Thin Solid Films. 2007;515(17):6654.CrossRef Janssen GCAM. Stress and strain in polycrystalline thin films. Thin Solid Films. 2007;515(17):6654.CrossRef
[37]
Zurück zum Zitat Moona MW, Jensen HM, Hutchinson JW, Oh KH, Evans AG. The characterization of telephone cord buckling of compressed thin films on substrates. J Mech Phys Solids. 2002;50(11):2355.CrossRef Moona MW, Jensen HM, Hutchinson JW, Oh KH, Evans AG. The characterization of telephone cord buckling of compressed thin films on substrates. J Mech Phys Solids. 2002;50(11):2355.CrossRef
Metadaten
Titel
Microstructure and mechanical properties of Cr films deposited with different peak powers by high-power impulse magnetron sputtering
verfasst von
Yu Wang
Bao-Hua Wu
Fan Jiang
Dong-Lin Ma
Yan Yu
Hong Sun
Nan Huang
Yong-Xiang Leng
Publikationsdatum
17.05.2017
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 1/2023
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-017-0897-6

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