Skip to main content
Erschienen in: Journal of Materials Science: Materials in Electronics 10/2024

01.04.2024

Mn/La co-doped WO3 (MnxLa0.03WO3+δ, x ≤ 0.1) ceramics for NTC thermistors

verfasst von: Kaifeng Li, Zhicheng Li, Yaqiong Wen, Yifei Zhan, Hong Zhang

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 10/2024

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The low sintering temperature (LST) is a great significance for the fabrication of sensors and electronic components. To exploit a system of LST negative temperature coefficient (NTC) thermistors, Mn/La co-doped WO3 ceramics (MnxLa0.03WO3+δ, x ≤ 0.1, denoted as xMLW) were prepared in this work by a traditional solid-state reaction technology. The phase component, microstructure, and electrical property of the prepared xMLW ceramics were investigated. The xMLW ceramics have the main phase with lattice structure as that of monoclinic WO3 with a space group of P21/n, and show typical NTC characteristics. By varying the concentration of Mn cations, the xMLW ceramics have adjustable room temperature resistivity (ρ25) ranging from 770 Ω·cm to 7.017 kΩ·cm and high thermal-sensitivity constants (B value) ranging from 2695 to 4219 K. The electrical conduction and NTC feature of the ceramics are discussed by analyzing impedance spectrum and lattice defect.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat L. Liu, Y. Zhou, R. Zheng, M. Gao, P. Zhao, A. Chang, Low-temperature synthesis and negative temperature coefficient conductivity properties of Mn–Ni–Cu–O spinel ceramics. J. Mater. Sci.: Mater. Electron. 34, 371 (2023) L. Liu, Y. Zhou, R. Zheng, M. Gao, P. Zhao, A. Chang, Low-temperature synthesis and negative temperature coefficient conductivity properties of Mn–Ni–Cu–O spinel ceramics. J. Mater. Sci.: Mater. Electron. 34, 371 (2023)
2.
Zurück zum Zitat M. Muralidharan, P. Rohini, E. Sunny, K. Dayas, A. Seema, Effect of Cu and Fe addition on electrical properties of Ni–Mn–Co–O NTC thermistor compositions. Ceram. Int. 38, 6481–6486 (2012)CrossRef M. Muralidharan, P. Rohini, E. Sunny, K. Dayas, A. Seema, Effect of Cu and Fe addition on electrical properties of Ni–Mn–Co–O NTC thermistor compositions. Ceram. Int. 38, 6481–6486 (2012)CrossRef
3.
Zurück zum Zitat H. Han, K.R. Park, Y. Hong, K. Shim, S. Mhin, Effect of Fe incorporation on cation distributions and hopping conductions in Ni-Mn-Co-O spinel oxides. J. Alloy. Compd. 732, 486–490 (2018)CrossRef H. Han, K.R. Park, Y. Hong, K. Shim, S. Mhin, Effect of Fe incorporation on cation distributions and hopping conductions in Ni-Mn-Co-O spinel oxides. J. Alloy. Compd. 732, 486–490 (2018)CrossRef
4.
Zurück zum Zitat N. El Horr, S. Guillemet-Fritsch, A. Rousset, H. Bordeneuve, C. Tenailleau, Microstructure of single-phase cobalt and manganese oxide spinel Mn3−xCoxO4 ceramics. J. Eur. Ceram. Soc. 34, 317–326 (2014)CrossRef N. El Horr, S. Guillemet-Fritsch, A. Rousset, H. Bordeneuve, C. Tenailleau, Microstructure of single-phase cobalt and manganese oxide spinel Mn3−xCoxO4 ceramics. J. Eur. Ceram. Soc. 34, 317–326 (2014)CrossRef
5.
Zurück zum Zitat Z. Ling, L. He, Thick-film negative-temperature-coefficient thermistors with a linear resistance-temperature relation. Chin. Phys. Lett. 30, 107201 (2013)CrossRef Z. Ling, L. He, Thick-film negative-temperature-coefficient thermistors with a linear resistance-temperature relation. Chin. Phys. Lett. 30, 107201 (2013)CrossRef
6.
Zurück zum Zitat P. Ouyang, H. Zhang, Y. Zhang, J. Wang, Z. Li, Zr-substituted SnO2-based NTC thermistors with wide application temperature range and high property stability. J. Mater. Sci.: Mater. Electron. 26, 6163–6169 (2015) P. Ouyang, H. Zhang, Y. Zhang, J. Wang, Z. Li, Zr-substituted SnO2-based NTC thermistors with wide application temperature range and high property stability. J. Mater. Sci.: Mater. Electron. 26, 6163–6169 (2015)
7.
Zurück zum Zitat S. Zhang, H. Zhang, S. Leng, Y. Wen, H. Wang, Z. Li, Electrical properties and aging characteristic of Sb/Ga co-doped single-cation oxide SnO2. J. Mater. Sci.: Mater. Electron. 33, 23821–23833 (2022) S. Zhang, H. Zhang, S. Leng, Y. Wen, H. Wang, Z. Li, Electrical properties and aging characteristic of Sb/Ga co-doped single-cation oxide SnO2. J. Mater. Sci.: Mater. Electron. 33, 23821–23833 (2022)
8.
Zurück zum Zitat G. Jiang, Z. Li, C. You, W. Hao, Z. Ma, H. Zhang, Temperature sensitivity and electrical stability of Sb/Mn co-doped SnO2 ceramics. J. Mater. Sci.: Mater. Electron. 32, 16945–16955 (2021) G. Jiang, Z. Li, C. You, W. Hao, Z. Ma, H. Zhang, Temperature sensitivity and electrical stability of Sb/Mn co-doped SnO2 ceramics. J. Mater. Sci.: Mater. Electron. 32, 16945–16955 (2021)
9.
Zurück zum Zitat Z. Yang, H. Zhang, Z. He, B. Li, Z. Li, Influence of B3+- and Na+-ions on electrical property and temperature sensitivity of NiO-based ceramics. J. Mater. Sci.: Mater. Electron. 30, 3088–3097 (2019) Z. Yang, H. Zhang, Z. He, B. Li, Z. Li, Influence of B3+- and Na+-ions on electrical property and temperature sensitivity of NiO-based ceramics. J. Mater. Sci.: Mater. Electron. 30, 3088–3097 (2019)
10.
Zurück zum Zitat L. Huang, Z. Li, K. Li, Y. Zhang, H. Zhang, S. Leng, Electrical conductivity and electrical stability of Bi/Mg modified NiO ceramics for NTC thermistors. Processing and Application of Ceramics 17, 172–180 (2023)CrossRef L. Huang, Z. Li, K. Li, Y. Zhang, H. Zhang, S. Leng, Electrical conductivity and electrical stability of Bi/Mg modified NiO ceramics for NTC thermistors. Processing and Application of Ceramics 17, 172–180 (2023)CrossRef
11.
Zurück zum Zitat D. Peng, Z. Li, L. Huang, C. You, H. Wang, H. Zhang, Characterization of NiO based ceramics modified with Y2O3/BiSbO3 for application of NTC thermistors. J. Mater. Sci.: Mater. Electron. 33, 11092–11105 (2022) D. Peng, Z. Li, L. Huang, C. You, H. Wang, H. Zhang, Characterization of NiO based ceramics modified with Y2O3/BiSbO3 for application of NTC thermistors. J. Mater. Sci.: Mater. Electron. 33, 11092–11105 (2022)
12.
Zurück zum Zitat B.K. Koo, Fabrication and characteristics of NTC thermistor for low temperature sintering. J. Korean Cryst. Growth Cryst. Technol. 28, 28–37 (2018) B.K. Koo, Fabrication and characteristics of NTC thermistor for low temperature sintering. J. Korean Cryst. Growth Cryst. Technol. 28, 28–37 (2018)
13.
Zurück zum Zitat L. Huang, H. Zhang, S. Leng, M. Li, Z. Li, Electrical properties of NiO-based composite ceramics modified by La2MO4 (M= Cu or Ni) for NTC thermistors. J. Mater. Sci.: Mater. Electron. 34, 1137 (2023) L. Huang, H. Zhang, S. Leng, M. Li, Z. Li, Electrical properties of NiO-based composite ceramics modified by La2MO4 (M= Cu or Ni) for NTC thermistors. J. Mater. Sci.: Mater. Electron. 34, 1137 (2023)
14.
Zurück zum Zitat C. Dong, R. Zhao, L. Yao, Y. Ran, X. Zhang, Y. Wang, A review on WO3 based gas sensors: Morphology control and enhanced sensing properties. J. Alloy. Compd. 820, 153194 (2020)CrossRef C. Dong, R. Zhao, L. Yao, Y. Ran, X. Zhang, Y. Wang, A review on WO3 based gas sensors: Morphology control and enhanced sensing properties. J. Alloy. Compd. 820, 153194 (2020)CrossRef
15.
Zurück zum Zitat T. Gao, B.P. Jelle, Electrochromism of hexagonal sodium tungsten bronze nanorods. Sol. Energy Mater. Sol. Cells 177, 3–8 (2018)CrossRef T. Gao, B.P. Jelle, Electrochromism of hexagonal sodium tungsten bronze nanorods. Sol. Energy Mater. Sol. Cells 177, 3–8 (2018)CrossRef
16.
Zurück zum Zitat C. Guo, S. Yin, T. Sato, Synthesis of one-dimensional hexagonal sodium tungsten oxide and its near-infrared shielding property. Nanosci. Nanotechnol. Lett. 3, 413–416 (2011)CrossRef C. Guo, S. Yin, T. Sato, Synthesis of one-dimensional hexagonal sodium tungsten oxide and its near-infrared shielding property. Nanosci. Nanotechnol. Lett. 3, 413–416 (2011)CrossRef
17.
Zurück zum Zitat I.M. Szilágyi, B. Fórizs, O. Rosseler, Á. Szegedi, P. Németh, P. Király, G. Tárkányi, B. Vajna, K. Varga-Josepovits, K. László, WO3 photocatalysts: Influence of structure and composition. J. Catal. 294, 119–127 (2012)CrossRef I.M. Szilágyi, B. Fórizs, O. Rosseler, Á. Szegedi, P. Németh, P. Király, G. Tárkányi, B. Vajna, K. Varga-Josepovits, K. László, WO3 photocatalysts: Influence of structure and composition. J. Catal. 294, 119–127 (2012)CrossRef
18.
Zurück zum Zitat T. Wang, Q. Qin, W. Zhang, Effect of La2O3 on the electrical properties of WO3-based varistor ceramics. Key Eng. Mater. 480, 137–141 (2011)CrossRef T. Wang, Q. Qin, W. Zhang, Effect of La2O3 on the electrical properties of WO3-based varistor ceramics. Key Eng. Mater. 480, 137–141 (2011)CrossRef
19.
Zurück zum Zitat V. Makarov, M. Trontelj, Sintering and electrical conductivity of doped WO3. J. Eur. Ceram. Soc. 16, 791–794 (1996)CrossRef V. Makarov, M. Trontelj, Sintering and electrical conductivity of doped WO3. J. Eur. Ceram. Soc. 16, 791–794 (1996)CrossRef
20.
Zurück zum Zitat S. Sawada, Thermal and electrical properties of tungsten oxide (WO3). J. Phys. Soc. Jpn. 11, 1237–1246 (1956)CrossRef S. Sawada, Thermal and electrical properties of tungsten oxide (WO3). J. Phys. Soc. Jpn. 11, 1237–1246 (1956)CrossRef
21.
Zurück zum Zitat X. Lu, T. Zhai, X. Zhang, Y. Shen, L. Yuan, B. Hu, L. Gong, J. Chen, Y. Gao, J. Zhou, Y. Tong, Z. Wang, WO3-x@Au@MnO2 core-shell nanowires on carbon fabric for high-performance flexible supercapacitors. Advance Materials 24, 938–944 (2012)CrossRef X. Lu, T. Zhai, X. Zhang, Y. Shen, L. Yuan, B. Hu, L. Gong, J. Chen, Y. Gao, J. Zhou, Y. Tong, Z. Wang, WO3-x@Au@MnO2 core-shell nanowires on carbon fabric for high-performance flexible supercapacitors. Advance Materials 24, 938–944 (2012)CrossRef
22.
Zurück zum Zitat Z. Wei, W. Wang, W. Li, X. Bai, J. Zhao, E.C.M. Tse, D.L. Phillips, Y. Zhu, Steering electron-hole migration pathways using oxygen vacancies in tungsten oxides to enhance their photocatalytic oxygen evolution performance. Angewandte Chemie-Int. Edit. 60, 8236–8242 (2021)CrossRef Z. Wei, W. Wang, W. Li, X. Bai, J. Zhao, E.C.M. Tse, D.L. Phillips, Y. Zhu, Steering electron-hole migration pathways using oxygen vacancies in tungsten oxides to enhance their photocatalytic oxygen evolution performance. Angewandte Chemie-Int. Edit. 60, 8236–8242 (2021)CrossRef
23.
Zurück zum Zitat S. Guan, L. Hao, M. Murayama, X. Xie, S. Komuro, X. Zhao, Influence of anneal temperature in air on surface morphology and photoluminescence of ZnO thin films. IOP Conf. Ser.: Mater. Sci. Eng. 522, 012004 (2019)CrossRef S. Guan, L. Hao, M. Murayama, X. Xie, S. Komuro, X. Zhao, Influence of anneal temperature in air on surface morphology and photoluminescence of ZnO thin films. IOP Conf. Ser.: Mater. Sci. Eng. 522, 012004 (2019)CrossRef
24.
25.
Zurück zum Zitat Z. Huang, J. Song, L. Pan, X. Zhang, L. Wang, J. Zou, Tungsten oxides for photocatalysis, electrochemistry, and phototherapy. Adv. Mater. 27, 5309–5327 (2015)CrossRefPubMed Z. Huang, J. Song, L. Pan, X. Zhang, L. Wang, J. Zou, Tungsten oxides for photocatalysis, electrochemistry, and phototherapy. Adv. Mater. 27, 5309–5327 (2015)CrossRefPubMed
Metadaten
Titel
Mn/La co-doped WO3 (MnxLa0.03WO3+δ, x ≤ 0.1) ceramics for NTC thermistors
verfasst von
Kaifeng Li
Zhicheng Li
Yaqiong Wen
Yifei Zhan
Hong Zhang
Publikationsdatum
01.04.2024
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 10/2024
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-024-12469-9

Weitere Artikel der Ausgabe 10/2024

Journal of Materials Science: Materials in Electronics 10/2024 Zur Ausgabe

Neuer Inhalt