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Arabian Journal for Science and Engineering
Erschienen in: Arabian Journal for Science and Engineering 7/2021

07.01.2021 | Research Article-Chemical Engineering

Modeling of Congo Red Adsorption onto Multi-walled Carbon Nanotubes Using Response Surface Methodology: Kinetic, Isotherm and Thermodynamic Studies

verfasst von: Veyis Selen, Ömer Güler

Erschienen in: Arabian Journal for Science and Engineering | Ausgabe 7/2021

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Abstract

In this present study, an adsorption process was investigated to removal of Congo Red (CR) dye from aqueous solutions by using multi-walled carbon nanotubes (MWCNTs) as an adsorbent. The physico-chemical properties of MWCNTs were characterized by TEM, SEM, Raman spectroscopy and BET surface area. The response surface methodology, which is including central composite design, was used to investigate the effects of four independent parameters (initial pH of solution (5.5–11.5), initial CR concentration (15–75 mg/L), MWCNTs amount (0.05–0.25 g/L) and contact time (20–60 min)). ANOVA evaluated with Design Expert 10.0 showed that a high value of regression coefficient (R2 = 0.988) a good agreement between experimental and model predicted response in addition to significance of the model. The optimum values of the independent variables giving the maximum removal efficiency (78.36%) of CR dye were obtained at the optimum adsorption conditions of initial solution pH: 5.5; initial CR concentration: 15 mg/L; MWCNTs dosage: 0.25 g/L and contact time: 59.62 min. The kinetic study illustrated that the experimental data are well defined with pseudo-second-order adsorption kinetic model. The maximum adsorption capacity (qmax) increased from 115.8 mg/g to 138.3 mg/g with the increase in temperature from 293 to 323 K. Thermodynamic parameters, ΔH (8.56 kJ/mol), ΔG (− 27.08 and − 30.73 kJ/mol) and ΔS (0.1215 kJ/mol K) were determined for the adsorption process.
Vorheriger Artikel Butyric Acid Reactive Extraction Using Trioctylamine in 1-Decanol: Response Surface Methodology Parametric Optimization Technique
Nächster Artikel Optimization of the Asymmetric Cellulose Acetate Membrane Synthesis Variables for Porosity and Pure Water Permeation Flux Using Response Surface Methodology: Microfiltration Application

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Metadaten
Titel
Modeling of Congo Red Adsorption onto Multi-walled Carbon Nanotubes Using Response Surface Methodology: Kinetic, Isotherm and Thermodynamic Studies
verfasst von
Veyis Selen
Ömer Güler
Publikationsdatum
07.01.2021
Verlag
Springer Berlin Heidelberg
Erschienen in
Arabian Journal for Science and Engineering / Ausgabe 7/2021
Print ISSN: 2193-567X
Elektronische ISSN: 2191-4281
DOI
https://doi.org/10.1007/s13369-020-05304-w

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