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Polymer Bulletin
Erschienen in: Polymer Bulletin 2/2012

01.01.2012 | Original Paper

Modeling of kinetics of pertechnetate removal by amino-functionalized glycidyl methacrylate copolymer

verfasst von: Danijela D. Maksin, Radmila V. Hercigonja, Magdalena Ž. Lazarević, Marija J. Žunić, Aleksandra B. Nastasović

Erschienen in: Polymer Bulletin | Ausgabe 2/2012

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Abstract

Technetium-99 comprises a significant health risk, since edible plants can bioaccumulate and convert it to more lipophilic species that cannot be excreted through urine. Batch kinetics of pertechnetate removal from aqueous solutions by two samples of crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) functionalized with diethylene triamine (PGME-deta) was investigated at the optimum pH value of 3.0, and the initial solution activity of 325 MBq dm−3. PGME-deta was characterized by elemental analysis, mercury intrusion porosimetry, and scanning electron microscopy. Five kinetic models (pseudo-first, pseudo-second order, Elovich, Bangham, and intraparticle diffusion) were used to determine the best-fit equation for pertechnetate sorption. After 24 h, PGME-deta samples sorbed more than 98% of pertechnetate present, with maximum sorption capacity of 25.5 MBq g−1, showing good potential for remediation of slightly contaminated groundwater.
Vorheriger Artikel Investigating the UV-curing performance for polyacrylated polymer in dendritic and regular conformation
Nächster Artikel UV-curable water-borne polyurethane primers for aluminum and polycarbonate interfaces

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Literatur
1.
Schwochau K (2000) Artificial occurrence. In: Technetium: chemistry and radiopharmaceutical applications, 1st edn. Wiley-VCH, New York, pp 10–34
2.
Garcia-Leon M (2005) 99Tc in the environment: sources, distribution and methods. J Nucl Radiochem Sci 6(3):253–259
3.
Rard JA, Rand MH, Anderegg G, Wanner H (1999) Discussion of data selection. In: Sandino MCA, Östhols E (eds) Chemical thermodynamics 3: chemical thermodynamics of technetium. Elsevier Science, North-Holland, pp 63–266
4.
Winkler A, Brühl H, Trapp C, Bock WD (1998) Mobility of technetium in various rock and defined combinations of natural minerals. Radiochim Acta 44(45):183–186
5.
Wharton MJ, Atkins B, Charnock JM, Livens FR, Pattrick RAD, Colison D (2000) An X-ray absorption spectroscopy study of the coprecipitation of Tc and Re with Mackinawite (FeS). Appl Geochem 15:347–354CrossRef
6.
USEPA, U.S. Environmental Protection Agency, Office of Air and Radiation (2004) Contaminant geochemistry and Kd values. In: Understanding variation in partition coefficient, Kd, values, volume III: review of geochemistry and available Kd values for Americium, Arsenic, Curium, Iodine, Neptunium, Radium, and Technetium. EPA 402-R-04-002C. http://​www.​epa.​gov/​radiation/​docs/​kdreport/​vol3/​402-r-04-002c.​pdf. Accessed 13 June 2011
7.
Yoshihara K (1996) Technetium in the environment. Top Curr Chem 176:17–35
8.
Amano R, Ando A, Hiraki T, Mori H, Matsuda H, Hisada K (1990) Rapid uptake of technetium-99m pertechnetate by several plants. Radioisotopes 39:583–586
9.
10.
Peretroukhine V, Sergeant C, Devès G, Poulain S, Vesvres MH, Thomas B, Simonoff M (2005) Technetium sorption by stibnite from natural water. Radiochim Acta 94(9–11):665–669
11.
Lieser KH, Bauscher CH (1988) Technetium in the hydrosphere and in the geosphere. II. Influence of pH, of complexing agents and of some minerals on the sorption of technetium. Radiochim Acta 44(45):125–128
12.
Cul GD, del Bostick WD, Trotter DR, Osborne PE (1993) Technetium-99 removal from process solutions and contaminated groundwater. Sep Sci Technol 28:551–564CrossRef
13.
Bors J, Dultz S, Riebe B (2000) Organophilic bentonites as adsorbents for radionuclides I. Adsorption of ionic fission products. Appl Clay Sci 16:1–13CrossRef
14.
Gu B, Dowlen KE, Liang L, Clausen JL (1996) Efficient separation and recovery of technetium-99 from contaminated groundwater. Sep Technol 6:123–132CrossRef
15.
Wang Y, Gao H, Yeredla R, Xu H, Abrecht M (2007) Control of pertechnetate sorption on activated carbon by surface functional groups. J Colloid Interface Sci 305:209–217CrossRef
16.
Holm E, Gäfvert T, Lindahl P, Roos P (2000) In situ sorption of technetium using activated carbon. Appl Radiat Isot 53:153–157CrossRef
17.
Liang L, Gu B, Yin X (1996) Removal of technetium-99 from contaminated groundwater with sorbents and reductive materials. Sep Technol 6:111–112CrossRef
18.
Chen QJ, Dahlgaard H, Hansen HJM, Aarkrog A (1990) Determination of 99Tc in environmental samples by anion exchange and liquid–liquid extraction at controlled valency. Anal Chim Acta 228:163–167CrossRef
19.
Suzuki T, Fujii Y, Yan W, Mimura H, Koyama S, Ozawa M (2009) Adsorption behavior of VII group elements on tertiary pyridine resin in hydrochloric acid solution. J Radioanal Nucl Chem 282:641–644CrossRef
20.
Bonnesen PV, Brown GM, Alexandratos S, Bavoux LB, Presley DJ, Patel V, Ober R, Moyer BA (2000) Development of bifunctional anion exchange resins with improved selectivity and sorptive kinetics for pertechnetate. Batch-equilibrium experiments. Environ Sci Technol 34:3761–3766CrossRef
21.
Chen J, Veltkamp JC (2002) Pertechnetate removal by macroporous polymer impregnated with 2-nitrophenyl octyl ether (NPOE). Solvent Extr Ion Exch 20:515–524CrossRef
22.
Katayev EA, Kolesnikov GV, Sessler JL (2009) Molecular recognition of pertechnetate and perrhenate. Chem Soc Rev 38:1572–1586CrossRef
23.
Nastasović A, Sandić Z, Suručić Lj, Maksin D, Jakovljević D, Onjia A (2009) Kinetics of hexavalent chromium sorption on amino-functionalized macroporous glycidyl methacrylate copolymer. J Hazard Mater 171(1–3):153–159CrossRef
24.
Kalalova E, Thuy P (1990) Separation of iridium from platinum using a modified glycidyl methacrylate copolymer with diethylamino groups. Angew Makromol Chem 180:159–167CrossRef
25.
Bicak N, Sherrington DC, Sungur S, Tan N (2003) A glycidyl methacrylate-based resin with pendant urea groups as a high capacity mercury specific sorbent. React Funct Polym 54:141–147CrossRef
26.
Kim E, Benedetti MF, Boulègue J (2004) Removal of dissolved rhenium by sorption onto organic polymers: study of rhenium as an analogue of radioactive technetium. Water Res 38:448–454CrossRef
27.
Plevaka AV, Troshkina ID, Zemskova LA, Voit AV (2009) Rhenium sorption by fibrous chitosan-carbon materials. Russ J Inorg Chem 54(7):1168–1171CrossRef
28.
29.
Ho YS (2006) Review of second-order models for adsorption systems. J Hazard Mater B136:681–689CrossRef
30.
Knoll G (1979) Radiation detection and measurement. Wiley, Hoboken, NJ
31.
Hercigonja RV, Maksin DD, Nastasović AB, Trifunović SS, Glodić PB, Onjia AE (2011) Adsorptive removal of technetium-99 using macroporous poly(GMA-co-EGDMA) modified with diethylene triamine. J Appl Polym Sci. doi: 10.​1002/​app.​34693
32.
Švec F, Fréchet JMJ (1995) Temperature, a simple and efficient tool for the control of pore size distribution in macroporous polymers. Macromolecules 28:7580–7582CrossRef
33.
Paredes B, González S, Rendueles M, Villa-García MA, Díaz M (2003) Influence of the amination conditions on the textural properties and chromatographic behaviour of amino-functionalized glycidyl methacrylate-based particulate supports. Acta Mater 51:6189–6198CrossRef
34.
Webb PA, Orr C (1997) Analytical methods in fine particle technology. Micrometrics Instrument Corporation, Norcross, GA
35.
Darab JG, Amonette AB, Burke DSD, Orr RD (2007) Removal of pertechnetate from simulated nuclear waste streams using supported zerovalent iron. Chem Mater 19:5703–5713CrossRef
36.
37.
IAEA (1994) Classification of radioactive waste: a safety guide. Safety series No. 111-G-l.l International Atomic Energy Agency, Vienna
38.
Bond AH, Chang FWK, Thakkar AH, Williamson JM, Gula MJ, Harvey JT, Griffin ST, Rogers RD, Horwitz EP (1999) Design, synthesis, and uptake performance of ABEC resins for the removal of pertechnetate from alkaline radioactive wastes. Ind Eng Chem Res 38:1676–1682CrossRef
39.
Anderson H, Asprey L (1960) Solvent extraction process for plutonium. US patent 2924506
40.
Rard JA (2005) Current status of the thermodynamic data for technetium and its compounds and aqueous species. J Nucl Radiochem Sci 6:197–204
41.
Um W, Chang HS, Icenhower JP, Lukens WW, Serne RJ, Qafoku NP, Westsik JH Jr, Buck EC, Smith SC (2011) Immobilization of 99-technetium (VII) by Fe(II)-goethite and limited reoxidation. Environ Sci Technol 45:4904–4913CrossRef
42.
Wildung RE, McFadden KM, Garland TR (1979) Technetium sources and behaviour in the environment. J Environ Qual 8:156–161CrossRef
43.
IAEA (2002) Application of ion exchange processes for the treatment of radioactive waste and management of spent ion exchangers, technical reports series No. 408. IAEA, Vienna
44.
USEPA (1981) U.S. Environmental Protection Agency. Summary report: control and treatment technology for the metal finishing industry-ion exchange. USEPA EPA 625/-81-007
45.
Diamond RM, Whitney DC (1966) Resin selectivity in dilute to concentrated aqueous solutions. In: Marinsky J (ed) Ion exchange, a series of advances, vol 1. Marcel Dekker, New York, pp 277–351
46.
Gregor HP, Belle J, Marcus RA (1955) Studies on ion-exchange resins. XIII. Selectivity coefficients of quaternary base anion-exchange resins toward univalent anions. J Am Chem Soc 77:2713–2719CrossRef
47.
Piracha A, Zulfiqar S, McNeill IC (1996) The thermal degradation of copolymers of glycidyl methacrylate and vinylacetate. Polym Degrad Stab 51:319–326CrossRef
48.
Çaykara T, Çakar F, Demirci S (2008) A new type of poly(glycidyl methacrylate) microbeads with surface grafted iminodiacetic acid: synthesis and characterization. Polym Bull 61:311–318CrossRef
49.
Koopal LK, van Riemsdijk WH, de Wit JCM, Benedetti MF (1994) Analytical isotherm equations for multicomponent adsorption to heterogeneous surfaces. J Colloid Interface Sci 166:51–60CrossRef
50.
51.
Plazinski W, Rudzinski W, Plazinska A (2009) Theoretical models of sorption kinetics including a surface reaction mechanism: a review. Adv Colloid Interface Sci 152:2–13CrossRef
52.
Lagergren S (1898) About the theory of so-called adsorption of soluble substances. ***K Sven Vetenskapsakad Handl 24:1–39
53.
Sparks DL (1989) Kinetics of soil chemical processes. Academic Press Inc., New York
54.
Ho YS, Ng JCY, McKay G (2000) Kinetics of pollutant sorption by biosorbents: review. Sep Purif Methods 29:189–232CrossRef
55.
Febrianto J, Kosasih AN, Sunarso J, Ju Y, Indraswati N, Ismadji S (2009) Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent: a summary of recent studies. J Hazard Mater 162:616–645CrossRef
56.
Janoš P, Michálek P, Turek L (2007) Sorption of ionic dyes onto untreated low-rank coal–oxihumolite: a kinetic study. Dyes Pigment 74:363–370CrossRef
57.
Lin CC, Lai Y (2006) Adsorption and recovery of lead(II) from aqueous solutions by immobilized Pseudomonas Aeruginosa PU21 beads. J Hazard Mater 137:99–105CrossRef
58.
Ho YS, McKay G (1998) A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents. Process Saf Environ Prot (Trans Ichem E, B) 76(4):332–340CrossRef
59.
Zhang J, Stanforth R (2005) Slow adsorption reaction between arsenic species and Goethite (α-FeOOH): diffusion or heterogeneous surface reaction control. Langmuir 21:2895–2901CrossRef
60.
Boyd GE, Adamson AW, Myers LS (1947) The exchange adsorption of ions from aqueous solutions by organic zeolites, II: kinetics. J Am Chem Soc 69:2836–2842CrossRef
61.
Özcan A, Özcan AS (2005) Adsorption of acid Red 57 from aqueous solutions onto surfactant-modified sepiolite. J Hazard Mater B125:252–259CrossRef
62.
Singh S, Rai BN, Rai LC (2001) Ni(II) and Cr(VI) sorption kinetics by Mycrocystis in single and multimetallic system. Process Biochem 36:1205–1212CrossRef
63.
Gupta SS, Bhattacharyya KG (2011) Kinetics of adsorption of metal ions on inorganic materials: a review. Adv Colloid Interface Sci 162:39–58CrossRef
64.
Aharoni C, Ungarish M (1977) Kinetics of activated chemisorptions: part 2. Theoretical models. J Chem Soc Faraday Trans 73:456–464CrossRef
65.
Tutem E, Apak R, Unal CF (1998) Adsorptive removal of chlorophenols from water by bituminous shale. Water Res 32(8):2315–2324CrossRef
66.
Ofomaja AE, Naidoo EB, Modise SJ (2010) Kinetic and pseudo-second-order modeling of lead biosorption onto pine cone powder. Ind Eng Chem Res 49:2562–2572CrossRef
Metadaten
Titel
Modeling of kinetics of pertechnetate removal by amino-functionalized glycidyl methacrylate copolymer
verfasst von
Danijela D. Maksin
Radmila V. Hercigonja
Magdalena Ž. Lazarević
Marija J. Žunić
Aleksandra B. Nastasović
Publikationsdatum
01.01.2012
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 2/2012
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-011-0634-5

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