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Polymer Bulletin
Erschienen in: Polymer Bulletin 2/2012

01.01.2012 | Original Paper

Synthesis and properties of 2-(10,11-dihydrodibenz[b,f]azepine-5-yl)carbazole-based monomers and polymers

verfasst von: Ausra Tomkeviciene, Tatjana Bartiuk, Juozas Vidas Grazulevicius

Erschienen in: Polymer Bulletin | Ausgabe 2/2012

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Abstract

The synthesis of a series of 2-(10,11-dihydrodibenz(b,f)azepinyl)carbazole-based monomers is reported. Full characterization of their structures is presented. The monomers were subjected to cationic polymerization using BF3·O(C2H5)2 as an initiator. The synthesized monomers and polymers were examined by differential scanning calorimetry, UV spectrometry, cyclic voltammetry and electron photoemission spectrometry. The electrochemical investigation of the solutions of the synthesized compounds revealed HOMO values ranging from −5.12 to −5.06 eV. Electron photoemission spectrometry of the solid samples gave ionization potentials of 5.40–5.50 eV.
Vorheriger Artikel Influence of selected photoinitiators type II on tack, peel adhesion, and shear strength of UV-crosslinked solvent-borne acrylic pressure-sensitive adhesives used for medical applications
Nächster Artikel The preparation of carbon nanotube/poly(ethylene oxide) composites using amphiphilic block copolymers

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Metadaten
Titel
Synthesis and properties of 2-(10,11-dihydrodibenz[b,f]azepine-5-yl)carbazole-based monomers and polymers
verfasst von
Ausra Tomkeviciene
Tatjana Bartiuk
Juozas Vidas Grazulevicius
Publikationsdatum
01.01.2012
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 2/2012
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-011-0564-2

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